Total carbon organic carbon and organic matter

Total Carbon, Organic Carbon, and Organic Matter

Total Carbon, Organic Carbon, and Organic Matter 1

SOIL SAMPLING AND HANDLING, G.T. Patterson and M.R. Carter Soil Sampling Designs, D. Pennock, T. Yates, and J. Braidek Sampling Forest Soils, N. Belanger and K.C.J. Van Rees Measuring Change in Soil Organic Carbon Storage, B.H. Ellert, H.H. Janzen, A.J. VandenBygaart, and E. Bremer Soil Sample Handling and Storage, S.C. Sheppard and J.A. Addison Quality Control in Soil Chemical Analysis, C. Swyngedouw and R. Lessard DIAGNOSTIC METHODS for SOIL and ENVIRONMENTAL MANAGEMENT, J.J. Schoenau and I.P. O'Halloran Nitrate and Exchangeable Ammonium Nitrogen, D.G. Maynard, Y.P. Kalra, and J.A. Crumbaugh Mehlich 3 Extractable Elements, N. Ziadi and T. Sen Tran Sodium Bicarbonate Extractable Phosphorus, J.J. Schoenau and I. P. O'Halloran Boron, Molybdenum and Selenium, G. M. Hettiarachchi and U. C. Gupta Trace Element Assessment, W.H. Hendershot, H. Lalande, D. Reyes, and D. MacDonald Readily Soluble Aluminum and Manganese in Acid Soils, Y.K. Soon, N. Belanger, and W.H. Hendershot Lime Requirement, N. Ziadi and T. Sen Tran Ion Supply Rates Using Ion Exchange Resins, P. Qian, J.J. Schoenau, and N. Ziadi Environmental Soil Phosphorus Indices, A.N. Sharpley, P.J.A. Kleinman and J.L. Weld Electrical Conductivity and Soluble Ions, J.J. Miller and D. Curtin SOIL CHEMICAL ANALYSES, Y.K. Soon and W.H. Hendershot Soil Reaction and Exchangeable Acidity, W.H. Hendershot, H. Laland,e and M. Duquette Collection and Characterization of Soil Solutions, J.D. MacDonald, N. Belanger, S. Sauve, F. Courchesne, and W.H. Hendershot Ion Exchange and Exchangeable Cations, W.H. Hendershot, H. Lalande, and M. Duquette Non-Exchangeable Ammonium, Y.K. Soon and B.C. Liang Carbonates, T.B. Goh and A.R. Mermut Total and Organic Carbon, J.O. Skjemstad and J.A. Baldock Total Nitrogen, P.M. Rutherford, W.B. McGill, C.T. Figueiredo, and J.M. Arocena Chemical Characterization of Soil Sulphur, C.G. Kowalenko and M. Grimmett Total and Organic Phosphorus, I.P. O'Halloran and B.J. Cade-Menum Characterization of Available P by Sequential Extraction, H. Tiessen and J.O. Moir Extractable Al, Fe, Mn, and Si, F. Courchesne and M.C. Turmel Determining Nutrient Availability in Forest Soils, N. Belanger, David Pare, and W.H. Hendershot Chemical Properties of Organic Soils, A. Karam SOIL BIOLOGICAL ANALYSES, E. Topp and C.A. Fox Cultural Methods for Soil and Root Associated Microorganisms, J.J. Germida and J.R. de Freitas Arbuscular Mycorrhiza, Y. Dalpe and C. Hamel Root Nodule Bacteria and Symbiotic Nitrogen Fixation, D. Prevost and H. Antoun Microarthropods, J.P Winter and V.M. Behan-Pelletier Nematodes, T.A. Forge and J. Kimpinski Earthworms, M.J. Clapperton, G.H. Baker and C.A. Fox Enchytraeids, S.M. Adl Protozoa, S.M. Adl, D. Acosta-Mercado, and D.H. Lynn Denitrification Techniques for Soils, C.F. Drury, D.D. Myrold, E.G. Beauchamp, and W.D.Reynolds Nitrification Techniques in Soil Systems, C.F. Drury, S.C. Hart, and X.M. Yang Substrate-Induced Respiration and Selective Inhibition as Measures of Microbial Biomass in Soils, V.L. Bailey, J.L. Smith, and H. Bolton Jr. Assessment of Soil Biological Activity, R.P.Beyaert and C.A. Fox Soil ATP, R.P. Voroney, G. Wen, and R.P. Beyaert Lipid-Based Community Analysis, K.E. Dunfield Bacterial Community Analyses by Denaturing Gradient Gel Electrophoresis (DGGE), E. Topp, Y.-C. Tien, and A. Hartmann Indicators of Soil Food Web Properties, T.A. Forge and M. Tenuta SOIL ORGANIC MATTER ANALYSES, E.G. Gregorich and M.H. Beare Carbon Mineralization, D.W. Hopkins Mineralizable Nitrogen, Denis Curtin and C.A. Campbell Physically Uncomplexed Organic Matter, E.G. Gregorich and M.H. Beare Extraction and Characterization of Dissolved Organic Matter, M.H. Chantigny, D.A. Angers, K. Kaiser, and K. Kalbitz Soil Microbial Biomass C, N, P and S, R.P. Voroney, P.C. Brookes, and R.P. Beyaert Carbohydrates, M.H. Chantigny and D.A. Angers Organic Forms of Nitrogen, D.C. Olk Soil Humus Fractions, D.W. Anderson and J.J Schoenau Soil Organic Matter Analysis by Solid-State 13C Nuclear Magnetic Resonance Spectroscopy, M. J. Simpson and C. M. Preston Stable Isotopes in Soil and Environmental Research, B.H. Ellert and L. Rock SOIL PHYSICAL ANALYSES, D.A. Angers and F.J. Larney Particle Size Distribution, D. Kroetsch and C. Wang Soil Shrinkage, C.D. Grant Soil Density and Porosity, X. Hao, B.C. Ball, J.L.B. Culley, M.R. Carter, and G.W. Parkin Soil Consistency: Upper and Lower Plastic Limits, R.A. McBride Compaction and Compressibility, P. Defossez, T. Keller and G. Richard Field Soil Strength, G.C. Topp and D.R. Lapen Air Permeability, C.D. Grant and P.H. Groenevelt Aggregate Stability to Water, D.A. Angers, M.S. Bullock, and G.R. Mehuys Dry Aggregate Size Distribution, F.J. Larney Soil Air, R.E. Farrell and J.A. Elliott Soil-Surface Gas Emissions, P. Rochette and N. Bertrand Bulk Density Measurement in Forest Soils, D.G. Maynard and M.P. Curran Physical Properties of Organic Soils and Growing Media: Particle Size and Degree of Decomposition, L.E. Parent and J. Caron Physical Properties of Organic Soils and Growing Media: Water and Air Storage and Flow Dynamics, J. Caron, D.E. Elrick, J.C. Michel, and R. Naasz SOIL WATER ANALYSES, W.D. Reynolds and G.C. Topp Soil Water Analyses: Principles and Parameters, W.D. Reynolds and G.C. Topp Soil Water Content, G.C. Topp, G.W. Parkin, and Ty P.A Ferre Soil Water Potential, N.J. Livingston and G.C. Topp Soil Water Desorption and Imbibition: Tension and Pressure Techniques, W.D. Reynolds and G.C. Topp Soil Water Desorption and Imbibition: Long Column, W.D. Reynolds and G.C. Topp Soil Water Desorption and Imbibition: Psychrometry, W.D. Reynolds and G.C. Topp Saturated Hydraulic Properties: Laboratory Methods, W.D. Reynolds Saturated Hydraulic Properties: Well Permeameter, W.D. Reynolds Saturated Hydraulic Properties: Ring Infiltrometer, W.D. Reynolds Saturated Hydraulic Properties: Auger-Hole, G.C. Topp Saturated Hydraulic Properties: Piezometer, G.C. Topp Unsaturated Hydraulic Properties: Laboratory Tension Infiltrometer, F.J. Cook Unsaturated Hydraulic Properties: Laboratory Evaporation, O.O. B. Wendroth and N. Wypler Unsaturated Hydraulic Properties: Field Tension Infiltrometer, W.D. Reynolds Unsaturated Hydraulic Properties: Instantaneous Profile, W.D. Reynolds Estimation of Soil Hydraulic Properties, F.J. Cook and H.P. Cresswell Analysis of Soil Variability, B.C. Si, R.G. Kachanoski, and W.D. Reynolds APPENDIX Site Description, G.T. Patterson and J.A. Brierley General Safe Laboratory Operation Procedures, P. St-Georges INDEX

Soil Sampling and Methods of Analysis

Scattered literature is harnessed to critically review the possible sources, chemistry, potential biohazards and best available remedial strategies for a number of heavy metals (lead, chromium, arsenic, zinc, cadmium, copper, mercury and nickel) commonly found in contaminated soils. The principles, advantages and disadvantages of immobilization, soil washing and phytoremediation techniques which are frequently listed among the best demonstrated available technologies for cleaning up heavy metal contaminated sites are presented. Remediation of heavy metal contaminated soils is necessary to reduce the associated risks, make the land resource available for agricultural production, enhance food security and scale down land tenure problems arising from changes in the land use pattern.

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Heavy Metals in Contaminated Soils: A Review of Sources, Chemistry, Risks and Best Available Strategies for Remediation

A simple and precise procedure for estimating total N in plant tissue is described; a modification is also described for analysis of samples containing high nitrate concentrations. Plant tissue samples are placed in pyrex Folin-Wu tubes and digested with a salt-catalyst-sulfuric acid mixture by heating the tubes in an aluminum block. Samples are digested at the boiling point of the mixture for 60 min after initial clearing of the digests. Analyses of diverse plant materials, containing from 0.006 to 0.3% NO₃-N₃ indicated that the proposed and standard AOAC procedures yielded essentially the same total N values. The coefficient of variation for the proposed methods varied from 0.87 to 1.10%. The tube digestion procedures described allows digestion of 60 plant samples simultaneously and thus greatly improve the efficiency of total N determinations.

Determination of Total Nitrogen in Plant Material1

Electron Spectroscopy for Chemical Analysis (ESCA) was used to provide information concerning the chemical bonding of zinc and copper present in the sludge obtained from the Dayton, Ohio sewage treatment plant. The binding energy of the Zn 2P/sub 3/2/ electron in sludge when placed under a vacuum of 10/sup -7/ Torr was 1023.8 +- 0.2 eV and the binding energy of the Cu 2p/sub 3/2/ electron in the sludge under similar conditions was 937.2 +- 0.3 eV. These energies are characteristic of both Zn and Cu being in the positive two oxidation state. The electronegativity of the ligand attached to either of these metals was found to be 3.5 +- 0.1 on the Pauling scale. This indicates that Zn and Cu exist in similar compounds, that the ligand binding site is oxygen, and that the possible compounds include carbonate, carboxylate, phosphate, nitrate, silicate, and/or oxide. ESCA, when used in conjunction with other methods, offers excellent potential for more specifically identifying the chemical form of metal in sludge or sludge mixtures.

Lee E. Sommers

Papers

Total carbon organic carbon and organic matter

Total Carbon, Organic Carbon, and Organic Matter

Determination of Total Nitrogen in Plant Material1

Chemical Composition of Sewage Sludges and Analysis of Their Potential Use as Fertilizers

Determination of Total Phosphorus in Soils: A Rapid Perchloric Acid Digestion Procedure