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Author

Leila L. Y. Visconte

Other affiliations: Instituto Militar de Engenharia
Bio: Leila L. Y. Visconte is an academic researcher from Federal University of Rio de Janeiro. The author has contributed to research in topics: Natural rubber & Vulcanization. The author has an hindex of 21, co-authored 138 publications receiving 1526 citations. Previous affiliations of Leila L. Y. Visconte include Instituto Militar de Engenharia.


Papers
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Journal ArticleDOI
TL;DR: In this paper, two types of aluminum trihydrate (ATH), with or without surface treatment, and mica were incorporated into TPU composites to obtain good flame retardancy in TPU-mica composites.

87 citations

Journal ArticleDOI
TL;DR: In this article, a laboratory-sized two-roll mill was used to incorporate rice husk ash into natural rubber and a conventional vulcanization system was used for curing and cure studies were carried out on a rheometer.
Abstract: A laboratory-sized two-roll mill was used to incorporate rice husk ash into natural rubber (NR). A conventional vulcanization system was used for curing and cure studies were carried out on a Monsanto rheometer. Physical testing of the NR vulcanizates involved determining tensile and tear resistances and hardness. Swelling behavior of NR compounds and scanning electron microscopy were used to investigate the interaction between rice husk ash and natural rubber. Also, dynamical mechanical thermal analysis was used to assess filler–rubber interactions in terms of storage modulus (E′) and loss tangent (tan δ). For comparison purposes, two commercial fillers, precipitated silica (Zeosil-175) and carbon black (N774), were also used. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2331–2346, 2002

68 citations

Journal ArticleDOI
TL;DR: An overview of the life cycle assessment of poly(ethylene terephthalate) (PET) packaging can be found in this article, where the authors highlight the need to conduct LCA studies of PET, since many aspects are still not fully understood.
Abstract: Life cycle assessment (LCA) is a common technique to evaluate the environmental impact of poly(ethylene terephthalate) (PET) packaging. A review is needed to gain a clear view of the accumulated knowledge, scientific trends and what remains to be done. The main purpose of this paper is to present an overview of LCA of PET, mainly for packaging. LCA studies of PET consist largely of two segments: final destination of post-consumer PET, comparing recycling with other options (incineration, landfilling); and alternative materials, comparing PET with other polymers or materials such as glass and aluminum cans. In the first case, the scenarios most often compared have been landfill disposal and mechanical recycling. There has also been considerable research on the use of post-consumer PET for energy conversion and chemical recycling. In the second case, the main polymer compared with PET is poly(lactic acid), whose mechanical properties make it unsuitable for carbonated beverage bottles. Numerous articles have focused only on energy consumption or global warming potential. Few studies have discussed mechanical recycling technologies in LCA and there is a lack of data on the processes used in developing countries. This review highlights the need to conduct LCA studies of PET, since many aspects are still not fully understood.

58 citations

Journal ArticleDOI
TL;DR: In this article, two types of fillers were incorporated into thermoplastic polyurethane elastomers (TPU): mica and aluminum trihydrate (ATH).

58 citations

Journal ArticleDOI
TL;DR: In this paper, Rice husk ash was incorporated into natural rubber (NR) using a laboratory size two-roll mill, and Fourier transform infrared spectroscopy (FTIR) analysis was done to verify the presence of the characteristic functional groups of precipitated silica in MHA and THA.
Abstract: Rice husk ash was incorporated into natural rubber (NR) using a laboratory size two-roll mill. Curing using a conventional vulcanization system (CV) was chosen, and cure studies were carried out on a Monsanto rheometer. Physical testing of the NR vulcanizates involved the determination of tensile, tear, and abrasion resistances, and hardness. Fourier transform infrared spectroscopy (FTIR) analysis was done to verify the presence of the characteristic functional groups of precipitated silica in MHA (milled husk ash) and THA (treated husk ash). The effect of the coupling agent, bis(3-triethoxysilylpropyl)-tetrasulfane (Si-69), on the curing and physical properties of the vulcanizates was investigated. A chemical treatment on a rice husk ash was done, and the effects of this procedure are also reported. For comparison, two commercial fillers, precipitated silica (Zeosil-175) and carbon black (N774), were also used. Although the presence of the silane coupling agent had not brought the expected increase in properties, treated husk ash showed exceptional performance in terms of tensile strength and abrasion resistance of the filled vulcanizates. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 76: 1019–1027, 2000

53 citations


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Journal ArticleDOI
TL;DR: The thermal stability and flame retardancy of polyurethanes is reviewed in this article, where a detailed description of TGA, TGA-MS and TGAFTIR methods for studying the decomposition mechanism and kinetics is also provided.

1,329 citations

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TL;DR: The use of adhesion promoters, additives or chemical modification of the filler can help in overcoming many of these limitations as mentioned in this paper, such as worse processability and reduction of the ductility.
Abstract: The rising concern towards environmental issues and, on the other hand, the need for more versatile polymer-based materials has led to increasing interest about polymer composites filled with natural-organic fillers, i.e. fillers coming from renewable sources and biodegradable. The composites, usually referred to as “green”, can find several industrial applications. On the other hand, some problems exist, such as worse processability and reduction of the ductility. The use of adhesion promoters, additives or chemical modification of the filler can help in overcoming many of these limitations. These composites can be further environment-friendly when the polymer matrix is biodegradable and comes from renewable sources as well. This short review briefly illustrates the main paths and results of research (both academic and industrial) on this topical subject, providing a quick overview (with no pretence of exhaustiveness over such a vast topic), as well as appropriate references for further in-depth studies.

889 citations

Journal ArticleDOI
TL;DR: A review of natural fiber reinfocred composites focusing on natural fiber types and sources, processing methods, modification of fibers, matrices (petrochemical and renewable), and their mechanical performance is presented in this paper.
Abstract: This century has witnessed remarkable achievements in green technology in material science through the development of natural fiber reinforced composites. The development of high-performance engineering products made from natural resources is increasing worldwide day by day. There is increasing interest in materials demonstrating efficient use of renewable resources. Nowadays, more than ever, companies are faced with opportunities and choices in material innovations. Due to the challenges of petroleum-based products and the need to find renewable solutions, more and more companies are looking at natural fiber composite materials. The primary driving forces for new bio-composite materials are the cost of natural fibers (currently priced at one-third of the cost of glass fiber or less), weight reduction (these fibers are half the weight of glass fiber), recycling (natural fiber composites are easier to recycle) and the desire for green products. This Review provides an overview of natural fiber reinfocred composites focusing on natural fiber types and sources, processing methods, modification of fibers, matrices (petrochemical and renewable), and their mechanical performance. It also focuses on future research, recent developments and applications and concludes with key issues that need to be resolved. This article critically summarizes the essential findings of the mostly readily utilized reinforced natural fibers in polymeric composite materials and their performance from 2000 to 2013.

691 citations

01 Jan 1985

626 citations