The mineral zircon is extremely variable both in terms of external morphology and internal textures. These features reflect the geologic history of the mineral, especially the relevant episode(s) of magmatic or metamorphic crystallization (and recrystallization), strain imposed both by external forces and by internal volume expansion caused by metamictization, and chemical alteration. The paper presents a selection of both the most typical, but also of the less common, features seen in zircon, categorized according to the different geological processes responsible for their formation. The atlas is intended as a general guide for the interpretation of zircon characteristics, and of related isotopic data.

Zircon has become one of the most widely used minerals for the extraction of information on the prehistory and genesis of magmatic, metamorphic and sedimentary rocks. Much of the geological usefulness of zircon stems from its suitability as a geochronometer based on the decay of U (and Th) to Pb, but in addition it is also the major host of the radiogenic isotopic tracer Hf, and it is used to determine oxygen isotopic compositions and REE and other trace element abundances, all of which yield useful clues concerning the history of the host rock, and in some case, the parent rock in which the precursor zircon crystallized.

One of the major advantages of zircon is its ability to survive magmatic, metamorphic and erosional processes that destroy most other common minerals. Zircon-forming events tend to be preserved as distinct structural entities on a pre-existing zircon grain. Because of this ability, quite commonly zircon consists of distinct segments, each preserving a particular period of zircon-formation (or consumption). A long experience and modern instrumentation and techniques have provided the “zircon community” the means to image and interpret preserved textures, and hence to decipher the history and evolution of a rock. One …

Atlas of Zircon Textures

Geophysical, petrological, and geochemical data provide important clues about the composition of the deep continental crust. On the basis of seismic refraction data, we divide the crust into type sections associated with different tectonic provinces. Each shows a three-layer crust consisting of upper, middle, and lower crust, in which P wave velocities increase progressively with depth. There is large variation in average P wave velocity of the lower crust between different type sections, but in general, lower crustal velocities are high (>6.9 km s−1) and average middle crustal velocities range between 6.3 and 6.7 km s−1. Heat-producing elements decrease with depth in the crust owing to their depletion in felsic rocks caused by granulite facies metamorphism and an increase in the proportion of mafic rocks with depth. Studies of crustal cross sections show that in Archean regions, 50–85% of the heat flowing from the surface of the Earth is generated within the crust. Granulite terrains that experienced isobaric cooling are representative of middle or lower crust and have higher proportions of mafic rocks than do granulite terrains that experienced isothermal decompression. The latter are probably not representative of the deep crust but are merely upper crustal rocks that have been through an orogenic cycle. Granulite xenoliths provide some of the deepest samples of the continental crust and are composed largely of mafic rock types. Ultrasonic velocity measurements for a wide variety of deep crustal rocks provide a link between crustal velocity and lithology. Meta-igneous felsic, intermediate and mafic granulite, and amphibolite facies rocks are distinguishable on the basis of P and S wave velocities, but metamorphosed shales (metapelites) have velocities that overlap the complete velocity range displayed by the meta-igneous lithologies. The high heat production of metapelites, coupled with their generally limited volumetric extent in granulite terrains and xenoliths, suggests they constitute only a small proportion of the lower crust. Using average P wave velocities derived from the crustal type sections, the estimated areal extent of each type of crust, and the average compositions of different types of granulites, we estimate the average lower and middle crust composition. The lower crust is composed of rocks in the granulite facies and is lithologically heterogeneous. Its average composition is mafic, approaching that of a primitive mantle-derived basalt, but it may range to intermediate bulk compositions in some regions. The middle crust is composed of rocks in the amphibolite facies and is intermediate in bulk composition, containing significant K, Th, and U contents. Average continental crust is intermediate in composition and contains a significant proportion of the bulk silicate Earth's incompatible trace element budget (35–55% of Rb, Ba, K, Pb, Th, and U).

Nature and composition of the continental crust: A lower crustal perspective

Assembly, configuration, and break-up history of Rodinia: A synthesis

Trace element abundances in igneous zircons, as determined by electron microprobe and laser-ablation microprobe ICPMS analysis, are shown to be sensitive to source rock type and crystallisation environment. The concentrations of 26 trace elements have been determined for zircons from a wide range of different rock types and reveal distinctive elemental abundances and chondrite-normalised trace element patterns for specific rock types. There is a general trend of increasing trace element abundance in zircons from ultramafic through mafic to granitic rocks. The average content of REE is typically less than 50 ppm in kimberlitic zircons, up to 600–700 ppm in carbonatitic and lamproitic zircons and 2,000 ppm in zircons from mafic rocks, and can reach per cent levels in zircons from granitoids and pegmatites. Relatively flat chondrite-normalised REE patterns with chondrite-normalised Yb/Sm ratios from 3 to 30 characterise zircons from kimberlites and carbonatites, but Yb/Sm is commonly over 100 in zircons from pegmatites. Th/U ratios typically range from 0.1 to 1, but can be 100–1000 in zircons from some carbonatites and nepheline syenite pegmatites. The geochemical signatures characteristic of zircon from some rock types can be recognised in bivariate discriminant diagrams, but multivariate statistical analysis is essential for the discrimination of zircons from most rock types. Classification trees based on recursive partitioning techniques provide a rapid means of relating parent rock type to zircon trace element analysis; zircons from many rock types can be discriminated at confidence levels of 75% or more. These trees allow recognition of the provenance of detrital zircons from heavy mineral concentrates, and significantly enhance the usefulness of zircon in regional crustal studies and as an indicator mineral in mineral exploration.

Igneous zircon: trace element composition as an indicator of source rock type

Protolith zircon in high-grade metagranitoids from Queensland, Australia, partially recrystallized during granulite-grade metamorphism. We describe the zircon in detail using integrated cathodoluminescence, U–Pb isotope, trace element and electron backscatter diffraction pattern (EBSP) analyses. Primary igneous oscillatory zoning is partially modified or obliterated in areas within single crystals, but is well preserved in other areas. A variety of secondary internal structures are observed, with large areas of transgressive recrystallized zircon usually dominant. Associated with these areas are recrystallization margins, interpreted to be recrystallization fronts, that have conformable boundaries with transgressive recrystallized areas, but contrasting cathodoluminescence and trace element chemistry. Trace element analyses of primary and secondary structures provide compelling evidence for closed-system solid-state recrystallization. By this process, trace elements in the protolith zircon are purged during recrystallization and partitioned between the enriched recrystallization front and depleted recrystallized areas. However, recrystallization is not always efficient, often leaving a ‘memory’ of the protolith trace element and isotopic composition. This results in the measurement of ‘mixed’ U–Pb isotope ages. Nonetheless, the age of metamorphism has been determined. A correlation between apparent age and Th/U ratio is indicative of incomplete re-setting by partial recrystallization. Recrystallization is shown to probably not significantly affect Lu–Hf ages. Recrystallization has been determined by textural and trace element analysis and EBSP data not to have proceeded by sub-grain rotation or local dissolution/re-precipitation, but probably by grain-boundary migration and defect diffusion. The formation of metamorphic zircon by solid-state recrystallization is probably common to high-grade terranes worldwide. The recognition of this process of formation is essential for correct interpretation of zircon-derived U–Pb ages and subsequent tectonic models.

https://onlinelibrary.wiley.com/doi/pdf/10.1046/j.1525-1314.2000.00266.x

Metamorphic zircon formation by solid-state recrystallization of protolith igneous zircon

Diamond formation occurs in high-pressure conditions more than 150 kilometres deep in the Earth's mantle. The diamonds make it to the surface in vertical pipe-like structures made up of volcanic rocks called kimberlites. Several thousand such kimberlite pipes have been mapped so far, but research has focused on very old cratons, the areas of oldest continental crust, as this is where most economically viable diamonds are found. Trond Torsvik and colleagues use a plate-tectonic reconstruction for the past 540 million years to locate the positions of these cratons relative to the deep mantle at times when kimberlites were erupted. The kimberlites are shown to have been associated with the edges of large-scale heterogeneities in the deepest mantle, which the authors infer were zones at the core–mantle boundary where magma upwelling generated the mantle plumes that led to the formation of the kimberlites. These plumes may have controlled the distribution of almost all kimberlites that have erupted in the past 540 million years. Diamonds are formed under high pressure more than 150 kilometres deep in the Earth's mantle, and are brought to the surface mainly by volcanic rocks called kimberlites. Here, plate reconstructions and tomographic images have been used to show that the edges of the largest heterogeneities in the deepest mantle, stable for at least 200 million years and possibly for 540 million years, seem to have controlled the eruption of most Phanerozoic kimberlites. This has implications for future exploration for kimberlites. Diamonds are formed under high pressure more than 150 kilometres deep in the Earth’s mantle and are brought to the surface mainly by volcanic rocks called kimberlites. Several thousand kimberlites have been mapped on various scales1,2,3,4, but it is the distribution of kimberlites in the very old cratons (stable areas of the continental lithosphere that are more than 2.5 billion years old and 300 kilometres thick or more5) that have generated the most interest, because kimberlites from those areas are the major carriers of economically viable diamond resources. Kimberlites, which are themselves derived from depths of more than 150 kilometres, provide invaluable information on the composition of the deep subcontinental mantle lithosphere, and on melting and metasomatic processes at or near the interface with the underlying flowing mantle. Here we use plate reconstructions and tomographic images to show that the edges of the largest heterogeneities in the deepest mantle, stable for at least 200 million years and possibly for 540 million years, seem to have controlled the eruption of most Phanerozoic kimberlites. We infer that future exploration for kimberlites and their included diamonds should therefore be concentrated in continents with old cratons that once overlay these plume-generation zones at the core–mantle boundary.

/pdf/diamonds-sampled-by-plumes-from-the-core-mantle-boundary-32wwgoxaye.pdf

Diamonds sampled by plumes from the core–mantle boundary

Earth’s residual geoid is dominated by a degree-2 mode, with elevated regions above large low shear-wave velocity provinces on the core–mantle boundary beneath Africa and the Pacific. The edges of these deep mantle bodies, when projected radially to the Earth’s surface, correlate with the reconstructed positions of large igneous provinces and kimberlites since Pangea formed about 320 million years ago. Using this surface-to-core–mantle boundary correlation to locate continents in longitude and a novel iterative approach for defining a paleomagnetic reference frame corrected for true polar wander, we have developed a model for absolute plate motion back to earliest Paleozoic time (540 Ma). For the Paleozoic, we have identified six phases of slow, oscillatory true polar wander during which the Earth’s axis of minimum moment of inertia was similar to that of Mesozoic times. The rates of Paleozoic true polar wander (<1°/My) are compatible with those in the Mesozoic, but absolute plate velocities are, on average, twice as high. Our reconstructions generate geologically plausible scenarios, with large igneous provinces and kimberlites sourced from the margins of the large low shear-wave velocity provinces, as in Mesozoic and Cenozoic times. This absolute kinematic model suggests that a degree-2 convection mode within the Earth’s mantle may have operated throughout the entire Phanerozoic.

https://www.pnas.org/content/pnas/111/24/8735.full.pdf

Deep mantle structure as a reference frame for movements in and on the Earth

New U‐Pb zircon ages and Sm‐Nd and Rb‐Sr isotopic data are presented for orthogneisses from north‐central Madagascar, including Ile Sainte Marie, Alaotra‐Beforona, Maevatanana, and Ambatolampy‐Ambatomarina. A migmatite tonalite gneiss from Ile Sainte Marie is dated precisely at \documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \usepackage[OT2,OT1]{fontenc} \newcommand\cyr{ \renewcommand\rmdefault{wncyr} \renewcommand\sfdefault{wncyss} \renewcommand\encodingdefault{OT2} \normalfont \selectfont} \DeclareTextFontCommand{\textcyr}{\cyr} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} \landscape $3187\pm 2$ \end{document} Ma and has a Sm‐Nd model age (TDM) of 3204 Ma, thereby establishing a Middle Archean age for the oldest, juvenile gneisses in northeast Madagascar. Dated orthogneisses, int...

https://www.jstor.org/stable/10.1086/314337

U-Pb Geochronology and Isotope Geochemistry of the Archean and Proterozoic Rocks of North-Central Madagascar

compositions ( Nd 750 = +5·46 to −0·87; ISr 750 = 0·7021– The Seychelles islands consist of undeformed and unmetamorphosed, 0·7061) that can be modelled as basaltic magmas derived from metaluminous monzogranites and granodiorites of Neoproterozoic depleted mantle, variably contaminated (0–15%) by Archaean age (>750 Ma). Subsolvus, and lesser hypersolvus granitoids are silicic crust. All petrologic, petrographic, geochemical, isotopic and crosscut by coeval dolerite dykes, dominantly of olivine tholeiite chronologic data for Neoproterozoic magmatic rocks of the Seychelles, composition. Field relations suggest that mixing between granitoid coupled with palaeomagnetic data indicating its position at the and doleritic magmas generated a variety of minor intermediate margin of the Rodinia supercontinent at >750 Ma, are at least rocks that occur as irregular masses and enclaves; their compositions consistent with, if not suggestive of, a continental or Andean-type plot as linear arrays between those of dolerites and granitoids. Two arc setting. We argue, therefore, that the conventionally accepted groups of granitoids can be distinguished based on colour, chemistry notion of an extensional (i.e. rift or plume) setting for Seychelles and isotopic signature. Mahe Group granitoids are grey, with magmatism is vulnerable. relatively low incompatible element concentrations and primitive isotopic signatures that cluster at Nd 750 = +2·85 ± 0·17 and ISr 750 = 0·7031 ± 0·0008 (some samples with impossibly low ISr 180 ppm,

Petrogenesis of Neoproterozoic Granitoids and Related Rocks from the Seychelles: the Case for an Andean-type Arc Origin

Published geologic maps, regional geological relations, and new U-Pb ages for intrusive igneous rocks in west-central Madagascar define a 450-km-long belt of rocks emplaced in middle Neoproterozoic time. We report precise U-Pb zircon and baddeleyite ages for 11 coeval gabbro and granitoid plutons from the Itremo region, located in the southern part of this belt. The ages for all gabbroic and granitic plutons and deformed equivalents define an ∼25 m.y. period of magmatic activity between 804 and 779 Ma (at maximum uncertainty). Granitoids intrusive into the Quartzo-Schisto-Calcaire series provide a minimum depositional age of 791 Ma for this Mesoproterozoic platformal sedimentary sequence. Our results, combined with other recent U-Pb age determinations, define a belt of plutonic rocks in west-central Madagascar emplaced between 804 and 776 Ma. We propose that these middle Neoproterozoic rocks constitute the root of a continental magmatic arc emplaced at the time of, or slightly preceding, the breakup of the Rodinian supercontinent. Neoproterozoic plate reconstructions place Madagascar on the putative margin of Rodinia, and therefore the plutonic belt in west-central Madagascar provides important constraints on the timing and extent of middle Neoproterozoic tectonic events in Rodinia and the critical period of Rodinia9s transformation into Gondwana.

Lewis D. Ashwal

Papers

Diamonds sampled by plumes from the core–mantle boundary

Deep mantle structure as a reference frame for movements in and on the Earth

U-Pb Geochronology and Isotope Geochemistry of the Archean and Proterozoic Rocks of North-Central Madagascar

Petrogenesis of Neoproterozoic Granitoids and Related Rocks from the Seychelles: the Case for an Andean-type Arc Origin

Neoproterozoic continental arc magmatism in west-central Madagascar