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Lloyd C. Pray

Bio: Lloyd C. Pray is an academic researcher from University of Wisconsin-Madison. The author has contributed to research in topics: Diagenesis & Facies. The author has an hindex of 14, co-authored 23 publications receiving 1980 citations. Previous affiliations of Lloyd C. Pray include United States Geological Survey & Marathon Oil.

Papers
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Journal ArticleDOI
TL;DR: In this paper, the authors present a taxonomic classification of porosity in sedimentary carbonates, based on the time and place in which porosity is created or modified, which is important elements of a genetically oriented classification.
Abstract: Pore systems in sedimentary carbonates are generally complex in their geometry and genesis, and commonly differ markedly from those of sandstones. Current nomenclature and classifications appear inadequate for concise description or for interpretation of porosity in sedimentary carbonates. In this article we review current nomenclature, propose several new terms, and present a classification of porosity which stresses interrelations between porosity and other geologic features. The time and place in which porosity is created or modified are important elements of a genetically oriented classification. Three major geologic events in the history of a sedimentary carbonate form a practical basis for dating origin and modification of porosity, independent of the stage of lithification. These events are (1) creation of the sedimentary framework by clastic accumulation or accretionary precipitation (final deposition), (2) passage of a deposit below the zone of major influence by processes related to and operating from the deposition surface, and (3) passage of the sedimentary rock into the zone of influence by processes operating from an erosion surface (unconformity). The first event, final deposition, permits recognition of predepositional, depositional, and post epositional stages of porosity evolution. Cessation of final deposition is the most practical basis for distinguishing primary and secondary (postdepositional) porosity. Many of the key postdepositional changes in sedimentary carbonates and their pore systems occur near the surface, either very early in burial history or at a penultimate stage associated with uplift and erosion. Porosity created or modified at these times commonly can be differentiated. On the basis of the three major events heretofore distinguished, we propose to term the early burial stage "eogenetic," the late stage "telogenetic," and the normally very long intermediate stage "mesogenetic." These new terms are also applicable to process, zones of burial, or porosity formed in these times or zones (e.g., eogenetic ceme tation, mesogenetic zone, telogenetic porosity). The proposed classification is designed to aid in geologic description and interpretation of pore systems End_Page 207------------------------------ and their carbonate host rocks. It is a descriptive and genetic system in which 15 basic porosity types are recognized: seven abundant types (interparticle, intraparticle, intercrystal, moldic, fenestral, fracture, and vug), and eight more specialized types. Modifying terms are used to characterize genesis, size and shape, and abundance of porosity. The genetic modifiers involve (1) process of modification (solution, cementation, and internal sedimentation), (2) direction or stage of modification (enlarged, reduced, or filled), and (3) time of porosity formation (primary, secondary, predepositional, depositional, eogenetic, mesogenetic, and telogenetic). Used with the basic porosity type, these genetic modifiers permit explicit designation of porosity origin and evolution. Pore shapes are classed as irregular or regular, and the latter are subdivided into equant, tubular, and platy shapes. A grade scale for size of regular-shaped pores, utilizing the average diameter of equant or tubular pores and the width of platy pores, has three main classes: micropores (< 1/16 mm), mesopores (1/16-4 mm), and megapores (4-256 mm). Megapores and mesopores are divided further into small and large subclasses. Abundance is noted by percent volume and/or by ratios of porosity types. Most porosity in sedimentary carbonates can be related specifically to sedimentary or diagenetic components that constitute the texture or fabric (fabric-selective porosity). Some porosity cannot be related to these features. Fabric selectivity commonly distinguishes pore systems of primary and early postdepositional (eogenetic) origin from those of later (telogenetic) origin that normally form after extensive diagenesis has transformed the very porous assemblage of stable and unstable carbonate minerals into a much less porous aggregate of ordered dolomite and/or calcite. Porosity in most carbonate facies, including most carbonate petroleum reservoir rocks, is largely fabric selective.

1,452 citations

Journal ArticleDOI
TL;DR: In this paper, the authors show that allochthonous carbonate debris flow deposits containing large blocks occur locally in upper Perdrix and Mount Hawk basin strata adjacent to three Devonian reef complexes (Ancient Wall, Miette and Southesk-Cairn).
Abstract: Field work indicates that allochthonous carbonate debris flow deposits containing large blocks occur locally in upper Perdrix and Mount Hawk basin strata adjacent to three Devonian reef complexes -- Ancient Wall, Miette and Southesk-Cairn (Mount MacKenzie). The deposits are mostly pebble to boulder carbonate mudstone conglomerates and breccias with pervasive, dark, interstitial micrite. The largest of the deposits interpreted as debris flows occur southeast of Mount Haultain (Ancient Wall). Here, disoriented blocks (as large as 25 by 50m in cross-section) of shoal-water limestone occur in two sheet-like deposits of irregular thickness (up to 20 m); these deposits are exposed for more than a kilometre from the buildup margin. Similar, possibly correlative, deposits up to 12 m thick and containing disoriented blocks 10 m across occur three kilometers from the buildup margin. The allochthonous clasts are mostly limestone and vary from nonfossiliferous mudstones to grainstones rich in normal-marine fossils. Some clasts are coral growth frameworks several metres across. Finer debris commonly including abundant basin clasts occurs largely in sheets and in 6 The authors wish to acknowledge the substantial support provided by the Denver Research Center of the Marathon Oil Company; the National Research Council of Canada, Grant No. A2128 to Mountjoy; the Geological Survey of Canada, Grant No. 29-66 to Mountjoy; and McGill University. We are also pleased to acknowledge the very appreciable assistance received from our former co-workers and many colleagues in the gathering of data and formulating of ideas. Special thanks are extended to former and present Marathon Oil Company geologists who assisted in the field work: M. J. Brady, P. W. Chaquette, W. P. Gruman, W. A. Hogg, D. B. MacKenzie, W. J. Meyers, F. W. Rutledge, R. P. Steinen and J. L. Wray. J. L. Wray also identified the stromatoporoids, algae, and foraminifera. Discussions with J. C. Harms of the Marathon Oil Company, R. A. Bagnold and M. A. Hampton were helpful in clarifying ideas about the genesis of the debris flows. Mountjoy gratefully acknowledges the discussion and help received from C. W. Stearn and graduate students, J. Hopkins and P. Srivastava. Particularly helpful has been Hopkins' doctorate research concerning a detailed stratigraphic and petrographic investigation of the sediments adjacent to the Miette and Ancient Wall buildup margins. P. J. Coleman, P. E. Playford and F. Read have offered valuable perspective on parts of the manuscript. Manuscript assistance has been furnished by McGill University, the University of California (Riverside) and the University of Wisconsin (Madison). End_Page 439------------------------ some channels adjacent to buildup margins at all localities. A few debris deposits of both sheet and channel form have graded calcarenite-to-calcilutite tops a few cm thick. We believe these allochthonous materials were largely transported by submarine debris flows from upslope basin and buildup environments. The larger debris deposits may have formed when the relief and slope at the buildup margin was higher than normal, but relief in excess of 50 to 60 m over several kilometres or slopes as high as 10 degrees are unlikely; some deposits may be related to buildup margin unconformities. Allochthonous debris deposits containing large blocks may occur at other Devonian buildup margins in both surface and subsurface. Recognition of such deposits can assist in determining buildup proximity, in better interpretation of buildup and buildup margin genesis, in determining time of diagenesis -- particularly cementation and dolomitization, and in correlation. Presence of thick sheets of megabreccias interpreted as intraformational debris flows need not imply the high relief, active tectonism, or the steep slopes or scarps that are frequently envisioned for these deposits.

119 citations

BookDOI
01 Jan 1965
TL;DR: A symposium on the diagenesis of carbonate rocks was held in Toronto, Canada on May 20, 1964 at the joint meeting of AAPG and SEPM.
Abstract: In its broadest sense, diagenesis encompasses those natural changes which occur in sediments or sedimentary rocks between the time of initial deposition and the time — if ever — when the changes created by elevated temperature, or pressure, or by other conditions can be considered to have crossed the threshold into the realm of metamorphism. Deciphering the nature of diagenetic processes, and the time or times when they took place, is of critical importance for adequate geological interpretation. Papers in this volume were presented at a symposium on the diagenesis of carbonate rocks held in Toronto, Canada on May 20, 1964 at the joint meeting of AAPG and SEPM.

54 citations


Cited by
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Book
23 Apr 2007
TL;DR: In this article, the authors discuss the relationship between Karst and general geomorphology and Hydrogeology and discuss the development of Karst underground systems, and present a detailed analysis of these systems.
Abstract: CHAPTER 1. INTRODUCTION TO KARST. 1.1 Definitions. 1.2 The Relationship Between Karst And General Geomorphology And Hydrogeology. 1.3 The Global Distribution Of Karst. 1.4 The Growth Of Ideas. 1.5 Aims Of The Book. 1.6 Karst Terminology. CHAPTER 2. THE KARST ROCKS. 2.1 Carbonate Rocks And Minerals. 2.2 Limestone Compositions And Depositional Facies. 2.3 Limestone Diagenesis And The Formation Of Dolomite. 2.4 The Evaporite Rocks. 2.5. Quartzites And Siliceous Sandstones. 2.6 Effects Of Lithologic Properties Upon Karst Development. 2.7 Interbedded Clastic Rocks. 2.8 Bedding Planes, Joints, Faults And Fracture Traces. 2.9 Fold Topography. 2.10 Paleokarst Unconformities. CHAPTER 3. DISSOLUTION: CHEMICAL AND KINETIC BEHAVIOUR OF THE KARST ROCKS. 3.1 Introduction. 3.2 Aqueous Solutions And Chemical Equilibria. 3.3 The Dissolution Of Anhydrite, Gypsum And Salt. 3.4 The Dissolution Of Silica. 3.5 Bicarbonate Equilibria And The Dissolution Of Carbonate Rocks In Normal Meteoric Waters. 3.6 The S-O-H System And The Dissolution Of Carbonate Rocks. 3.7 Chemical Complications In Carbonate Dissolution. 3.8 Biokarst Processes. 3.9 Measurements In The Field And Lab Computer Programs. 3.10 Dissolution And Precipitation Kinetics Of Karst Rocks. CHAPTER 4. DISTRIBUTION AND RATE OF KARST DENUDATION. 4.1 Global Variations In The Solutional Denudation Of Carbonate Terrains. 4.2 Measurement And Calculation Of Solutional Denudation Rates. 4.3 Solution Rates In Gypsum, Salt And Other Non-Carbonate Rocks. 4.4 Interpretation Of Measurements. CHAPTER 5. KARST HYDROLOGY. 5.1 Basic Hydrological Concepts, Terms And Definitions. 5.2 Controls On The Development Of Karst Hydrologic Systems. 5.3 Energy Supply And Flow Network Development. 5.4 Development Of The Water Table And Phreatic Zones. 5.5 Development Of The Vadose Zone. 5.6 Classification And Characteristics Of Karst Aquifers. 5.7 Applicability Of Darcy's Law To Karst. 5.8 The Fresh Water/Salt Water Interface. CHAPTER 6. ANALYSIS OF KARST DRAINAGE SYSTEMS. 6.1 The 'Grey Box' Nature Of Karst. 6.2 Surface Exploration And Survey Techniques. 6.3 Investigating Recharge And Percolation In The Vadose Zone. 6.4 Borehole Analysis. 6.5 Spring Hydrograph Analysis. 6.6 Polje Hydrograph Analysis. 6.7 Spring Chemograph Interpretation. 6.8 Storage Volumes And Flow Routing Under Different States Of The Hydrograph. 6.9 Interpreting The Organisation Of A Karst Aquifer. 6.10 Water Tracing Techniques. 6.11 Computer Modelling Of Karst Aquifers. CHAPTER 7. SPELEOGENESIS: THE DEVELOPMENT OF CAVE SYSTEMS. 7.1 Classifying Cave Systems. 7.2 Building The Plan Patterns Of Unconfined Caves. 7.3 Unconfined Cave Development In Length And Depth. 7.4 System Modifications Occurring Within A Single Phase. 7.5 Multi-Phase Cave Systems. 7.6 Meteoric Water Caves Developed Where There Is Confined Circulation Or Basal Injection Of Water. 7.7 Hypogene Caves: (A) Hydrothermal Caves Associated Chiefly With Co2. 7.8 Hypogene Caves: (B) Caves Formed By Waters Containing H2s. 7.9 Sea Coast Eogenetic Caves. 7.10 Passage Cross-Sections And Smaller Features Of Erosional Morphology. 7.11 Condensation, Condensation Corrosion, And Weathering In Caves. 7.12 Breakdown In Caves. CHAPTER 8. CAVE INTERIOR DEPOSITS. 8.1 Introduction. 8.2 Clastic Sediments. 8.3 Calcite, Aragonite And Other Carbonate Precipitates. 8.4 Other Cave Minerals. 8.5 Ice In Caves. 8.6 Dating Of Calcite Speleothems And Other Cave Deposits. 8.7 Paleo-Environmental Analysis Of Calcite Speleothems. 8.8 Mass Flux Through A Cave System: The Example Of Friar's Hole, W.Va. CHAPTER 9. KARST LANDFORM DEVELOPMENT IN HUMID REGIONS. 9.1 Coupled Hydrological And Geochemical Systems. 9.2 Small Scale Solution Sculpture - Microkarren And Karren. 9.3 Dolines - The 'Diagnostic' Karst Landform? 9.4 The Origin And Development Of Solution Dolines. 9.5 The Origin Of Collapse And Subsidence Depressions. 9.6 Polygonal Karst. 9.7 Morphometric Analysis Of Solution Dolines. 9.8 Landforms Associated With Allogenic Inputs. 9.9 Karst Poljes. 9.10 Corrosional Plains And Shifts In Baselevel. 9.11 Residual Hills On Karst Plains. 9.12 Depositional And Constructional Karst Features. 9.13 Special Features Of Evaporite Terrains. 9.14 Karstic Features Of Quartzose And Other Rocks. 9.15 Sequences Of Carbonate Karst Evolution In Humid Terrains. CHAPTER 10.THE INFLUENCE OF CLIMATE, CLIMATIC CHANGE AND OTHER ENVIRONMENTAL FACTORS ON KARST DEVELOPMENT. 10.1 The Precepts Of Climatic Geomorphology. 10.2 The Hot Arid Extreme. 10.3 The Cold Extreme: 1 Karst Development In Glaciated Terrains. 10.4 The Cold Extreme: 2 Karst Development In Permafrozen Terrains. 10.5 Sea Level Changes, Tectonic Movement And Implications For Coastal Karst Development. 10.6 Polycyclic, Polygenetic And Exhumed Karsts. CHAPTER 11. KARST WATER RESOURCES MANAGEMENT. 11.1 Water Resources And Sustainable Yields. 11.2 Determination Of Available Water Resources. 11.3 Karst Hydrogeological Mapping. 11.4 Human Impacts On Karst Water. 11.5 Groundwater Vulnerability, Protection, And Risk Mapping. 11.6 Dam Building, Leakages, Failures And Impacts. CHAPTER 12. HUMAN IMPACTS AND ENVIRONMENTAL REHABILITATION. 12.1 The Inherent Vulnerability Of Karst Systems. 12.2 Deforestation, Agricultural Impacts And Rocky Desertification. 12.3 Sinkholes Induced By De-Watering, Surcharging, Solution Mining And Other Practices On Karst. 12.4 Problems Of Construction On And In The Karst Rocks - Expect The Unexpected! 12.5 Industrial Exploitation Of Karst Rocks And Minerals. 12.6 Restoration Of Karstlands And Rehabilitation Of Limestone Quarries. 12.7 Sustainable Management Of Karst. 12.8 Scientific, Cultural And Recreational Values Of Karstlands.

2,108 citations

Journal ArticleDOI
TL;DR: In this paper, a pore classification consisting of three major matrix-related pore types is presented that can be used to quantify matrix related pore and relate them to pore networks.
Abstract: Matrix-related pore networks in mudrocks are composed of nanometer- to micrometer-size pores. In shale-gas systems, these pores, along with natural fractures, form the flow-path (permeability) network that allows flow of gas from the mudrock to induced fractures during production. A pore classification consisting of three major matrix-related pore types is presented that can be used to quantify matrix-related pores and relate them to pore networks. Two pore types are associated with the mineral matrix; the third pore type is associated with organic matter (OM). Fracture pores are not controlled by individual matrix particles and are not part of this classification. Pores associated with mineral particles can be subdivided into interparticle (interP) pores that are found between particles and crystals and intraparticle (intraP) pores that are located within particles. Organic-matter pores are intraP pores located within OM. Interparticle mineral pores have a higher probability of being part of an effective pore network than intraP mineral pores because they are more likely to be interconnected. Although they are intraP, OM pores are also likely to be part of an interconnected network because of the interconnectivity of OM particles. In unlithifed near-surface muds, pores consist of interP and intraP pores, and as the muds are buried, they compact and lithify. During the compaction process, a large number of interP and intraP pores are destroyed, especially in ductile grain-rich muds. Compaction can decrease the pore volume up to 88% by several kilometers of burial. At the onset of hydrocarbon thermal maturation, OM pores are created in kerogen. At depth, dissolution of chemically unstable particles can create additional moldic intraP pores.

1,895 citations

Journal ArticleDOI
TL;DR: In this paper, the authors present a taxonomic classification of porosity in sedimentary carbonates, based on the time and place in which porosity is created or modified, which is important elements of a genetically oriented classification.
Abstract: Pore systems in sedimentary carbonates are generally complex in their geometry and genesis, and commonly differ markedly from those of sandstones. Current nomenclature and classifications appear inadequate for concise description or for interpretation of porosity in sedimentary carbonates. In this article we review current nomenclature, propose several new terms, and present a classification of porosity which stresses interrelations between porosity and other geologic features. The time and place in which porosity is created or modified are important elements of a genetically oriented classification. Three major geologic events in the history of a sedimentary carbonate form a practical basis for dating origin and modification of porosity, independent of the stage of lithification. These events are (1) creation of the sedimentary framework by clastic accumulation or accretionary precipitation (final deposition), (2) passage of a deposit below the zone of major influence by processes related to and operating from the deposition surface, and (3) passage of the sedimentary rock into the zone of influence by processes operating from an erosion surface (unconformity). The first event, final deposition, permits recognition of predepositional, depositional, and post epositional stages of porosity evolution. Cessation of final deposition is the most practical basis for distinguishing primary and secondary (postdepositional) porosity. Many of the key postdepositional changes in sedimentary carbonates and their pore systems occur near the surface, either very early in burial history or at a penultimate stage associated with uplift and erosion. Porosity created or modified at these times commonly can be differentiated. On the basis of the three major events heretofore distinguished, we propose to term the early burial stage "eogenetic," the late stage "telogenetic," and the normally very long intermediate stage "mesogenetic." These new terms are also applicable to process, zones of burial, or porosity formed in these times or zones (e.g., eogenetic ceme tation, mesogenetic zone, telogenetic porosity). The proposed classification is designed to aid in geologic description and interpretation of pore systems End_Page 207------------------------------ and their carbonate host rocks. It is a descriptive and genetic system in which 15 basic porosity types are recognized: seven abundant types (interparticle, intraparticle, intercrystal, moldic, fenestral, fracture, and vug), and eight more specialized types. Modifying terms are used to characterize genesis, size and shape, and abundance of porosity. The genetic modifiers involve (1) process of modification (solution, cementation, and internal sedimentation), (2) direction or stage of modification (enlarged, reduced, or filled), and (3) time of porosity formation (primary, secondary, predepositional, depositional, eogenetic, mesogenetic, and telogenetic). Used with the basic porosity type, these genetic modifiers permit explicit designation of porosity origin and evolution. Pore shapes are classed as irregular or regular, and the latter are subdivided into equant, tubular, and platy shapes. A grade scale for size of regular-shaped pores, utilizing the average diameter of equant or tubular pores and the width of platy pores, has three main classes: micropores (< 1/16 mm), mesopores (1/16-4 mm), and megapores (4-256 mm). Megapores and mesopores are divided further into small and large subclasses. Abundance is noted by percent volume and/or by ratios of porosity types. Most porosity in sedimentary carbonates can be related specifically to sedimentary or diagenetic components that constitute the texture or fabric (fabric-selective porosity). Some porosity cannot be related to these features. Fabric selectivity commonly distinguishes pore systems of primary and early postdepositional (eogenetic) origin from those of later (telogenetic) origin that normally form after extensive diagenesis has transformed the very porous assemblage of stable and unstable carbonate minerals into a much less porous aggregate of ordered dolomite and/or calcite. Porosity in most carbonate facies, including most carbonate petroleum reservoir rocks, is largely fabric selective.

1,452 citations

Journal ArticleDOI
TL;DR: Dolomite is not a simple mineral; it can form as a primary precipitate, a diagenetic replacement, or as a hydrothermal/metamorphic phase, all that it requires is permeability, a mechanism that facilitates fluid flow, and a sufficient supply of magnesium.

1,095 citations