Author
M. Padmanabhan
Bio: M. Padmanabhan is an academic researcher from Indian Institute of Technology Madras. The author has contributed to research in topics: Thiazolidine & Zinc. The author has an hindex of 1, co-authored 1 publications receiving 6 citations.
Topics: Thiazolidine, Zinc, Cadmium, Mercury (element)
Papers
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TL;DR: In this article, the infrared spectral studies suggest that silver and zinc derivatives are N-bonded, cadmium complex is S-Bonded and mercury derivatives are both N- and S-bunded.
6 citations
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TL;DR: In this paper, the perchlorate ion complexes have been studied and the metal-perchlorate bond has been termed as "semicoordination" and has been shown to be weak.
Abstract: Publisher Summary This chapter discusses the perchlorate ion complexes. Coordination of perchlorate to transition and nontransition metal ions has been well established, though in most of the cases the metal-perchlorate bond is rather weak and has been termed as “semicoordination”. The highly symmetrical perchlorate ion is a hard base and falls into the category of relatively nonpolarizable and noncoordinating anions such as BF 4 ˉ and PF 6 ˉ. Its ability to coordinate strongly to soft metal ions is therefore limited. When coordination does occur, the perchlorate group may be linked to a metal ion in a monodentate and/or bidentate manner through oxygen atoms; the latter linkage can be either chelating. X-ray crystal structure analysis has unequivocally established coordination of perchlorate in a number of perchlorate complexes.
71 citations
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TL;DR: In this paper, the infrared spectra of the solid complexes and of 1H nuclear magnetic resonance spectra were compared, and it was shown that 2J(1H199Hg) indicates bonding to sulfur only.
11 citations
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TL;DR: Palladium(II) and platinum (II) halides with 3,6-disubstituted 2,7-dihydro-1,4,5-thiadiazepine derivatives (L) form complexes of general formula as discussed by the authors.
6 citations
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TL;DR: In this article, Ubersicht uber Strukturen und Spektren von festen Quecksilberhalogeniden und ihren Solvaten is presented, together with solvaten.
Abstract: Review: Ubersicht uber Strukturen und Spektren von festen Quecksilberhalogeniden und ihren Solvaten.
6 citations