M. Pilar Carranza

TL;DR: New coordination polymers have been obtained by the self-assembly of silver salts AgX and 2,4-diamino-6-R-1,3,5-triazines L of formulas AgLX and a new species has been detected at low temperatures, and this exhibits restricted rotation of the phenyl ring.

TL;DR: The synthesis of octahedral copper and zinc coordination complexes containing ligands of the type 6R,2,4-bis(3,5-dimethylpyrazol-1-yl)triazine is described and synergistic effects are present when both interactions coexist.

TL;DR: The cytotoxicity of 1 and the potential of 5 in PDT make them good candidates for subsequent conjugation, through the carboxyl group, to "selected peptides" which could facilitate the selective vectorization of the complex toward receptors that are overexpressed in neoplastic cell lines.

TL;DR: Several complexes with a [2 × 2] grid structure have been obtained by the self-assembly of different copper(I) salts and ligands of the type 4,6-bis(pyrazol-1-yl)pyrimidine containing different substituents on the heterocycles to evaluate the influence over the solid state and solution behavior of the functionalization of the pyrimidine ring with a primary amino substituent.

TL;DR: The synthesis of several silver double helices containing bis(3,5dimethylpyrazolyl)-6-(R)-s-triazine ligands is described, and both derivatives represent the first reported examples of a new interaction mode for a triazine ring that involves a Triazine N atom bridging two metal centers.