M
Malcolm L. H. Green
Researcher at University of Oxford
Publications - 800
Citations - 32440
Malcolm L. H. Green is an academic researcher from University of Oxford. The author has contributed to research in topics: Carbon nanotube & Cyclopentadienyl complex. The author has an hindex of 82, co-authored 800 publications receiving 31121 citations. Previous affiliations of Malcolm L. H. Green include Gas Technology Institute & University of Illinois at Urbana–Champaign.
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Journal ArticleDOI
Cycloheptatri-ene and -enyl derivatives of niobium
Malcolm L. H. Green,Andrew K. Hughes,Patrick C. McGowan,Philip Mountford,Peter Scott,Stephen J. Simpson +5 more
TL;DR: The 17-electron compound [Nb(η6-C7H8)(PMe3)2Cl2] as mentioned in this paper contains mutually trans tertiary phosphine and chloro ligands, and the first crystallographically characterised η4-cycloheptatriene ligand, which is discussed in relation to its 13C NMR spectrum and the use of inverse-mode (1H-observed)13C-1H shift correlation NMR spectroscopy.
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π-7e-Cycloheptatrienyl molybdenum chemistry: a versatile preparative route
TL;DR: In this paper, the preparation and reactions of π-cycloheptatrienyl derivatives of molybdenum are described, and a number of them are discussed.
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Synthesis and molecular structures of the sandwich anion [K(18-crown-6)][Nb(η-C7H7)(η-C5H5)] and cation [Nb(η-C7H7)(η-C5H4Me)(thf)]PF6
TL;DR: The 17-electron compounds Nb(η-C7H7)(η -C5H4R) undergo reversible oneelectron oxidation and reduction, giving the structurally characterised compounds [Nb(nb(c7h7),c5h4Me)(thf)]PF6 and [K(18crown-6)], respectively; the latter has an unusual distorted chain structure as discussed by the authors.
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Cycloheptatrienyl molybdenum chemistry
TL;DR: In this article, the new sandwich complexes (π-C 7 H 7 )Mo(π-arene) + [PF 6 ] − readily undergo reactions in which the arene ligand is displaced and, hence, provide a route into cycloheptatrienyl molybdenum chemistry which does not involve carbonyl ligands.
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The reaction of [W(PMe3)4(η2-CH2PMe2)H] with carbon dioxide and dihydrogen: characterisation of [{W(PMe3)3(η1-PMe2CH2)}2(C3H2O6)] using two-dimensional nuclear magnetic resonance spectroscopy
TL;DR: In this article, a mixture of CO 2 and H 2 (1/1, 3 atm) at room temperature was used to characterise two-dimensional homo- and hetero-nuclear correlation NMR techniques.