Author
Malcolm L. H. Green
Other affiliations: Gas Technology Institute, University of Illinois at Urbana–Champaign, British Gas plc ...read more
Bio: Malcolm L. H. Green is an academic researcher from University of Oxford. The author has contributed to research in topics: Carbon nanotube & Cyclopentadienyl complex. The author has an hindex of 82, co-authored 800 publications receiving 31121 citations. Previous affiliations of Malcolm L. H. Green include Gas Technology Institute & University of Illinois at Urbana–Champaign.
Papers published on a yearly basis
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TL;DR: Tungsten atoms react with spiro[2.4]hepta-4,6-diene giving [[graphic omitted]H2]2] as discussed by the authors, which undergoes hydride abstraction with Ph3C+ giving the cation [W(η5:η2: η5-C5H4CH2CHCH2C2H4)H]+(3); complex (1) react with PhlCl2 to give [W
Abstract: Tungsten atoms react with spiro[2.4]hepta-4,6-diene giving [[graphic omitted]H2)2](1) which undergoes hydride abstraction with Ph3C+ giving the cation [W(η5:η2:η5-C5H4CH2CHCHCH2C2H4)H]+(3); complex (1) react with PhlCl2 to give [W(η-C5H4CH2CH2Cl)2Cl2], (9), which is reduced back to (1) with sodium amalgam; the compounds [[graphic omitted]H2)(η-C5H4Et)I], (6) undergoes reversible 1,2-hydrogen shift reactions when treated with tertiary phosphines.
3 citations
TL;DR: In this article, superconducting alkali metal fullerides can be synthesized in less than 60 s reaction time using a microwave-induced argon plasma; the rapid synthesis of K3C60 is described.
Abstract: Superconducting alkali metal fullerides can be synthesized in less than 60 s reaction time using a microwave-induced argon plasma; the rapid synthesis of K3C60 is described.
3 citations
TL;DR: The molecular structures of the dimeric cobalt compounds [Co(PPhMe 2 )(CO) 3 ] 2 and [Co 2 (PPhme 2 ) 3 (CO) 5 ] have been characterised by X-ray crystallography.
3 citations
TL;DR: The new compounds [Mo(η-C5H5)(dmpe)Cl3], this paper, Mo( Δ-C 5H5)2(DMpe)][PF6] have been prepared and characterised by i.m.r., 1H n.m., and mass spectra.
Abstract: The new compounds [Mo(η-C5H5)(dmpe)Cl3], [Mo(η-C5H5)(dmpe)H3], [Mo(η-C5H5)(dmpe)H4][PF6], [Mo(η-C5H5)(dmpe)O][PF6], [Mo(η-C5H5)(dmpe)(PhCCPh)][PF6], [Mo(η-C5H5)(dmpe)(MeCCMe)]-[PF6], and [Mo(η-C5H5)2(dmpe)][PF6][dmpe = 1,2-bis(dimethylphosphino)ethane] have been prepared and characterised by i.r., 1H n.m.r., and mass spectra.
3 citations
TL;DR: In this paper, the formation of aromatics during the reaction between methane and oxygen between 970 and 1220K, at elevated pressure has been studied, and high selectivities and yields of the aromatics, i.e. benzene and toluene, are obtained over certain oxide catalysts, although, aromatics are also formed when no catalyst is present.
Abstract: The formation of aromatics during the reaction between methane and oxygen between 970 and 1220K, at elevated pressure has been studied. High selectivities and yields of the aromatics, i. e. benzene and toluene, are obtained over certain oxide catalysts, although, aromatics are also formed when no catalyst is present. A manganese oxide catalyst doped with sodium chloride gave the highest yield of aromatics, however, supported nickel or platinum catalysts, which have been reported to be active catalysts for aromatics formation, were found to give lower yields of aromatics than for the gas-phase reaction. The mechanism for the production of aromatics has been investigated.
3 citations
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TL;DR: In this article, the authors reported the synthesis of abundant single-shell tubes with diameters of about one nanometre, whereas the multi-shell nanotubes are formed on the carbon cathode.
Abstract: CARBON nanotubes1 are expected to have a wide variety of interesting properties. Capillarity in open tubes has already been demonstrated2–5, while predictions regarding their electronic structure6–8 and mechanical strength9 remain to be tested. To examine the properties of these structures, one needs tubes with well defined morphologies, length, thickness and a number of concentric shells; but the normal carbon-arc synthesis10,11 yields a range of tube types. In particular, most calculations have been concerned with single-shell tubes, whereas the carbon-arc synthesis produces almost entirely multi-shell tubes. Here we report the synthesis of abundant single-shell tubes with diameters of about one nanometre. Whereas the multi-shell nanotubes are formed on the carbon cathode, these single-shell tubes grow in the gas phase. Electron diffraction from a single tube allows us to confirm the helical arrangement of carbon hexagons deduced previously for multi-shell tubes1.
8,018 citations
TL;DR: The interest in nanoscale materials stems from the fact that new properties are acquired at this length scale and, equally important, that these properties are equally important.
Abstract: The interest in nanoscale materials stems from the fact that new properties are acquired at this length scale and, equally important, that these properties * To whom correspondence should be addressed. Phone, 404-8940292; fax, 404-894-0294; e-mail, mostafa.el-sayed@ chemistry.gatech.edu. † Case Western Reserve UniversitysMillis 2258. ‡ Phone, 216-368-5918; fax, 216-368-3006; e-mail, burda@case.edu. § Georgia Institute of Technology. 1025 Chem. Rev. 2005, 105, 1025−1102
6,852 citations
TL;DR: Although not yet providing compelling mechanical strength or electrical or thermal conductivities for many applications, CNT yarns and sheets already have promising performance for applications including supercapacitors, actuators, and lightweight electromagnetic shields.
Abstract: Worldwide commercial interest in carbon nanotubes (CNTs) is reflected in a production capacity that presently exceeds several thousand tons per year. Currently, bulk CNT powders are incorporated in diverse commercial products ranging from rechargeable batteries, automotive parts, and sporting goods to boat hulls and water filters. Advances in CNT synthesis, purification, and chemical modification are enabling integration of CNTs in thin-film electronics and large-area coatings. Although not yet providing compelling mechanical strength or electrical or thermal conductivities for many applications, CNT yarns and sheets already have promising performance for applications including supercapacitors, actuators, and lightweight electromagnetic shields.
4,596 citations
TL;DR: The features of nanoparticle therapeutics that distinguish them from previous anticancer therapies are highlighted, and how these features provide the potential for therapeutic effects that are not achievable with other modalities are described.
Abstract: Nanoparticles — particles in the size range 1–100 nm — are emerging as a class of therapeutics for cancer. Early clinical results suggest that nanoparticle therapeutics can
show enhanced efficacy, while simultaneously reducing side effects, owing to properties such as more targeted localization in tumours and active cellular uptake. Here, we
highlight the features of nanoparticle therapeutics that distinguish them from previous anticancer therapies, and describe how these features provide the potential for
therapeutic effects that are not achievable with other modalities. While large numbers of preclinical studies have been published, the emphasis here is placed on preclinical and clinical studies that are likely to affect clinical investigations and their implications for advancing the treatment of patients with cancer.
3,975 citations
TL;DR: Department of Materials Science, University of Patras, Greece, Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, and Dipartimento di Scienze Farmaceutiche, Universita di Trieste, Piazzale Europa 1, 34127 Triesteadays.
Abstract: Department of Materials Science, University of Patras, 26504 Rio Patras, Greece, Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Avenue, 116 35 Athens, Greece, Institut de Biologie Moleculaire et Cellulaire, UPR9021 CNRS, Immunologie et Chimie Therapeutiques, 67084 Strasbourg, France, and Dipartimento di Scienze Farmaceutiche, Universita di Trieste, Piazzale Europa 1, 34127 Trieste, Italy
3,886 citations