M
Marc Decoster
Researcher at University of Western Brittany
Publications - 8
Citations - 185
Marc Decoster is an academic researcher from University of Western Brittany. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 7, co-authored 8 publications receiving 184 citations.
Papers
More filters
Journal ArticleDOI
Novel Infinite Three-Dimensional Networks with Highly Conjugated Polynitrile Ligands: Syntheses, Crystal Structures, and Magnetic Properties of [Cu{C[C(CN)2]3}(H2O)2]n and [Cu{C[C(CN)2]3}(en)]n (en=NH2CH2CH2NH2)
TL;DR: An unprecedented coordination mode for the highly conjugated cyanocarbanion [C{C(CN)2}3]2− (1) is observed in the title complexes.
Journal ArticleDOI
Comparison of the properties of the 1,1,2,4,5,5-hexacyano-3-aza-penta-1,4-dienide[(NC)2CC(CN)NC(CN)C(CN)2] unit as anion and as ligand. Crystal structures of (Et4N)(C10N7) and [{Ag(C10N7)}∞]
TL;DR: In this article, the C 10 N 7 unit was shown to have a planar geometry with central CN bond lengths of 1.317(4) and 1.334(4), 1.33(1) A in 1, 1.34(1), 1, 1.3(3), and 128.2(9)° in 2.
Journal ArticleDOI
Radical cation-radical anion salts: Molybdenum complexes containing the [TCNQ]•− or [TCNE]•− radical anions. X-ray crystal structure of [Mo(Et2NCS2)4](TCNQ)
Marc Decoster,Françoise Conan,Jacques E. Guerchais,Y. Le Mest,J. Sala Pala,John C. Jeffery,Eric Faulques,A. Leblanc,P. Molinie +8 more
TL;DR: In this article, cyclic voltammetry and ESR studies revealed the presence for all types of complexes of the molybdenum(V) radical cation [Mo(dtc) 4 ] •− which is associated with the radical anion TCNX •− in 2 (X = Q) and 4(X = E) and with a 1:1 mixture of neutral and anionic TCNQ species in 3.
Journal ArticleDOI
Determination of charge transfer in molybdenum complexes of 7,7,8,8-tetracyano-p-quinodimethane with vibrational spectroscopy
Eric Faulques,A. Leblanc,P. Molinie,Marc Decoster,Françoise Conan,Jacques E. Guerchais,Jean Sala-Pala +6 more
TL;DR: In this article, the influence of charge transfer on the vibrational lines of three molybdenum TCNQ complexes [MoO(dtc)3](TCNQ) 1a, [Mo O(t2NCS2) 2a, and [Mo(ttc)4](tccnQ)2 3a) is reported.
Journal ArticleDOI
Monomer, Dimer, and Tetramer States in Molybdenum Complexes of Tetracyanoquinodimethane
TL;DR: In this article, the determination of monomers, dimers, and alternating states of tetracyanoquinodimethane (TCNQ) species in molybdenum complexes using optical absorption and Raman spectroscopy is reported.