Author
Mark S. Falcone
Bio: Mark S. Falcone is an academic researcher from University of Washington. The author has contributed to research in topics: Sesquiterpene & Gas chromatography. The author has an hindex of 3, co-authored 3 publications receiving 130 citations.
Papers
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TL;DR: In this article, the identification of sesquiterpenes by gas-liquid chromatography was evaluated, and the most reproducible form of GLC data was found to be the SESQUERPene data.
100 citations
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27 citations
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TL;DR: In this paper, the composition of the sesquiterpene portions of ginger oil, cade oil, celery seed oil, vetiver oil, technical guaiene, and the leaf oil of Chamaecyparis nootkatensis has been studied by small-scale dehydrogenation coupled with GLC analysis.
4 citations
Cited by
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TL;DR: In this article, some 900 Kovats' indices of 400 individual compounds on methyl silicone (dimethyl polysiloxane) and/or Carbowax 20M liquid phases are summarized from the general literature.
2,118 citations
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TL;DR: This method was exemplified by the first highly efficient total synthesis of natural product (-)-hinesol, which is an active ingredient of cerebral circulation and metabolism improvers.
Abstract: In one step, the skeleton of cis-spirovetivanes was constructed with high stereoselectivity by the phosphine-catalyzed [3+2] cycloaddition reaction of tert-butyl 2,3-butadienoate or 2-butynoate with 3-methyl-2-methylenecyclohexanone (5). This method was exemplified by the first highly efficient total synthesis of natural product (-)-hinesol, which is an active ingredient of cerebral circulation and metabolism improvers.
155 citations
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01 Nov 1979TL;DR: Gas chromatography (G C) proved to be the method by which to show that the earthy odor was caused by a single chemical substance which was named geosmin, and to demonstrate the presence ofGeosmin in many actinomycete fermentation broths and isolate enough for structure determination.
Abstract: (1979). Volatile Substances from Actinomycetes: Their Role in the Odor Pollution of Water. CRC Critical Reviews in Microbiology: Vol. 7, No. 3, pp. 191-214.
147 citations
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TL;DR: The spiro motif is finding increasing inclusion in drug candidates, and as a structural component in several promising classes of chiral ligands used in asymmetric synthesis, which is examined in this review.
Abstract: The structures of natural products from a variety of sources contain spirocycles, two rings that share a common atom. The spiro motif is finding increasing inclusion in drug candidates, and as a structural component in several promising classes of chiral ligands used in asymmetric synthesis. Total syntheses of products containing all-carbon spirocycles feature several common methods of ring closure which we examine in this review.
140 citations