Mark W. Benecke

Bio: Mark W. Benecke is an academic researcher. The author has contributed to research in topics: Water content & Sorbent. The author has an hindex of 2, co-authored 2 publications receiving 27 citations.

Field-Scale Assessment of Desiccation Implementation for Deep Vadose Zone Contaminants

Abstract: Desiccation of the vadose zone has the potential to reduce the flux of contaminants to underlying groundwater by removing moisture and decreasing the aqueous-phase permeability of the desiccated zone. However, data to evaluate implementation of desiccation are needed to enable consideration of desiccation as a potential remedy. Implementation of desiccation was field tested by injecting dry nitrogen gas to a target treatment zone and monitoring the spatial and temporal progress of the drying process. Aqueous waste discharges to disposal cribs approximately 50 years ago distributed water and contaminants, including primarily technetium-99 and nitrate, within the 100-m deep vadose zone at the test site. A field test location was selected adjacent to one of the former disposal cribs. The test was conducted in a contaminated portion of the vadose zone dominated by fine sands with lenses of silt material. Desiccation reduced volumetric moisture content to as low as 0.01. The lateral and vertical distribution of drying from the injection well was influenced by the subsurface heterogeneity. However, over time, desiccation occurred in the initially wetter, lower permeability lenses.

Vadose Zone Soil Moisture Wicking Using Super-Absorbent Polymers

Abstract: Super-absorbent polymers (SAPs) have the potential to remove water and associated contaminants from unsaturated sediments in the field. Column and flow cell experiment were conducted to test the ability of four types of SAPs to remove water from unsaturated porous media. Column experiments, with emplacement of a layer of polymer on top of unsaturated porous media, showed the ability of the SAPs to extract up to 80% of the initially emplaced water against gravity into the sorbent over periods up to four weeks. In column experiments where the sorbent was emplaced between layers of unsaturated porous media, gel formation was observed at both the sorbent-porous medium interfaces. The extraction percentages over four weeks of contact time were similar for both column configurations and no obvious differences were observed for the four tested SAPs. Two different flow cells were used to test the wicking behavior of SAPs in two dimensions using three configurations. The largest removal percentages occurred for the horizontal sorbent layer configuration which has the largest sorbent-porous medium interfacial area. In a larger flow cell, a woven nylon “sock” was packed with sorbent and subsequently placed between perforated metal plates, mimicking a well configuration. After one week of contactmore » time the sock was removed and replaced by a fresh sock. The results of this experiment showed that the sorbent was able to continuously extract water from the porous media, although the rate decreased over time. The declining yield during both periods is associated with the sharp reduction in water saturation and relative permeability near the sorbent. It was also observed that the capillary pressure continued to increase over the total contact time of 14 days, indicating that the sorbent remained active over that period. This work has demonstrated the potential of soil moisture wicking using SAPs at the proof-of-principle level.« less

Review: Technical and policy challenges in deep vadose zone remediation of metals and radionuclides.

Abstract: Contamination in deep vadose zone environments is isolated from exposure so direct contact is not a factor in its risk to human health and the environment. Instead, movement of contamination to the groundwater creates the potential for exposure and risk to receptors. Limiting flux from contaminated vadose zone is key for protection of groundwater resources, thus the deep vadose zone is not necessarily considered a resource requiring restoration. Contaminant discharge to the groundwater must be maintained low enough by natural attenuation (e.g., adsorption processes or radioactive decay) or through remedial actions (e.g., contaminant mass reduction or mobility reduction) to meet the groundwater concentration goals. This paper reviews the major processes for deep vadose zone metal and radionuclide remediation that form the practical constraints on remedial actions. Remediation of metal and radionuclide contamination in the deep vadose zone is complicated by heterogeneous contaminant distribution and the sat...

Monitoring Vadose Zone Desiccation with Geophysical Methods

Abstract: Soil desiccation was recently field tested as a potential vadose zone remediation technology. Desiccation removes water from the vadose zone and significantly decreases the aqueous-phase permeability of the desiccated zone, thereby decreasing movement of moisture and contaminants. The two- and three-dimensional distribution of moisture content reduction with time provides valuable information for desiccation operations and for determining when treatment goals have been reached. This type of information can be obtained through the use of geophysical methods. Neutron moisture logging, cross-hole electrical resistivity tomography, and cross-hole ground-penetrating radar approaches were evaluated with respect to their ability to provide effective spatial and temporal monitoring of desiccation during a treatability study conducted in the vadose zone of the USDOE Hanford site in the state of Washington.

Enhancing the information content of geophysical data for nuclear site characterisation

Abstract: Our knowledge and understanding to the heterogeneous structure and processes occurring in the Earth’s subsurface is limited and uncertain. The above is true even for the upper 100m of the subsurface, yet many processes occur within it (e.g. migration of solutes, landslides, crop water uptake, etc.) are important to human activities. Geophysical methods such as electrical resistivity tomography (ERT) greatly improve our ability to observe the subsurface due to their higher sampling frequency (especially with autonomous time-lapse systems), larger spatial coverage and less invasive operation, in addition to being more cost-effective than traditional point-based sampling. However, the process of using geophysical data for inference is prone to uncertainty. There is a need to better understand the uncertainties embedded in geophysical data and how they translate themselves when they are subsequently used, for example, for hydrological or site management interpretations and decisions. This understanding is critical to maximize the extraction of information in geophysical data. To this end, in this thesis, I examine various aspects of uncertainty in ERT and develop new methods to better use geophysical data quantitatively. The core of the thesis is based on two literature reviews and three papers. In the first review, I provide a comprehensive overview of the use of geophysical data for nuclear site characterization, especially in the context of site clean-up and leak detection. In the second review, I survey the various sources of uncertainties in ERT studies and the existing work to better quantify or reduce them. I propose that the various steps in the general workflow of an ERT study can be viewed as a pipeline for information and uncertainty propagation and suggested some areas have been understudied. One of these areas is measurement errors. In paper 1, I compare various methods to estimate and model ERT measurement errors using two long-term ERT monitoring datasets. I also develop a new error model that considers the fact that each electrode is used to make multiple measurements. In paper 2, I discuss the development and implementation of a new method for geoelectrical leak detection. While existing methods rely on obtaining resistivity images through inversion of ERT data first, the approach described here estimates leak parameters directly from raw ERT data. This is achieved by constructing hydrological models from prior site information and couple it with an ERT forward model, and then update the leak (and other hydrological) parameters through data assimilation. The approach shows promising results and is applied to data from a controlled injection experiment in Yorkshire, UK. The approach complements ERT imaging and provides a new way to utilize ERT data to inform site characterisation. In addition to leak detection, ERT is also commonly used for monitoring soil moisture in the vadose zone, and increasingly so in a quantitative manner. Though both the petrophysical relationships (i.e., choices of appropriate model and parameterization) and the derived moisture content are known to be subject to uncertainty, they are commonly treated as exact and error‐free. In paper 3, I examine the impact of uncertain petrophysical relationships on the moisture content estimates derived from electrical geophysics. Data from a collection of core samples show that the variability in such relationships can be large, and they in turn can lead to high uncertainty in moisture content estimates, and they appear to be the dominating source of uncertainty in many cases. In the closing chapters, I discuss and synthesize the findings in the thesis within the larger context of enhancing the information content of geophysical data, and provide an outlook on further research in this topic.