Markus Flury

Bio: Markus Flury is an academic researcher from Washington State University. The author has contributed to research in topics: Soil water & Mulch. The author has an hindex of 53, co-authored 161 publications receiving 9618 citations. Previous affiliations of Markus Flury include University of Tennessee & Empresa Brasileira de Pesquisa Agropecuária.

Susceptibility of soils to preferential flow of water : a field study

Abstract: Flow pathways of water and solutes in soils form distinct patterns, which are not a priori predictable. Macropore structure is a prime cause, but other factors, such as differing initial or boundary conditions, may also predispose a soil to produce bypassing of infiltrating water. This study was conducted to assess the flow pathways of water in different soils and to investigate the effect of initial water content on the flow pattern. Dye-tracing experiments were carried out at 14 different field sites. The sites represent a good portion of soils used for agricultural crop production in Switzerland. Each site consisted of two 1.4 by 1.4 m plots, one of which had been covered with a plastic roof for two months before the experiment to achieve different initial water contents. Forty millimeters of water containing the dye Brilliant Blue FCF (C.I. Food Blue 2) were applied within 8 hours onto the plots with a sprinkling apparatus. One day after irrigation the plots were excavated, and the stained pattern was examined on a vertical 1 by l m soil profile. The spatial structure of flow patterns showed remarkable differences. In most soils, water bypassed the soil matrix. In some soils, dye penetrated beyond l m depth, whereas in others it remained in the top 50 cm. Structured soils were more prone to produce bypass flow, deep dye penetration, and pulse splitting than nonstructured soils. The initial water content had a less pronounced effect in some soils and no effect in others.

Modeling Soil Processes: Review, Key Challenges, and New Perspectives

Abstract: The remarkable complexity of soil and its importance to a wide range of ecosystem services presents major challenges to the modeling of soil processes. Although major progress in soil models has occurred in the last decades, models of soil processes remain disjointed between disciplines or ecosystem services, with considerable uncertainty remaining in the quality of predictions and several challenges that remain yet to be addressed. First, there is a need to improve exchange of knowledge and experience among the different disciplines in soil science and to reach out to other Earth science communities. Second, the community needs to develop a new generation of soil models based on a systemic approach comprising relevant physical, chemical, and biological processes to address critical knowledge gaps in our understanding of soil processes and their interactions. Overcoming these challenges will facilitate exchanges between soil modeling and climate, plant, and social science modeling communities. It will allow us to contribute to preserve and improve our assessment of ecosystem services and advance our understanding of climate-change feedback mechanisms, among others, thereby facilitating and strengthening communication among scientific disciplines and society. We review the role of modeling soil processes in quantifying key soil processes that shape ecosystem services, with a focus on provisioning and regulating services. We then identify key challenges in modeling soil processes, including the systematic incorporation of heterogeneity and uncertainty, the integration of data and models, and strategies for effective integration of knowledge on physical, chemical, and biological soil processes. We discuss how the soil modeling community could best interface with modern modeling activities in other disciplines, such as climate, ecology, and plant research, and how to weave novel observation and measurement techniques into soil models. We propose the establishment of an international soil modeling consortium to coherently advance soil modeling activities and foster communication with other Earth science disciplines. Such a consortium should promote soil modeling platforms and data repository for model development, calibration and intercomparison essential for addressing contemporary challenges.

Experimental evidence of transport of pesticides through field soils - a review

Abstract: Much information is available in the literature about pesticide transport through soils at the field scale. The purpose of this study is to review the literature with a focus on pesticide leaching to groundwater. The literature was compiled and discussed with respect to different factors that influence pesticide leaching. Pesticide leaching below the root zone has been demonstrated in sandy as well as in loamy soils. Particularly in loamy soils, there is evidence that even strongly adsorbing chemicals can move along preferential flow pathways and that the travel times of pesticides are comparable to those of conservative solutes. The amounts of pesticides leached below the root zone by worst case rainfall events depend on the chemical properties and can reach up to 5% of the applied mass. When there is no heavy rainfall shortly following application of chemicals, the mass annually leached below the root zone is in the range of <0.1 to 1%, occasionally it can reach up to 4%. Although a direct comparison cannot be made, the mass lost by leaching seems generally to be smaller than that lost by runoff, depending of course on the slope of the fields. Several factors that affect pesticide leaching, such asmore » surface preparation, soil structure, soil water content, type of irrigation, pesticide formulation, time of application and rainfall events, are discussed with support of experimental evidence. While some factors showed inconsistent effects, others show promise in controlling leaching mechanisms. These latter factors include initial water content, surface preparation, and time of pesticide application. Based on the reviewed literature recommendations were made for future research activities. 172 refs., 1 fig., 7 tabs.« less

Dyes as tracers for vadose zone hydrology

Abstract: [1] Dyes are important tracers to investigate subsurface water movement. For more than a century, dye tracers have provided clues about the hydrological cycle as well as flow and transport processes in the subsurface. Groundwater contamination often originates in the vadose zone. Agrochemicals applied to the soil surface, toxic compounds accidentally spilled by human activities, and contaminants released from waste repositories leach through the vadose zone and can ultimately pollute groundwater resources. Dyes are an important tool to assess flow pathways of such contaminants. This review compiles information on dyes used as hydrological tracers, with particular emphasis on vadose zone hydrology. We summarize briefly different human-applied tracers, including nondye tracers. We then provide a historical sketch of the use of dyes as tracers and describe newer developments in visualization and quantification of tracer experiments. Relevant chemical properties of dyes used as tracers are discussed and illustrated with dye intermediates and selected dye tracers. The types of dyes used as tracers in subsurface hydrology are summarized, and recommendations are made regarding the use of dye tracers. The review concludes with a toxicological assessment of dyes used as hydrological tracers. Many different dyes have been proposed as tracers for water movement in the subsurface. All of these compounds, however, are to some degree retarded by the subsurface medium. Nevertheless, dyes are useful tracers to visualize flow pathways.

Tracer Characteristics of Brilliant Blue FCF

Abstract: Dyes are widely used to stain the travel paths of water and solutes in soils. Brilliant Blue FCF (C.I. Food Blue 2) is a valuable dye tracer for visualizing water flow patterns. Because this dye is nontoxic, it is particularly suited for field use. Depending on pH, the dye is either neutral or dissociates to a mono- or bivalent anion. The water solubility is 200 kg m -3 . In this study, properties of the dye that characterize the adsorbing behavior in soil were determined. Batch adsorption experiments were carried out in the laboratory, and a field experiment was conducted to compare the mobility of Brilliant Blue FCF with that of I - and Br - . The batch studies gave distribution coefficients K d of 0.19, 3.00, and 5.78 dm 3 kg -1 for three different soils. The results of the batch studies suggest that the dye forms ion pairs with Ca 2+ . The field experiment showed that the dye is retarded compared with the conservative tracer Br - . A comparison between Brilliant Blue FCF and I - analyzed with the iodide-starch method resulted in a relative retardation of 1.2 Brilliant Blue FCF compared with I -

Choosing appropriate techniques for quantifying groundwater recharge

Abstract: DOI 10.1007/s10040-0010176-2 Abstract Various techniques are available to quantify recharge; however, choosing appropriate techniques is often difficult. Important considerations in choosing a technique include space/time scales, range, and reliabili- ty of recharge estimates based on different techniques; other factors may limit the application of particular tech- niques. The goal of the recharge study is important be- cause it may dictate the required space/time scales of the recharge estimates. Typical study goals include water-re- source evaluation, which requires information on re- charge over large spatial scales and on decadal time scales; and evaluation of aquifer vulnerability to contam- ination, which requires detailed information on spatial variability and preferential flow. The range of recharge rates that can be estimated using different approaches should be matched to expected recharge rates at a site. The reliability of recharge estimates using different tech- niques is variable. Techniques based on surface-water and unsaturated-zone data provide estimates of potential recharge, whereas those based on groundwater data gen- erally provide estimates of actual recharge. Uncertainties in each approach to estimating recharge underscore the need for application of multiple techniques to increase

Global Water Pollution and Human Health

Abstract: Water quality issues are a major challenge that humanity is facing in the twenty-first century. Here, we review the main groups of aquatic contaminants, their effects on human health, and approaches to mitigate pollution of freshwater resources. Emphasis is placed on chemical pollution, particularly on inorganic and organic micropollutants including toxic metals and metalloids as well as a large variety of synthetic organic chemicals. Some aspects of waterborne diseases and the urgent need for improved sanitation in developing countries are also discussed. The review addresses current scientific advances to cope with the great diversity of pollutants. It is organized along the different temporal and spatial scales of global water pollution. Persistent organic pollutants (POPs) have affected water systems on a global scale for more than five decades; during that time geogenic pollutants, mining operations, and hazardous waste sites have been the most relevant sources of long-term regional and local water pollution. Agricultural chemicals and wastewater sources exert shorter-term effects on regional to local scales.

Microplastics and Nanoplastics in Aquatic Environments: Aggregation, Deposition, and Enhanced Contaminant Transport

Abstract: Plastic litter is widely acknowledged as a global environmental threat, and poor management and disposal lead to increasing levels in the environment. Of recent concern is the degradation of plastics from macro- to micro- and even to nanosized particles smaller than 100 nm in size. At the nanoscale, plastics are difficult to detect and can be transported in air, soil, and water compartments. While the impact of plastic debris on marine and fresh waters and organisms has been studied, the loads, transformations, transport, and fate of plastics in terrestrial and subsurface environments are largely overlooked. In this Critical Review, we first present estimated loads of plastics in different environmental compartments. We also provide a critical review of the current knowledge vis-a-vis nanoplastic (NP) and microplastic (MP) aggregation, deposition, and contaminant cotransport in the environment. Important factors that affect aggregation and deposition in natural subsurface environments are identified and c...