M
Matthew S. Sigman
Researcher at University of Utah
Publications - 346
Citations - 22121
Matthew S. Sigman is an academic researcher from University of Utah. The author has contributed to research in topics: Catalysis & Enantioselective synthesis. The author has an hindex of 74, co-authored 322 publications receiving 18452 citations. Previous affiliations of Matthew S. Sigman include Argonne National Laboratory & OSI Pharmaceuticals.
Papers
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Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners.
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Schiff base catalysts for the asymmetric strecker reaction identified and optimized from parallel synthetic libraries
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Ligand-Modulated Palladium-Catalyzed Aerobic Alcohol Oxidations
TL;DR: The discovery and investigation of ligand-modulated Pd-catalyzed aerobic alcohol oxidations is documented and key insights into how new, more effective catalysts can be designed are provided.
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Exploiting non-covalent π interactions for catalyst design
Andrew J. Neel,Andrew J. Neel,Andrew J. Neel,Margaret J. Hilton,Matthew S. Sigman,F. Dean Toste,F. Dean Toste +6 more
TL;DR: In this paper, the physical origins and properties of π interactions are explained and their effects on molecular binding and chemical transformations are investigated, which offers opportunities for rational manipulation of these complex non-covalent interactions and their direct incorporation into the design of small-molecule catalysts and enzymes.
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Substrate channelling as an approach to cascade reactions.
Ian Wheeldon,Shelley D. Minteer,Scott Banta,Scott Calabrese Barton,Plamen Atanassov,Matthew S. Sigman +5 more
TL;DR: The incorporation of substrate channelling into synthetic cascades is a rapidly developing concept, and recent examples of the fabrication of cascades with controlled diffusion and flux of intermediates are presented.