The increasing interest in energy storage for the grid can be attributed to multiple factors, including the capital costs of managing peak demands, the investments needed for grid reliability, and the integration of renewable energy sources. Although existing energy storage is dominated by pumped hydroelectric, there is the recognition that battery systems can offer a number of high-value opportunities, provided that lower costs can be obtained. The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.

Electrical Energy Storage for the Grid: A Battery of Choices

The status of ambient temperature sodium ion batteries is reviewed in light of recent developments in anode, electrolyte and cathode materials. These devices, although early in their stage of development, are promising for large-scale grid storage applications due to the abundance and very low cost of sodium-containing precursors used to make the components. The engineering knowledge developed recently for highly successful Li ion batteries can be leveraged to ensure rapid progress in this area, although different electrode materials and electrolytes will be required for dual intercalation systems based on sodium. In particular, new anode materials need to be identified, since the graphite anode, commonly used in lithium systems, does not intercalate sodium to any appreciable extent. A wider array of choices is available for cathodes, including high performance layered transition metal oxides and polyanionic compounds. Recent developments in electrodes are encouraging, but a great deal of research is necessary, particularly in new electrolytes, and the understanding of the SEI films. The engineering modeling calculations of Na-ion battery energy density indicate that 210 Wh kg−1 in gravimetric energy is possible for Na-ion batteries compared to existing Li-ion technology if a cathode capacity of 200 mAh g−1 and a 500 mAh g−1 anode can be discovered with an average cell potential of 3.3 V.

Sodium‐Ion Batteries

Rechargeable lithium-sulfur batteries.

Energy production and storage have become key issues concerning our welfare in daily life. Present challenges for batteries are twofold. In the first place, the increasing demand for powering systems of portable electronic devices and zero-emission vehicles stimulates research towards high energy and high voltage systems. In the second place, low cost batteries are required in order to advance towards smart electric grids that integrate discontinuous energy flow from renewable sources, optimizing the performance of clean energy sources. Na-ion batteries can be the key for the second point, because of the huge availability of sodium, its low price and the similarity of both Li and Na insertion chemistries. In spite of the lower energy density and voltage of Na-ion based technologies, they can be focused on applications where the weight and footprint requirement is less drastic, such as electrical grid storage. Much work has to be done in the field of Na-ion in order to catch up with Li-ion technology. Cathodic and anodic materials must be optimized, and new electrolytes will be the key point for Na-ion success. This review will gather the up-to-date knowledge about Na-ion battery materials, with the aim of providing a wide view of the systems that have already been explored and a starting point for the new research on this battery technology.

Na-ion batteries, recent advances and present challenges to become low cost energy storage systems

Overview of current development in electrical energy storage technologies and the application potential in power system operation

The is a comprehensive review on the needs and potential storage technologies for electrical grid that is expected to integrate significant levels of renewables. This review offers details of the technologies, in terms of needs, status, challenges and future R&d directions.

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Electrochemical Energy Storage for Green Grid

Cost and performance model for redox flow batteries

The variability and nondispatchable nature of wind and solar energy production presents substantial challenges for maintaining system balance. Depending on the economic considerations, energy storage can be a viable solution to balance energy production with consumption. This paper proposes to use discrete Fourier transform to decompose the required balancing power into different time-varying periodic components, i.e., intraweek, intraday, intrahour, and real-time. Each component can be used to quantify the maximum energy storage requirement for different types of energy storage. This requirement is the physical limit that could be theoretically accommodated by a power system. The actual energy storage capacity can be further quantified within this limit by the cost-benefit analysis (future work). The proposed approach has been successfully used in a study conducted for the 2030 Western Electricity Coordinating Council system model. Some results of this study are provided in this paper.

Sizing Energy Storage to Accommodate High Penetration of Variable Energy Resources

The U.S. electric power infrastructure is a significantly underutilized strategic asset which, with the proper shift in operational paradigms could provide a significant portion of the energy requirements for the existing U.S. light duty vehicle (LDV) fleet. This shift would result in reduced emissions, improved economics for utilities, and a reduced dependence on oil. A previous study has shown that the existing generation and transmission assets of the U.S. electric power infrastructure could feasibly supply the electricity for approximately 70% of the U.S. LDV fleet. In the limitations of the distribution system were not explicitly addressed and are more difficult to quantify because of the large diversity of distribution systems topology, design guidelines and load growth. This paper focuses on the impacts of a high penetration of plug-in electric hybrid vehicles (PHEVs) on the distribution systems. Presented are results specific for the Pacific Northwest.

Impact assessment of plug-in hybrid vehicles on pacific northwest distribution systems

The Platform for Regional Integrated Modeling and Analysis (PRIMA) is an innovative modeling system developed at Pacific Northwest National Laboratory (PNNL) to simulate interactions among natural and human systems at scales relevant to regional decision making. PRIMA brings together state-of-the-art models of regional climate, hydrology, agriculture and land use, socioeconomics, and energy systems using a flexible coupling approach. Stakeholder decision support needs underpin the application of the platform to regional issues, and an uncertainty characterization process is used to identify robust decisions. The platform can be customized to inform a variety of complex questions, such as how a policy in one sector might affect the ability to meet climate mitigation targets or adaptation goals in another sector. Current numerical experiments focus on the eastern United States, but the framework is designed to be regionally flexible. This paper provides a high-level overview of PRIMA’s functional capabilities and describes some key challenges and opportunities associated with integrated regional modeling.

Investigating the Nexus of Climate, Energy, Water, and Land at Decision-Relevant Scales: The Platform for Regional Integrated Modeling and Analysis (PRIMA)

Michael Kintner-Meyer

Papers

Electrochemical Energy Storage for Green Grid

Cost and performance model for redox flow batteries

Sizing Energy Storage to Accommodate High Penetration of Variable Energy Resources

Impact assessment of plug-in hybrid vehicles on pacific northwest distribution systems

Investigating the Nexus of Climate, Energy, Water, and Land at Decision-Relevant Scales: The Platform for Regional Integrated Modeling and Analysis (PRIMA)