Showing papers by "Min Xu published in 2020"

Climate and hydrological changes in the Ob River Basin during 1936–2017

Abstract: Changes in the hydrological regimes of Arctic rivers could affect the thermohaline circulation of the Arctic Ocean. In this study, we analysed spatiotemporal variations in temperature and precipitation in the Ob River Basin regions during 1936–2017 based on data from the Global Precipitation Climatology Center. Changes in discharge and response to climate change were examined based on monthly observed data during the same period. It is indicated the Ob River Basin experienced significant overall rapid warming and wetting (increased precipitation) in the study period, with average rates of 0.20°C (10 year⁻¹) and 5.3 mm (10 year⁻¹), respectively. The annual spatial variations of temperature and precipitation showed different scales in different regions. The discharge in spring and winter significantly increased at a rate of 384.1 and 173.1 m³/s (10 year⁻¹), respectively. Hydrograph separation indicated infiltration and supported that deep flow paths increased the contribution of groundwater to base flow. Meanwhile, the variation of the ratio of Qₘₐₓ/Qₘᵢₙ suggested that the basin storage and the mechanism of discharge generation have significantly changed. The hydrological processes were influenced by changes of permafrost in a certain in the Ob River Basin. An increase in the recession coefficient (RC) implies that the permafrost degradation in the basin due to climate warming affected hydrological processes in winter. Permafrost degradation affected the Qₘₐₓ/Qₘᵢₙ more significantly in the warm season than RC due to the enhanced infiltration that converted more surface water into groundwater in the cold season. The impact of precipitation on discharge, including surface flow and base flow, was more significant than temperature at the annual and seasonal scales in the Ob River Basin. The base flow was more obviously influenced by temperature than surface flow. The results of this study are significant for analyses of the basin water budget and freshwater input to the Arctic Ocean.

Correction: Xu, M., et al. Modeling Glacier Mass Balance and Runoff in the Koxkar River Basin on the South Slope of the Tianshan Mountains, China, from 1959 to 2009. Water 2017, 9, 100

Abstract: The authors wish to make the following corrections to this paper [...]

Screening of metal–organic frameworks for water adsorption heat transformation using structure–property relationships

Abstract: It is of great importance to correlate the water adsorption performance of MOFs to their physicochemical features in order to design and prepare MOFs for applications in adsorption heat transformation. In this work, both data analysis from existing studies and Grand Canonical Monte Carlo molecular simulation investigations were carried out. The results indicated that the highest water adsorption capacity was determined by the pore volume of MOF adsorbents, while there was a linear correlation interrelationship between isosteric heats of adsorption and the water adsorption performance at a low relative pressure. More detailed analysis showed that the charge distribution framework and pore size of MOFs contributed together to the hydrophilicity. Electrostatic interaction between water molecules and the framework atoms played a key role at low relative water pressure. A quantitative structure–property relationship model that can correlate the hydrophilicity of MOFs to their pore size and atomic partial charge was established. Along with some qualitative considerations, the screening methodology is proposed and is used to screen proper MOFs in the CoRE database. Seven MOFs were detected, and four of them were synthesized to validate the screening principle. The results indicated that these four MOFs possessed outstanding water adsorption performance and could be considered as promising candidates in applications for adsorption heating and cooling.