Mirto Mozzon

TL;DR: The reaction chemistry of nitriles with transition metal complexes is reviewed in this paper, where the authors survey data published during the period 1977-early 1994 on new reaction processes such as insertion into metal-hydrogen and carbon bonds, coupling between one nitrile and an unsaturated metal fragment, reduction to amines, attack by protic and aprotic nucleophiles and electrophilic attack as well as some catalytic transformations.

TL;DR: Preparation de complexes cis-Cl 2 (L)M[CN(R)CH 2 CH 2 NH], cisCl 2(L)Pd[CN[R]CH 2CH 2 S] et cis-cl 2 (p-MeOC 6 H 4 NC)Pt [CN(C 6H 4 -p-OMe) CH 2 CH2 O] as discussed by the authors

TL;DR: In this paper, the chemistry of alkynyl and alkyne ligands in platinum complexes of different oxidation states is described, focusing on the synthetic aspects of mono-and polynuclear compounds and on the reactivity of σ-alkynyl or π-alkyne species in different stoichiometric reactions such as insertion, addition of nucleophiles and electrophiles, rearrangements and isomerization processes.

TL;DR: In this paper, a series of bis(nitrile) complexes cis-and trans-Cl2Pt(NCR)2 has been prepared by either one of the two methods, K2PteCl4/H2O/ RCN(excess) or PtCl2/RCN(neat), both of which usually yield the nitrile complexes as a mixture of cis and trans isomers in different ratios depending on the experimental conditions such as the reaction temperature and the reaction time.

TL;DR: In this paper, the coordination and organometallic chemistry of P- and As-carbonyl stabilized ylides is reviewed, with a special emphasis on their catalytic activity.