Mohd Asri Mat Teridi

Bio: Mohd Asri Mat Teridi is an academic researcher from National University of Malaysia. The author has contributed to research in topics: Perovskite (structure) & Thin film. The author has an hindex of 25, co-authored 101 publications receiving 2252 citations. Previous affiliations of Mohd Asri Mat Teridi include University College West.

Enhanced photoelectrochemical performance of Z-scheme g-C3N4/BiVO4 photocatalyst

Abstract: BiVO4 is a considerably promising semiconductor for photoelectrochemical water splitting due to its stability, low cost and moderate band gap. In this research, g-C3N4 was proposed in Z-scheme configuration which boosted the performance of BiVO4 up to four times. The experimental observations were counterchecked with Density Functional Theory (DFT) simulations. A TiO2/BiVO4 heterojunction was developed and its performance was compared with that of g-C3N4/BiVO4. The photocurrent for g-C3N4/BiVO4 was 0.42 mAcm−2 at 1.23 V vs. RHE which was the highest among g-C3N4 based Z-scheme heterojunction devices. Lower charge transfer resistance, higher light absorption and more oxygen vacancy sites were observed for the g-C3N4 based heterojunction. The simulated results attested that g-C3N4 and BiVO4 formed a van der Waals type heterojunction, where an internal electric field facilitated the separation of electron/hole pair at g-C3N4/BiVO4 interface which further restrained the carrier recombination. Both the valence and conduction band edge positions of g-C3N4 and BiVO4 changed with the Fermi energy level. The resulted heterojunction had small effective masses of electrons (0.01 me) and holes (0.10 me) with ideal band edge positions where both CBM and VBM were well above and below the redox potential of water.

Defect chemistry and defect engineering of TiO2-based semiconductors for solar energy conversion

Abstract: This tutorial review considers defect chemistry of TiO2 and its solid solutions as well as defect-related properties associated with solar-to-chemical energy conversion, such as Fermi level, bandgap, charge transport and surface active sites. Defect disorder is discussed in terms of defect reactions and the related charge compensation. Defect equilibria are used in derivation of defect diagrams showing the effect of oxygen activity and temperature on the concentration of both ionic and electronic defects. These defect diagrams may be used for imposition of desired semiconducting properties that are needed to maximize the performance of TiO2-based photoelectrodes for the generation of solar hydrogen fuel using photo electrochemical cells (PECs) and photocatalysts for water purification. The performance of the TiO2-based semiconductors is considered in terms of the key performance-related properties (KPPs) that are defect related. It is shown that defect engineering may be applied for optimization of the KPPs in order to achieve optimum performance.

Graphitic carbon nitride (g-C3N4) electrodes for energy conversion and storage: a review on photoelectrochemical water splitting, solar cells and supercapacitors

Abstract: Graphitic carbon nitride (g-C3N4) has emerged as one of the most promising photocatalysts due to its metal-free nature, abundance of raw material, and thermal physical–chemical stability. The breakthrough research studies in recent years have mostly been concentrated on the engineering of the intrinsic and morphological properties of g-C3N4-based photocatalysts in the framework of powder suspensions for artificial photosynthesis and environmental remediation. However, practical applications of g-C3N4-based electrodes and devices are still in the early stages of development due to challenging fabrication methods of g-C3N4 thin films. This review addresses the classification of diverse techniques to deposit g-C3N4-based thin films and explores a broad spectrum of applications pertinent to g-C3N4-based electrodes. Although this paper is principally focused on photoelectrochemical water splitting, other emerging applications of g-C3N4 in solar cells, electrocatalysts and supercapacitors are also reviewed. Lastly, further suggestions are posited for other potential applications, challenges and future orientations.

Prospects of life cycle assessment of renewable energy from solar photovoltaic technologies: A review

Abstract: Life cycle assessment (LCA) is a comprehensive method used to investigate the environmental impacts and energy use of a product throughout its entire life cycle. For solar photovoltaic (PV) technologies, LCA studies need to be conducted to address environmental and energy issues and foster the development of PV technologies in a sustainable manner. This paper reviews and analyzes LCA studies on solar PV technologies, such as silicon, thin film, dye-sensitized solar cell, perovskite solar cell, and quantum dot-sensitized solar cell. The PV life cycle assumes a cradle-to-grave mechanism, starting from the extraction of raw materials until the disposal or recycling of the solar PV. Three impact assessment methods in LCA were reviewed and summarized, namely, cumulative energy demand (CED), energy payback time (EPBT), and GHG emission rate, based on data and information published in the literature. LCA results show that mono-crystalline silicon PV technology has the highest energy consumption, longest EPBT, and highest greenhouse gas emissions rate compared with other solar PV technologies.

The architecture of the electron transport layer for a perovskite solar cell

Abstract: The emergence of perovskite solar cells (PSCs) recently has brought new hope to the solar cell industry due to their incredible improvement of the power conversion efficiency (PCE), which can now exceed 20.0% within seven years of tremendous research. The efficiency and stability of PSCs depend strongly on the morphology and type of materials selected as the electron transport layer (ETL) in the device. In this review, the functions of the ETL based on titania (TiO2) in n–i–p architecture PSCs, including planar heterojunction and mesoporous-structured devices, are reviewed in terms of the device performance and stability. Studies found that the application of suitable fabrication techniques and manipulation of the nanostructural properties of TiO2 are crucial factors in ameliorating the short-circuit current density, JSC, and fill factor, FF, of PSCs. On top of that, the effect of substituting TiO2 with other potential inorganic materials like zinc oxide (ZnO), tin oxide (SnO2), ternary metal oxides, and metal sulphides, as well as organic semiconductors including fullerene, graphene, and ionic liquids, towards the photovoltaic properties and stability of the devices are also elaborated and discussed. Meanwhile, the utilization of non-electron transport layers (non-ETLs), such as alumina (Al2O3) and zirconia (ZrO2), as the mesoporous scaffold in PSCs is found to enhance the open-circuit voltage, VOC, of the devices.

Halide Perovskite Photovoltaics: Background, Status, and Future Prospects

Abstract: The photovoltaics of organic–inorganic lead halide perovskite materials have shown rapid improvements in solar cell performance, surpassing the top efficiency of semiconductor compounds such as CdTe and CIGS (copper indium gallium selenide) used in solar cells in just about a decade. Perovskite preparation via simple and inexpensive solution processes demonstrates the immense potential of this thin-film solar cell technology to become a low-cost alternative to the presently commercially available photovoltaic technologies. Significant developments in almost all aspects of perovskite solar cells and discoveries of some fascinating properties of such hybrid perovskites have been made recently. This Review describes the fundamentals, recent research progress, present status, and our views on future prospects of perovskite-based photovoltaics, with discussions focused on strategies to improve both intrinsic and extrinsic (environmental) stabilities of high-efficiency devices. Strategies and challenges regardi...

Mn3O4-Graphene Hybrid as a High Capacity Anode Material for Lithium Ion Batteries

Abstract: We developed two-step solution-phase reactions to form hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery applications. Mn3O4 nanoparticles grown selectively on RGO sheets over free particle growth in solution allowed for the electrically insulating Mn3O4 nanoparticles wired up to a current collector through the underlying conducting graphene network. The Mn3O4 nanoparticles formed on RGO show a high specific capacity up to ~900mAh/g near its theoretical capacity with good rate capability and cycling stability, owing to the intimate interactions between the graphene substrates and the Mn3O4 nanoparticles grown atop. The Mn3O4/RGO hybrid could be a promising candidate material for high-capacity, low-cost, and environmentally friendly anode for lithium ion batteries. Our growth-on-graphene approach should offer a new technique for design and synthesis of battery electrodes based on highly insulating materials.

Understanding Degradation Mechanisms and Improving Stability of Perovskite Photovoltaics.

Abstract: This review article examines the current state of understanding in how metal halide perovskite solar cells can degrade when exposed to moisture, oxygen, heat, light, mechanical stress, and reverse bias. It also highlights strategies for improving stability, such as tuning the composition of the perovskite, introducing hydrophobic coatings, replacing metal electrodes with carbon or transparent conducting oxides, and packaging. The article concludes with recommendations on how accelerated testing should be performed to rapidly develop solar cells that are both extraordinarily efficient and stable.

The rapid evolution of highly efficient perovskite solar cells

Abstract: Perovskite solar cells (PSCs) have attracted much attention because of their rapid rise to 22% efficiencies. Here, we review the rapid evolution of PSCs as they enter a new phase that could revolutionize the photovoltaic industry. In particular, we describe the properties that make perovskites so remarkable, and the current understanding of the PSC device physics, including the operation of state-of-the-art solar cells with efficiencies above 20%. The extraordinary progress of long-term stability is discussed and we provide an outlook on what the future of PSCs might soon bring the photovoltaic community. Some challenges remain in terms of reducing non-radiative recombination and increasing conductivity of the different device layers, and these will be discussed in depth in this review.

Oxygen Vacancy-Mediated Photocatalysis of BiOCl: Reactivity, Selectivity, and Perspectives.

Abstract: Semiconductor photocatalysis is a trustworthy approach to harvest clean solar light for energy conversions, while state-of-the-art catalytic efficiencies are unsatisfactory because of the finite light response and/or recombination of robust charge carriers. Along with the development of modern material characterization techniques and electronic-structure computations, oxygen vacancies (OVs) on the surface of real photocatalysts, even in infinitesimal concentration, are found to play a more decisive role in determining the kinetics, energetics, and mechanisms of photocatalytic reactions. This Review endeavors to clarify the inherent functionality of OVs in photocatalysis at the surface molecular level using 2D BiOCl as the platform. Structure sensitivity of OVs on reactivity and selectivity of photocatalytic reactions is intensely discussed via confining OVs onto prototypical BiOCl surfaces of different structures. The critical understanding of OVs chemistry can help consolidate and advance the fundamental theories of photocatalysis, and also offer new perspectives and guidelines for the rational design of catalysts with satisfactory performance.