Muhammad Adnan

Bio: Muhammad Adnan is an academic researcher from Chosun University. The author has contributed to research in topics: Organic solar cell & Acceptor. The author has an hindex of 18, co-authored 39 publications receiving 728 citations. Previous affiliations of Muhammad Adnan include University of Agriculture, Faisalabad & UPRRP College of Natural Sciences.

Adsorption of Phosgene Gas on Pristine and Copper-Decorated B12N12 Nanocages: A Comparative DFT Study.

Abstract: Nanostructured gas sensors find diverse applications in environmental and agricultural monitoring. Herein, adsorption of phosgene (COCl2) on pure and copper-decorated B12N12 (Cu–BN) is analyzed thr...

All Sequential Dip-Coating Processed Perovskite Layers from an Aqueous Lead Precursor for High Efficiency Perovskite Solar Cells.

Abstract: A novel, sequential method of dip-coating a ZnO covered mesoporous TiO2 electrode was performed using a non-halide lead precursor in an aqueous system to form a nanoscale perovskite film. The introduction of a ZnO interfacial layer induced significant adsorption in the non-halide lead precursor system. An efficient successive solid-state ion exchange and reaction process improved the morphology, crystallinity, and stability of perovskite solar cells. Improved surface coverage was achieved using successive ionic layer adsorption and reaction processes. When all sequential dipping conditions were controlled, a notable power conversion efficiency of 12.41% under standard conditions (AM 1.5, 100 mW·cm−2) was achieved for the perovskite solar cells fabricated from an aqueous non-halide lead precursor solution without spin-casting, which is an environmentally benign and low-cost manufacturing processes.

Designing indenothiophene-based acceptor materials with efficient photovoltaic parameters for fullerene-free organic solar cells

Abstract: Non-fullerene small molecular acceptors (NFSMAs) exhibit promising photovoltaic performance which promoted the rapid progress of organic solar cells (OSCs). In this study, an attempt is done to explore indenothiophene-based high-performance small molecular electron acceptors for organic solar cells. We have designed five acceptor molecules (M1–M5) with strong donor moiety indenothiophene linked to five different end-capped group acceptor moieties: diflouro-2-methylene-3-oxo-2,3-dihydroindene-1-ylidene)malononitrile (A1), 1-(dicyanomethylene)-2-methylene-3-oxo-2,3-dihydro-1H-indene-5,6-dicarbonitrile (A2), methyl-6-cyano-3-(dicyanomethylene)-2-methylene-1-oxo-2,3-dihydro-1H-indene-5-carboylate (A3), 2-(6-cyano-5-fluoro-2-methylene-3-oxo-2,3 dihydro-1H-indene-1-ylidene)malononitrile (A4), and (Z)-methyl 3-(benzo [c][1,2,5]thiadiazol-4-yl)-2-cyanoacrylate (A5) respectively. The structure–property relationship was studied and effects of structural modification on the optoelectronic properties of these acceptors (M1–M5) were determined systematically by comparing it with reference molecule R, which is recently reported as excellent non-fullerene-based small acceptor molecule. Among all designed molecules, M5 is proven as a suitable candidate for organic solar cell applications due to better photovoltaic properties including narrow HOMO-LUMO energy gap (2.11 eV), smallest electron mobility (λe = 0.0038 eV), highest λmax values (702.82 nm in gas) and (663.09 nm in chloroform solvent) and highest open-circuit voltage (Voc = 1.49 V) with respect to HOMOPTB7-Th–LUMOacceptor. Our results indicate that introducing more end-capped electron-accepting units is a simple and effective alternative strategy for the design of promising NFSMAs. This theoretical framework also proves that the conceptualized NFSMAs are superior and thus are recommended for the future construction of high-performance organic solar cell devices.

Revisiting the role of renewable and non-renewable energy consumption on Turkey’s ecological footprint: Evidence from Quantile ARDL approach

Abstract: The current study re-investigates the impact of renewable and non-renewable energy consumption on Turkey’s ecological footprint. This study applies Quantile Autoregressive Lagged (QARDL) approach for the period of 1965Q1-2017Q4. We further apply Granger-causality in Quantiles to check the causal relationship among the variables. The results of QARDL show that error correction parameter is statistically significant with the expected negative sign for all quantiles which confirm an existence of significant reversion to the long-term equilibrium connection between the related variables and ecological footprint in Turkey. In particular, the outcomes suggested that renewable energy decrease ecological footprint in long-run on each quantile. However, the results of economic growth and non-renewable energy impact positively to ecological footprint in long-short run period at all quantiles. Finally, we tested the Environmental Kuznets Curve (EKC) hypothesis and the results of QARDL confirmed the EKC in Turkey. Furthermore, the findings of causal investigation from Granger-causality in quantiles evident the presence of a bi-directional causal relationship between renewable energy consumption, energy consumption and economic growth with ecological footprint in the Turkish economy.

Genesis of Pure Se(0) Nano- and Micro- structures in Wastewater

Abstract: Advanced materials are essential to the quality of modern day life, but the synthesis of these compounds is often inefficient in terms of energy, time and resources; especially when considering the hydrothermal batch methods used to prepare many such compounds – often requiring week-long reaction times with variable yields and product quality. In contrast, Continuous flow synthesis (CFS) provides a more readily scalable means for the efficient, effective and reproducible synthesis of inorganic compounds. This publication demonstrates the novel CFS of several metal ammonium phosphates and compare the effect of synthesis route on particle size, size distribution, and crystallinity.

Functional materials, device architecture, and flexibility of perovskite solar cell

Abstract: Perovskite solar cells (PSCs) are an emerging photovoltaic technology that promises to offer facile and efficient solar power generation to meet future energy needs. PSCs have received considerable attention in recent years, have attained power conversion efficiencies (PCEs) over 22%, and are a promising candidate to potentially replace the current photovoltaic technology. The emergence of PSCs has revolutionized photovoltaic research and development because of their high efficiencies, inherent flexibility, the diversity of materials/synthetic methods that can be employed to manufacture them, and the various possible device architectures. Further optimization of material compositions and device architectures will help further improve efficiency and device stability. Moreover, the search for new functional materials will allow for mitigation of the existing limitations of PSCs. This review covers the recently developed advanced techniques and research trends related to this emerging photovoltaic technology, with a focus on the diversity of functional materials used for the various layers of PSC devices, novel PSC architectures, methods that increase overall cell efficiency, and substrates that allow for enhanced device flexibility.