Current research into semiconductor clusters is focused on the properties of quantum dots-fragments of semiconductor consisting of hundreds to many thousands of atoms-with the bulk bonding geometry and with surface states eliminated by enclosure in a material that has a larger band gap. Quantum dots exhibit strongly size-dependent optical and electrical properties. The ability to join the dots into complex assemblies creates many opportunities for scientific discovery.

Semiconductor Clusters, Nanocrystals, and Quantum Dots

The interest in nanoscale materials stems from the fact that new properties are acquired at this length scale and, equally important, that these properties * To whom correspondence should be addressed. Phone, 404-8940292; fax, 404-894-0294; e-mail, mostafa.el-sayed@ chemistry.gatech.edu. † Case Western Reserve UniversitysMillis 2258. ‡ Phone, 216-368-5918; fax, 216-368-3006; e-mail, burda@case.edu. § Georgia Institute of Technology. 1025 Chem. Rev. 2005, 105, 1025−1102

Chemistry and properties of nanocrystals of different shapes.

The need to develop inexpensive renewable energy sources stimulates scientific research for efficient, low-cost photovoltaic devices.1 The organic, polymer-based photovoltaic elements have introduced at least the potential of obtaining cheap and easy methods to produce energy from light.2 The possibility of chemically manipulating the material properties of polymers (plastics) combined with a variety of easy and cheap processing techniques has made polymer-based materials present in almost every aspect of modern society.3 Organic semiconductors have several advantages: (a) lowcost synthesis, and (b) easy manufacture of thin film devices by vacuum evaporation/sublimation or solution cast or printing technologies. Furthermore, organic semiconductor thin films may show high absorption coefficients4 exceeding 105 cm-1, which makes them good chromophores for optoelectronic applications. The electronic band gap of organic semiconductors can be engineered by chemical synthesis for simple color changing of light emitting diodes (LEDs).5 Charge carrier mobilities as high as 10 cm2/V‚s6 made them competitive with amorphous silicon.7 This review is organized as follows. In the first part, we will give a general introduction to the materials, production techniques, working principles, critical parameters, and stability of the organic solar cells. In the second part, we will focus on conjugated polymer/fullerene bulk heterojunction solar cells, mainly on polyphenylenevinylene (PPV) derivatives/(1-(3-methoxycarbonyl) propyl-1-phenyl[6,6]C61) (PCBM) fullerene derivatives and poly(3-hexylthiophene) (P3HT)/PCBM systems. In the third part, we will discuss the alternative approaches such as polymer/polymer solar cells and organic/inorganic hybrid solar cells. In the fourth part, we will suggest possible routes for further improvements and finish with some conclusions. The different papers mentioned in the text have been chosen for didactical purposes and cannot reflect the chronology of the research field nor have a claim of completeness. The further interested reader is referred to the vast amount of quality papers published in this field during the past decade.

Conjugated polymer-based organic solar cells

We report a synthesis of highly luminescent (CdSe)ZnS composite quantum dots with CdSe cores ranging in diameter from 23 to 55 A. The narrow photoluminescence (fwhm ≤ 40 nm) from these composite dots spans most of the visible spectrum from blue through red with quantum yields of 30−50% at room temperature. We characterize these materials using a range of optical and structural techniques. Optical absorption and photoluminescence spectroscopies probe the effect of ZnS passivation on the electronic structure of the dots. We use a combination of wavelength dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, small and wide angle X-ray scattering, and transmission electron microscopy to analyze the composite dots and determine their chemical composition, average size, size distribution, shape, and internal structure. Using a simple effective mass theory, we model the energy shift for the first excited state for (CdSe)ZnS and (CdSe)CdS dots with varying shell thickness. Finally, we characterize the...

(CdSe)ZnS Core-Shell Quantum Dots - Synthesis and Characterization of a Size Series of Highly Luminescent Nanocrystallites

This Review summarizes recent progress in the development of polymer solar cells. It covers the scientific origins and basic properties of polymer solar cell technology, material requirements and device operation mechanisms, while also providing a synopsis of major achievements in the field over the past few years. Potential future developments and the applications of this technology are also briefly discussed.

Polymer solar cells

The electron injection process, which limits the electroluminescent performance of organic devices, has been enhanced tremendously by inserting a layer of LiF with appropriate thickness between the cathode and a quinacridone doped organic layer. Devices with an Al/LiF cathode demonstrated a luminance in excess of 20 000 cd/m2 and an external quantum efficiency of 3%, which is comparable to devices with a Mg/LiF cathode. These devices show maximum luminance of 45 000 cd/m2 prior to failure in continuous bias operation. For the same LiF thickness, the operating voltage for devices with Al/LiF was lower than the corresponding operating voltage for devices with Mg/LiF or Mg alone. Tunneling theory is used to explain this enhancement.

Highly efficient and bright organic electroluminescent devices with an aluminum cathode

Fiber lasers have seen progressive developments in terms of spectral coverage and linewidth, output power, pulse energy, and ultrashort pulse width since the first demonstration of a glass fiber laser in 1964. Their applications have extended into a variety of fields accordingly. In this paper, the milestones of glass fiber laser development are briefly reviewed and recent advances of high-power continuous wave, Q-switched, mode-locked, and single-frequency fiber lasers in the 1, 1.5, 2, and 3 μm regions and their applications in such areas as industry, medicine, research, defense, and security are addressed in detail.

Fiber lasers and their applications [Invited]

Quantum dots of InP, GaP and GaInP{sub 2} with diameters ranging from 20-65 {Angstrom} were synthesized as well-crystallized nanoparticles with bulk zinc blende structure. The high sample quality of the InP and GaP QDs results in excitonic features in the absorption spectra. The GaP and GaInP{sub 2} QD colloids exhibited very intense (quantum yields of 15-25%) visible photoluminescence at room temperature. The photoluminescence for InP preparations showed two emission bands: one band in the visible at the band edge of the QD (50 nm Stokes shift), and a second band above 800 nm. The near-IR PL is attributed to deep traps, presumably phosphorus vacancies on the QD surface. This band disappears after activation of particles by controlled addition of etchant. In that case very intense band-edge emission (quantum yield 30% at room temperature and 60% at 10 K) was obtained. The QDs were characterized by TEM, SAXS, AFM, powder x-ray diffraction, steady state optical absorption and photoluminescence spectroscopy, ps to ns transient photoluminescence spectroscopy, and fs to ps pump-probe absorption (i.e., hole-burning) spectroscopy. Results will also be reported on efforts to produce ordered arrays of InP QDs.

Synthesis and Characterization of InP, GaP, and GaInP2 Quantum Dots

We present a compact integrated fiber laser with more than 200 mW of output power. It combines polarized fiber output with very narrow linewidth of less than 2 kHz. The coherence length of the laser is measured to be longer than 5 km. The laser features high mode stability of less than /spl plusmn/10 MHz over hours. The relative intensity noise (RIN) spectrum is dominated by a peak at the relaxation oscillation frequency and is shot-noise limited otherwise. The RIN peak at 1 MHz is reduced to /spl sim/-130 dB/Hz by integrating a negative feedback circuit. In addition to thermal wavelength tuning, the laser frequency can be modulated at a bandwidth of up to 10 kHz via the piezoelectric effect.

Low-noise narrow-linewidth fiber laser at 1550 nm (June 2003)

We report a simple optical sensing device capable of measuring the refractive index of liquids propagating in microfluidic channels. The sensor is based on a single-mode optical fiber that is tapered to submicrometer dimensions and immersed in a transparent curable soft polymer. A channel for liquid analyte is created in the immediate vicinity of the taper waist. Light propagating through the tapered section of the fiber extends into the channel, making the optical loss in the system sensitive to the refractive-index difference between the polymer and the liquid. The fabrication process and testing of the prototype sensing devices are described. The sensor can operate both as a highly responsive on–off device and in the continuous measurement mode, with an estimated accuracy of refractive-index measurement of ?5×10?4.

N. Peyghambarian

Papers

Highly efficient and bright organic electroluminescent devices with an aluminum cathode

Fiber lasers and their applications [Invited]

Synthesis and Characterization of InP, GaP, and GaInP2 Quantum Dots

Low-noise narrow-linewidth fiber laser at 1550 nm (June 2003)

Evanescent field-based optical fiber sensing device for measuring the refractive index of liquids in microfluidic channels