Catalysts based on single atoms of scarce precious metals can lead to more efficient use through enhanced reactivity and selectivity. However, single atoms on catalyst supports can be mobile and aggregate into nanoparticles when heated at elevated temperatures. High temperatures are detrimental to catalyst performance unless these mobile atoms can be trapped. We used ceria powders having similar surface areas but different exposed surface facets. When mixed with a platinum/aluminum oxide catalyst and aged in air at 800°C, the platinum transferred to the ceria and was trapped. Polyhedral ceria and nanorods were more effective than ceria cubes at anchoring the platinum. Performing synthesis at high temperatures ensures that only the most stable binding sites are occupied, yielding a sinter-resistant, atomically dispersed catalyst.

Thermally stable single-atom platinum-on-ceria catalysts via atom trapping

Progress and recent trends in homogeneous charge compression ignition (HCCI) engines

The atmospheric effects of soot aerosols include interference with radiative transfer, visibility impairment, and alteration of cloud formation and are highly sensitive to the manner by which soot is internally mixed with other aerosol constituents. We present experimental studies to show that soot particles acquire a large mass fraction of sulfuric acid during atmospheric aging, considerably altering their properties. Soot particles exposed to subsaturated sulfuric acid vapor exhibit a marked change in morphology, characterized by a decreased mobility-based diameter but an increased fractal dimension and effective density. These particles experience large hygroscopic size and mass growth at subsaturated conditions (<90% relative humidity) and act efficiently as cloud-condensation nuclei. Coating with sulfuric acid and subsequent hygroscopic growth enhance the optical properties of soot aerosols, increasing scattering by ≈10-fold and absorption by nearly 2-fold at 80% relative humidity relative to fresh particles. In addition, condensation of sulfuric acid is shown to occur at a similar rate on ambient aerosols of various types of a given mobility size, regardless of their chemical compositions and microphysical structures. Representing an important mechanism of atmospheric aging, internal mixing of soot with sulfuric acid has profound implications on visibility, human health, and direct and indirect climate forcing.

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Variability in morphology, hygroscopicity, and optical properties of soot aerosols during atmospheric processing

Combustion instability is investigated in the case of a multiple inlet combustor with dump. It is shown that low-frequency instabilities are acoustically coupled and occur at the eigenfrequencies of the system. Using spark-schlieren and a special phase-average imaging of the C 2 -radical emission, the fluid-mechanical processes involved in a vortex-driven mode of instability are investigated. The phase-average images provide maps of the local non-steady heat release. From the data collected on the combustor the processes of vortex shedding, growth, interactions and burning are described. The phases between the pressure, velocity and heat-release fluctuations are determined. The implications of the global Rayleigh criterion are verified and a mechanism for low-frequency vortex-driven instabilities is proposed.

https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0022112087000958

Nick Collings

Papers

The effective density and fractal dimension of particles emitted from a light-duty diesel vehicle with a diesel oxidation catalyst

New method for particle mass classification—the Couette centrifugal particle mass analyzer

Unipolar diffusion charging of aerosol particles in the transition regime

The fast-response flame ionization detector

A Fast Response Particulate Spectrometer for Combustion Aerosols