Over the past three decades a new spectroscopic technique with unique possibilities has emerged. Based on coherent and time-resolved detection of the electric field of ultrashort radiation bursts in the far-infrared, this technique has become known as terahertz time-domain spectroscopy (THz-TDS). In this review article the authors describe the technique in its various implementations for static and time-resolved spectroscopy, and illustrate the performance of the technique with recent examples from solid-state physics and physical chemistry as well as aqueous chemistry. Examples from other fields of research, where THz spectroscopic techniques have proven to be useful research tools, and the potential for industrial applications of THz spectroscopic and imaging techniques are discussed.

Terahertz spectroscopy and imaging – Modern techniques and applications

Science and technologies based on terahertz frequency electromagnetic radiation (100 GHz–30 THz) have developed rapidly over the last 30 years. For most of the 20th Century, terahertz radiation, then referred to as sub-millimeter wave or far-infrared radiation, was mainly utilized by astronomers and some spectroscopists. Following the development of laser based terahertz time-domain spectroscopy in the 1980s and 1990s the field of THz science and technology expanded rapidly, to the extent that it now touches many areas from fundamental science to 'real world' applications. For example THz radiation is being used to optimize materials for new solar cells, and may also be a key technology for the next generation of airport security scanners. While the field was emerging it was possible to keep track of all new developments, however now the field has grown so much that it is increasingly difficult to follow the diverse range of new discoveries and applications that are appearing. At this point in time, when the field of THz science and technology is moving from an emerging to a more established and interdisciplinary field, it is apt to present a roadmap to help identify the breadth and future directions of the field. The aim of this roadmap is to present a snapshot of the present state of THz science and technology in 2017, and provide an opinion on the challenges and opportunities that the future holds. To be able to achieve this aim, we have invited a group of international experts to write 18 sections that cover most of the key areas of THz science and technology. We hope that The 2017 Roadmap on THz science and technology will prove to be a useful resource by providing a wide ranging introduction to the capabilities of THz radiation for those outside or just entering the field as well as providing perspective and breadth for those who are well established. We also feel that this review should serve as a useful guide for government and funding agencies.

https://iopscience.iop.org/article/10.1088/1361-6463/50/4/043001/pdf

The 2017 terahertz science and technology roadmap

According to Edholm’s law, the demand for point-to-point bandwidth in wireless short-range communications has doubled every 18 months over the last 25 years It can be predicted that data rates of around 5–10 Gb/s will be required in ten years In order to achieve 10 Gb/s data rates, the carrier frequencies need to be increased beyond 100 GHz Over the past ten years, several groups have considered the prospects of using sub-terahertz (THz) and THz waves (100–2000 GHz) as a means to transmit data wirelessly Some of the reported advantages of THz communications links are inherently higher bandwidth compared to millimeter wave links, less susceptibility to scintillation effects than infrared wireless links, and the ability to use THz links for secure communications Our goal of this paper is to provide a comprehensive review of wireless sub-THz and THz communications

Review of terahertz and subterahertz wireless communications

This Review summarizes recent developments in the field of responsive photonic crystal structures, including principles for design and fabrication and many strategies for applications, for example as optical switches or chemical and biological sensors. A number of fabrication methods are now available to realize responsive photonic structures, the majority of which rely on self-assembly processes to achieve ordering. Compared with microfabrication techniques, self-assembly approaches have lower processing costs and higher production efficiency, however, major efforts are still needed to further develop such approaches. In fact, some emerging techniques such as spin coating, magnetic assembly, and flow-induced self-assembly have already shown great promise in overcoming current challenges. When designing new systems with improved performance, it is always helpful to bear in mind the lessons learnt from natural photonic structures.

Responsive photonic crystals.

The increasing demand of unoccupied and unregulated bandwidth for wireless communication systems will inevitably lead to the extension of operation frequencies toward the lower THz frequency range. Higher carrier frequencies will allow for fast transmission of huge amounts of data as needed for new emerging applications. Despite the tremendous hurdles that have to be overcome with regard to sources and detectors, circuit and antenna technology and system architecture to realize ultrafast data transmission in a scenario with extensive transmission loss, a new area of research is beginning to form. In this article we give an overview of emerging technologies and system research that might lead to ubiquitous THz communication systems in the future.

A Review on Terahertz Communications Research

Terahertz (THz) spectroscopy, and especially THz imaging, holds large potential in the field of nondestructive, contact-free testing. The ongoing advances in the development of THz systems, as well as the appearance of the first related commercial products, indicate that large-scale market introduction of THz systems is rapidly approaching. We review selected industrial applications for THz systems, comprising inline monitoring of compounding processes, plastic weld joint inspection, birefringence analysis of fiber-reinforced components, water distribution monitoring in polymers and plants, as well as quality inspection of food products employing both continuous wave and pulsed THz systems.

Terahertz imaging: applications and perspectives

Many time-domain terahertz applications require systems with high bandwidth, high signal-to-noise ratio and fast measurement speed. In this paper we present a terahertz time-domain spectrometer based on 1550 nm fiber laser technology and InGaAs photoconductive switches. The delay stage offers both a high scanning speed of up to 60 traces / s and a flexible adjustment of the measurement range from 15 ps – 200 ps. Owing to a precise reconstruction of the time axis, the system achieves a high dynamic range: a single pulse trace of 50 ps is acquired in only 44 ms, and transformed into a spectrum with a peak dynamic range of 60 dB. With 1000 averages, the dynamic range increases to 90 dB and the measurement time still remains well below one minute. We demonstrate the suitability of the system for spectroscopic measurements and terahertz imaging.

/pdf/terahertz-time-domain-spectrometer-with-90-db-peak-dynamic-595yrugpsz.pdf

Terahertz-time domain spectrometer with 90 dB peak dynamic range

This paper is a survey of existing and upcoming industrial applications of terahertz technologies, comprising sections on polymers, paint and coatings, pharmaceuticals, electronics, petrochemicals, gas sensing, and paper and wood industries. Finally, an estimate of the market size and growth rates is given, as obtained from a comparison of market reports.

https://www.mdpi.com/1424-8220/19/19/4203/pdf

Industrial Applications of Terahertz Sensing: State of Play.

Monitoring polymeric compounding processes inline with THz time-domain spectroscopy

We present a low-cost terahertz wave plate based on form birefringence fabricated using ordinary paper. Measurements of the transfer function of the wave plate between polarizers closely agree with predictions based on the measured complex indices of refraction of the effective medium. For the design frequency, the dependence on wave plate angle also agrees with theory.

Nico Vieweg

Papers

Terahertz imaging: applications and perspectives

Terahertz-time domain spectrometer with 90 dB peak dynamic range

Industrial Applications of Terahertz Sensing: State of Play.

Monitoring polymeric compounding processes inline with THz time-domain spectroscopy

Paper terahertz wave plates