This chapter reviews the present-day composition of the continental crust, the methods employed to derive these estimates, and the implications of the continental crust composition for the formation of the continents, Earth differentiation, and its geochemical inventories. We review the composition of the upper, middle, and lower continental crust. We then examine the bulk crust composition and the implications of this composition for crust generation and modification processes. Finally, we compare the Earth's crust with those of the other terrestrial planets in our solar system and speculate about what unique processes on Earth have given rise to this unusual crustal distribution.

/pdf/composition-of-the-continental-crust-2hxz49vsod.pdf

Composition of the Continental Crust

http://www.zetaware.com/public/McKenzie_1978.pdf

Some remarks on the development of sedimentary basins

A survey is given of the dimensions and composition of the present continental crust. The abundances of immobile elements in sedimentary rocks are used to establish upper crustal composition. The present upper crustal composition is attributed largely to intracrustal differentiation resulting in the production of granites senso lato. Underplating of the crust by ponded basaltic magmas is probably a major source of heat for intracrustal differentiation. The contrast between the present upper crustal composition and that of the Archean upper crust is emphasized. The nature of the lower crust is examined in the light of evidence from granulites and xenoliths of lower crustal origin. It appears that the protoliths of most granulite facies exposures are more representative of upper or middle crust and that the lower crust has a much more basic composition than the exposed upper crust. There is growing consensus that the crust grows episodically, and it is concluded that at least 60% of the crust was emplaced by the late Archean (ca. 2.7 eons, or 2.7 Ga). There appears to be a relationship between episodes of continental growth and differentiation and supercontinental cycles, probably dating back at least to the late Archean. However, such cycles do not explain the contrast in crustal compositions between Archean and post-Archean. Mechanisms for deriving the crust from the mantle are considered, including the role of present-day plate tectonics and subduction zones. It is concluded that a somewhat different tectonic regime operated in the Archean and was responsible for the growth of much of the continental crust. Archean tonalites and trond-hjemites may have resulted from slab melting and/or from melting of the Archean mantle wedge but at low pressures and high temperatures analogous to modern boninites. In contrast, most andesites and subduction-related rocks, now the main contributors to crustal growth, are derived ultimately from the mantle wedge above subduction zones. The cause of the contrast between the processes responsible for Archean and post-Archean crustal growth is attributed to faster subduction of younger, hotter oceanic crust in the Archean (ultimately due to higher heat flow) compared with subduction of older, cooler oceanic crust in more recent times. A brief survey of the causes of continental breakup reveals that neither plume nor lithospheric stretching is a totally satisfactory explanation. Speculations are presented about crustal development before 4000 m.y. ago. The terrestrial continental crust appears to be unique compared with crusts on other planets and satellites in the solar system, ultimately a consequence of the abundant free water on the Earth.

The geochemical evolution of the continental crust

A global plate motion model, named NUVEL-1, which describes current plate motions between 12 rigid plates is described, with special attention given to the method, data, and assumptions used Tectonic implications of the patterns that emerged from the results are discussed It is shown that wide plate boundary zones can form not only within the continental lithosphere but also within the oceanic lithosphere; eg, between the Indian and Australian plates and between the North American and South American plates Results of the model also suggest small but significant diffuse deformation of the oceanic lithosphere, which may be confined to small awkwardly shaped salients of major plates

Current plate motions

SUMMARY 
We determine best-fitting Euler vectors, closure-fitting Euler vectors, and a new global model (NUVEL-1) describing the geologically current motion between 12 assumed-rigid plates by inverting plate motion data we have compiled, critically analysed, and tested for self-consistency. We treat Arabia, India and Australia, and North America and South America as distinct plates, but combine Nubia and Somalia into a single African plate because motion between them could not be reliably resolved. The 1122 data from 22 plate boundaries inverted to obtain NUVEL-1 consist of 277 spreading rates, 121 transform fault azimuths, and 724 earthquake slip vectors. We determined all rates over a uniform time interval of 3.0m.y., corresponding to the centre of the anomaly 2A sequence, by comparing synthetic magnetic anomalies with observed profiles. The model fits the data well. Unlike prior global plate motion models, which systematically misfit some spreading rates in the Indian Ocean by 8–12mm yr−1, the systematic misfits by NUVEL-1 nowhere exceed ∼3 mm yr−1. The model differs significantly from prior global plate motion models. For the 30 pairs of plates sharing a common boundary, 29 of 30 P071, and 25 of 30 RM2 Euler vectors lie outside the 99 per cent confidence limits of NUVEL-1. Differences are large in the Indian Ocean where NUVEL-1 plate motion data and plate geometry differ from those used in prior studies and in the Pacific Ocean where NUVEL-1 rates are systematically 5–20 mm yr−1 slower than those of prior models. The strikes of transform faults mapped with GLORIA and Seabeam along the Mid-Atlantic Ridge greatly improve the accuracy of estimates of the direction of plate motion. These data give Euler vectors differing significantly from those of prior studies, show that motion about the Azores triple junction is consistent with plate circuit closure, and better resolve motion between North America and South America. Motion of the Caribbean plate relative to North or South America is about 7 mm yr−1 slower than in prior global models. Trench slip vectors tend to be systematically misfit wherever convergence is oblique, and best-fitting poles determined only from trench slip vectors differ significantly from their corresponding closure-fitting Euler vectors. The direction of slip in trench earthquakes tends to be between the direction of plate motion and the normal to the trench strike. Part of this bias may be due to the neglect of lateral heterogeneities of seismic velocities caused by cold subducting slabs, but the larger part is likely caused by independent motion of fore-arc crust and lithosphere relative to the overriding plate.

The available data, mainly topography, geoid, and heat flow, describing hotspots worldwide are examined to constrain the mechanisms for swell uplift and to obtain fluxes and excess temperatures of mantle plumes. Swell uplift is caused mainly by excess temperatures that move with the lithosphere plate and to a lesser extent hot asthenosphere near the hotspot. The volume, heat, and buoyancy fluxes of hotspots are computed from the cross-sectional areas of swells, the shapes of noses of swells, and, for on ridge hotspots, the amount of ascending material needed to supply the length of ridge axis which has abnormally high elevation and thick crust. The buoyancy fluxes range over a factor of 20 with Hawaii, 8.7 Mg s -1, the largest. The buoyancy flux for Iceland is 1.4 Mg s -1 which is similar to the flux of Cape Verde. The excess temperature of both on-ridge and off-ridge hotspots is around the 200oC value inferred from petrology but is not tightly constrained by geophysical considerations. This observation, the similarity of the fluxes of on-ridge and offridge plumes, and the tendency for hotspots to cross the ridge indicate that similar plumes are likely to cause both types of hotspots. The buoyancy fluxes of 37 hotspots are estimated; the global buoyancy flux is 50 Mg s -1, which is equivalent to a globally averaged surface heat flow of 4 mWm -2 from core sources and would cool the core at a rate of 50 o C b.y. -1. Based on a thermal model and the assumption that the likelihood of subduction is independent of age, most of the heat from hotspots is implaced in the lower lithosphere and later subducted. I.NTRODUCWION ridge plumes using Iceland as an example. The geometry of flow implied by the assumed existence of a low viscosity Linear seamount chains, such as the Hawaiian Islands, are asthenospheric channel is illustrated by this exercise. Then the frequently attributed to mantle plumes which ascend from deep methods for obtaining the flux of plumes on a rapidly moving in the Earth, perhaps the core-mantle boundary. The excessive plate are discussed with Hawaii as an example. These methods volcanism of on-ridge hotspots, such as Iceland, is also often involve determining the flux from the plume from the crossattributed to plumes. If on-ridge and midplate hotspots are sectional area of the swell and taking advantage of the kinematreally manifestations of the same phenomenon, one would ics of the interaction of asthenospheric flow away from the expect that the temperature and flux of the upwelling material plume and asthenospheric flow induced by the drag of the would be similar under both features. In particular, the core- lithospheric plate. The methods for extending this approach to mantle boundary is expected to be nearly isothermal so that the hotspots on slowly moving plates are then discussed which Cape temperature of plumes ascending from the basal boundary layer Verde as an example. An estimate of the global mass and heat should be the same globally provided that cooling by entrain- transfer by plumes is then obtained by applying the methods to ment of nearby material and thermal conduction are minor. 34 additional hotspots. The magnitude of this total estimated Finally, the global heat loss from plumes should imply a reason- flux is compatible with the heat flux expected from cooling the

http://www.mantleplumes.org/WebDocuments/Sleep1990.pdf

Hotspots and Mantle Plumes' Some Phenomenology

Earth is over 4,500 million years old. Massive bombardment of the planet took place for the first 500–700 million years, and the largest impacts would have been capable of sterilizing the planet. Probably until 4,000 million years ago or later, occasional impacts might have heated the ocean over 100 °C. Life on Earth dates from before about 3,800 million years ago, and is likely to have gone through one or more hot-ocean 'bottlenecks'. Only hyperthermophiles (organisms optimally living in water at 80–110 °C) would have survived. It is possible that early life diversified near hydrothermal vents, but hypotheses that life first occupied other pre-bottleneck habitats are tenable (including transfer from Mars on ejecta from impacts there). Early hyperthermophile life, probably near hydrothermal systems, may have been non-photosynthetic, and many housekeeping proteins and biochemical processes may have an original hydrothermal heritage. The development of anoxygenic and then oxygenic photosynthesis would have allowed life to escape the hydrothermal setting. By about 3,500 million years ago, most of the principal biochemical pathways that sustain the modern biosphere had evolved, and were global in scope.

The habitat and nature of early life

The geology of northern and central Africa is characterized by broad plateaux, narrower swells and volcanism occurring from ∼45 Myr ago to the present. The greatest magma volumes occur on the >1,000-km-wide Ethiopian and east African plateaux, which are transected by the Red Sea, Gulf of Aden and east African rift systems, active since the late Oligocene epoch. Evidence for one or more mantle plumes having impinged beneath the plateaux comes from the dynamic compensation inferred from gravity studies, the generally small degrees of extension observed and the geochemistry of voluminous eruptive products1,2,3,4. Here we present a model of a single large plume impinging beneath the Ethiopian plateau that takes into account lateral flow and ponding of plume material in pre-existing zones of lithospheric thinning5. We show that this single plume can explain the distribution and timing of magmatism and uplift throughout east Africa. The thin lithosphere beneath the Mesozoic–Palaeogene rifts and passive margins of Africa and Arabia guides the lateral flow of plume material west to the Cameroon volcanic line and south to the Comoros Islands. Our results demonstrate the strong control that the lithosphere exerts on the spatial distribution of plume-related melting and magmatism.

Cenozoic magmatism throughout east Africa resulting from impact of a single plume

The crustal Urey cycle of CO2 involving silicate weathering and metamorphism acts as a dynamic climate buffer. In this cycle, warmer temperatures speed silicate weathering and carbonate formation, reducing atmospheric CO2 and thereby inducing global cooling. Over long periods of time, cycling of CO2 into and out of the mantle also dynamically buffers CO2. In the mantle cycle, CO2 is outgassed at ridge axes and island arcs, while subduction of carbonatized oceanic basalt and pelagic sediments returns CO2 to the mantle. Negative feedback is provided because the amount of basalt carbonatization depends on CO2 in seawater and therefore on CO2 in the air. On the early Earth, processes involving tectonics were more vigorous than at present, and the dynamic mantle buffer dominated over the crustal one. The mantle cycle would have maintained atmospheric and oceanic CO2 reservoirs at levels where the climate was cold in the Archean unless another greenhouse gas was important. Reaction of CO2 with impact ejecta and its eventual subduction produce even lower levels of atmospheric CO2 and small crustal carbonate reservoirs in the Hadean. Despite its name, the Hadean climate would have been freezing unless tempered by other greenhouse gases.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2000JE001247

Carbon dioxide cycling and implications for climate on ancient Earth

Summary The thermal history of Atlantic continental margins resembles that of the oceanic crust as it spreads away from a mid-oceanic ridge, since the margin was formed when a ridge began spreading beneath a pre-existing continent. During break-up the thickness of the continental crust along the new margin was reduced by subarea1 erosion and subcrustal processes. Afterwards the continental shelf subsided, probably due to thermal contraction of the lithosphere. The observed subsidence rate on the Atlantic and Gulf coasts of the United States declined exponentially with a time constant of about 50My, as it does for ridges. Except for the Florida peninsula, deviations of the observed sedimentation from a smooth curve with respect to time could be associated with eustatic changes and variations in the supply of sediments. The subsidence rate of basins in the mid-continent of North America also decreases with a 50 My time constant. In Kansas a subcrustal process must have thinned the crust and initiated subsidence as a sequence of thinly bedded sediments beneath the basin is uneroded.

Norman H. Sleep

Papers

Hotspots and Mantle Plumes' Some Phenomenology

The habitat and nature of early life

Cenozoic magmatism throughout east Africa resulting from impact of a single plume

Carbon dioxide cycling and implications for climate on ancient Earth

Thermal Effects of the Formation of Atlantic Continental Margins by Continental Break up