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Olivier Dezellus

Bio: Olivier Dezellus is an academic researcher from Claude Bernard University Lyon 1. The author has contributed to research in topics: Wetting & Alloy. The author has an hindex of 20, co-authored 55 publications receiving 1180 citations. Previous affiliations of Olivier Dezellus include University of Lyon & Commissariat à l'énergie atomique et aux énergies alternatives.


Papers
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TL;DR: In this paper, the effect of interfacial reactions in removing the wetting barriers existing on many ceramic and metallic solids is discussed, and the recent results and theoretical developments concerning the reactive wetting of solids by liquid metals are reviewed.
Abstract: After a brief presentation of thermodynamics and kinetics of non-reactive wetting, the recent results and theoretical developments concerning the reactive wetting of solids by liquid metals are reviewed. A section is devoted to illustrate and discuss the effect of interfacial reactions in removing the wetting barriers existing on many ceramic and metallic solids.

158 citations

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TL;DR: In this article, the mechanisms of reaction-limited spreading of molten copper and nickel silicides on carbon substrates were studied by the dispensed drop variant of the sessile drop technique under high vacuum.

106 citations

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TL;DR: In this article, the authors investigated the thermodynamic parameters of bulk polycrystalline MoAlB and found that at temperatures above 1708 K, in vacuum and inert atmospheres, this compound incongruently melts into the binary MoB and liquid aluminum metal.
Abstract: MoAlB is the first and, so far, the only transition-metal boride that forms alumina when heated in air and is thus potentially useful for high-temperature applications. Herein, the thermal stability in argon and vacuum atmospheres and the thermodynamic parameters of bulk polycrystalline MoAlB were investigated experimentally. At temperatures above 1708 K, in vacuum and inert atmospheres, this compound incongruently melts into the binary MoB and liquid aluminum metal as confirmed by differential thermal analysis, quenching experiments, x-ray diffraction, and scanning electron microscopy. Making use of that information together with heat-capacity measurements in the 4–1000-K temperature range—successfully modeled as the sum of lattice, electronic, and dilation contributions—the standard enthalpy, entropy, and free energy of formation are computed and reported for the full temperature range. The standard enthalpy of formation of MoAlB at 298 K was found to be −132 ± 3.2 kJ/mol. Lastly, the thermal conductivity values are computed and modeled using a variation of the Slack model in the 300–1600-K temperature range.

88 citations

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TL;DR: In this article, the wettability of carbon materials by molten silicon was investigated at 1430∘C under vacuum by using the dispensed drop variant of the sessile drop technique.
Abstract: The wettability of carbon materials by molten silicon was investigated at 1430∘C under vacuum by using the dispensed drop variant of the sessile drop technique. The results are compared with data in the literature and used to contribute to a comprehensive understanding of wetting in the liquid-Si/solid-C system. Consequences on the dynamics of Liquid Silicon Infiltration (LSI) processes are discussed.

74 citations

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TL;DR: In this article, the authors present progress accomplished during the last few years in modelling the second type of wetting controlled by the reaction process at or close to the triple line, and compare the predictions of equations derived from a model describing the change in contact angle and spreading rate with time.
Abstract: In reactive metal/ceramic systems the wetting rate of small, millimeter sized droplets on smooth ceramic surfaces is controlled by the slower of two successive phenomena that intervene in the reaction process: diffusive transport of reacting species to or from the triple line, and local reaction kinetics at the triple line. The first case, of diffusive wetting, was modelled by Mortensen et al. [Scripta mater. 36 (1997) 645] a few years ago. The purpose of this paper is to present progress accomplished during the last few years in modelling the second type of wetting controlled by the reaction process at or close to the triple line. The predictions of equations derived from a model describing the change in contact angle and spreading rate with time are compared with experimental results obtained for different silicon alloys on carbon substrates.

72 citations


Cited by
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Journal ArticleDOI
01 Apr 1988-Nature
TL;DR: In this paper, a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) is presented.
Abstract: Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

9,929 citations

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TL;DR: A critical review of the M(n + 1)AX(n) phases from a materials science perspective is given in this article, where the authors discuss the potential for low-temperature synthesis, which is essential for deposition of MAX phases onto technologically important substrates.

905 citations

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TL;DR: The MAX phases are a group of layered ternary compounds with the general formula Mn+1AXn (M: early transition metal; A: group A element; X: C and/or N; n = 1-3), which combine some properties of metals such as good electrical and thermal conductivity, machinability, low hardness, thermal shock resistance and damage tolerance, with those of ceramics, such as high elastic moduli, high temperature strength, and oxidation and corrosion resistance as mentioned in this paper.
Abstract: The MAX phases are a group of layered ternary compounds with the general formula Mn+1AXn (M: early transition metal; A: group A element; X: C and/or N; n = 1–3), which combine some properties of metals, such as good electrical and thermal conductivity, machinability, low hardness, thermal shock resistance and damage tolerance, with those of ceramics, such as high elastic moduli, high temperature strength, and oxidation and corrosion resistance. The publication of papers on the MAX phases has shown an almost exponential increase in the past decade. The existence of further MAX phases has been reported or proposed. In addition to surveying this activity, the synthesis of MAX phases in the forms of bulk, films and powders is reviewed, together with their physical, mechanical and corrosion/oxidation properties. Recent research and development has revealed potential for the practical application of the MAX phases (particularly using the pressureless sintering and physical vapour deposition coating rout...

851 citations

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TL;DR: Partial transient liquid phase (PTLP) bonding as discussed by the authors is a variant of TLP bonding that is typically used to join ceramics and has found many applications, most notably the joining and repair of Ni-based superalloy components.
Abstract: Transient liquid phase (TLP) bonding is a relatively new bonding process that joins materials using an interlayer. On heating, the interlayer melts and the interlayer element (or a constituent of an alloy interlayer) diffuses into the substrate materials, causing isothermal solidification. The result of this process is a bond that has a higher melting point than the bonding temperature. This bonding process has found many applications, most notably the joining and repair of Ni-based superalloy components. This article reviews important aspects of TLP bonding, such as kinetics of the process, experimental details (bonding time, interlayer thickness and format, and optimal bonding temperature), and advantages and disadvantages of the process. A wide range of materials that TLP bonding has been applied to is also presented. Partial transient liquid phase (PTLP) bonding is a variant of TLP bonding that is typically used to join ceramics. PTLP bonding requires an interlayer composed of multiple layers; the most common bond setup consists of a thick refractory core sandwiched by thin, lower-melting layers on each side. This article explains how the experimental details and bonding kinetics of PTLP bonding differ from TLP bonding. Also, a range of materials that have been joined by PTLP bonding is presented.

453 citations

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TL;DR: A review of the state-of-the-art in FGM can be found in this paper, where the authors present their current understanding of important issues, such as modeling, processing, microstructures and mechanical properties.
Abstract: Functionally graded materials (FGMs) represent a class of novel materials in which compositions/constituents and/or microstructures gradually change along single or multiple spatial directions, resulting in a gradual change in properties and functions which can be tailored for enhanced performance. FGMs can be fabricated using a variety of well-established processing methods; however, it is also known that there are inherent drawbacks to existing synthesis methods. As an emerging technology that provides a high degree of control over spatial resolution, additive manufacturing (AM) provides an intriguing pathway to circumvent the drawbacks of currently available methods. AM involves the selective deposition of individual layers of single or multiple materials, and as such it offers the potential of local control of composition and microstructure in multiple dimensions; such process conditions, in principle, can be tailored to construct complex FGMs with multi-dimensional and directional gradient structures. In this review paper, our current understanding of important issues, such as modeling, processing, microstructures and mechanical properties, as related to FGMs produced via AM, are described and discussed in an effort to assess the state of the art in this field as well as to provide insight into future research directions.

267 citations