scispace - formally typeset
Search or ask a question
Author

P. G. Simpson

Bio: P. G. Simpson is an academic researcher. The author has contributed to research in topics: 2,2'-Bipyridine. The author has an hindex of 2, co-authored 2 publications receiving 230 citations.

Papers
More filters

Cited by
More filters
Journal ArticleDOI
TL;DR: In this paper, Darstellung, Eigenschaften, Substituenteneffekte und Donoreigenschalkte werden zusammenfassend behandelt.

226 citations

Journal ArticleDOI
TL;DR: In this article, the synthesis of tetradentate reagents for the efficient separation of americium(III) and europium (III) is reported together with the structure of the complex formed with euro p-III.

131 citations

Journal ArticleDOI
TL;DR: In this paper, lead coordination polymers, namely, [Pb(INO)2]·3H2O (1), Pb(NO3)2 with isonicotinic acid N-oxide (HINO), or nicotinic amino acid Noxide (N-oxide) (HNNO), have been prepared by the reaction of Pb2O2 with ICN or ICN and characterized by elemental analysis, IR, and single-crystal X-ray diffraction.
Abstract: Six new lead coordination polymers, namely, [Pb(INO)2]·3H2O (1), [Pb(INO)2·NO3·H2O] (2), [Pb(INO)·Cl] (3), Na1.5[Pb2(INO)5]·0.5NO3 (4), [Pb3(NNO)4·(NO3)2·H2O] (5), and [Pb(NNO)2] (6), have been prepared by the reaction of Pb(NO3)2 with isonicotinic acid N-oxide (HINO), or nicotinic acid N-oxide (HNNO), and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. Compound 1, consisting of a one-dimensional (1D) infinite chain, is a three-dimensional (3D) supramolecular framework with a 1D rectanglar channel in which free water molecules locate. The structure of 2 consists of 1D chains built by two parallel INO ligands bridging a pair of rhombic-planar [Pb2O2] units, which is further extended into a 2D supramolecular layer via hypervalent interactions and interlayer π-π interactions. Compound 3 consists of a two-dimensional (2D) inorganic layer containing 16-membered rings, which are further linked through μ-INO to generate a unique 3D open framework. In compound 4, the self-assembly b...

116 citations