P
Pedro E. Sánchez-Jiménez
Researcher at Spanish National Research Council
Publications - 117
Citations - 5236
Pedro E. Sánchez-Jiménez is an academic researcher from Spanish National Research Council. The author has contributed to research in topics: Calcium looping & Calcination. The author has an hindex of 39, co-authored 104 publications receiving 3966 citations. Previous affiliations of Pedro E. Sánchez-Jiménez include University of Colorado Boulder & University of Cambridge.
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Kinetic analysis of complex solid-state reactions. A new deconvolution procedure.
TL;DR: A method that involves the deconvolution of the individual processes from the overall differential kinetic curves obtained under linear heating rate conditions, followed by the kinetic analysis of the discrete processes using combined kinetic analysis, is proposed.
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Combined kinetic analysis of solid-state reactions: a powerful tool for the simultaneous determination of kinetic parameters and the kinetic model without previous assumptions on the reaction mechanism.
TL;DR: A modification in the combined kinetic analysis is proposed by using an empirical equation that fits every f(alpha) of the ideal kinetic models most extensively used in the literature and even their deviations produced by particle size distributions or heterogeneities in particle morphologies.
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Critical study of the isoconversional methods of kinetic analysis
TL;DR: In this article, a critical study of the use of isoconversional methods for the kinetic analysis of non-isothermal data corresponding to processes with either a real or an apparent variation of the activation energy, E, with the reacted fraction, α, has been carried out using for the first time simulated curves.
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Kinetic model for thermal dehydrochlorination of poly(vinyl chloride)
TL;DR: In this article, a novel method for calculating degradation kinetics is presented, which has been applied to the thermal dehydrochlorination of two different samples of PVC and demonstrated the correlation between the kinetics of the thermal de-chlorination and the structure of this macromolecule.
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Generalized master plots as a straightforward approach for determining the kinetic model: The case of cellulose pyrolysis
TL;DR: In this paper, a set of experimental curves recorded under different heating schedules, i.e., linear heating rate, isothermal and constant rate thermal analysis (CRTA), has been analyzed using isoconversional and master plots methodology to discriminate the kinetic model followed by the reaction.