Philip J. Maziasz

Bio: Philip J. Maziasz is an academic researcher from Oak Ridge National Laboratory. The author has contributed to research in topics: Alloy & Creep. The author has an hindex of 40, co-authored 160 publications receiving 5830 citations. Previous affiliations of Philip J. Maziasz include United States Department of Energy.

Creep-resistant, Al2O3-forming austenitic stainless steels.

Abstract: A family of inexpensive, Al2O3-forming, high-creep strength austenitic stainless steels has been developed. The alloys are based on Fe-20Ni-14Cr-2.5Al weight percent, with strengthening achieved through nanodispersions of NbC. These alloys offer the potential to substantially increase the operating temperatures of structural components and can be used under the aggressive oxidizing conditions encountered in energy-conversion systems. Protective Al2O3 scale formation was achieved with smaller amounts of aluminum in austenitic alloys than previously used, provided that the titanium and vanadium alloying additions frequently used for strengthening were eliminated. The smaller amounts of aluminum permitted stabilization of the austenitic matrix structure and made it possible to obtain excellent creep resistance. Creep-rupture lifetime exceeding 2000 hours at 750 degrees C and 100 megapascals in air, and resistance to oxidation in air with 10% water vapor at 650 degrees and 800 degrees C, were demonstrated.

Recent advances in B2 iron aluminide alloys : deformation, fracture and alloy design

Abstract: This paper reviews the deformation, fracture and alloy design of B2 iron aluminides based on FeAl. Moisture-induced environmental embrittlement is shown to be a leading cause of low tensile ductility and brittle cleavage fracture of Ferich FeAl alloys at ambient temperatures. With increasing Al concentration, two other factors, namely intrinsic grain-boundary weakness and quenched-in vacancies become important in limiting the tensile ductility of FeAl alloys. FeAl alloys show a yield-strength anomaly at intermediate temperatures. Recent work indicates that the anomaly is a result of hardening by thermal vacancies at elevated temperatures. The understanding of the deformation and fracture behavior has led to the development of FeAl-base alloys and composites with improved metallurgical and mechanical properties for structural applications. These FeAl-based alloys can be prepared by melting and casting or by powder processing. The unique combination of the excellent oxidation and carburization/sulfidation resistance coupled with relatively low material density and good mechanical properties at room and elevated temperatures has sparked industrial interest in FeAl alloys and composites for a number of applications.

Recent developments in stainless steels

Abstract: This article presents an overview of the developments in stainless steels made since the 1990s. Some of the new applications that involve the use of stainless steel are also introduced. A brief introduction to the various classes of stainless steels, their precipitate phases and the status quo of their production around the globe is given first. The advances in a variety of subject areas that have been made recently will then be presented. These recent advances include (1) new findings on the various precipitate phases (the new J phase, new orientation relationships, new phase diagram for the Fe–Cr system, etc.); (2) new suggestions for the prevention/mitigation of the different problems and new methods for their detection/measurement and (3) new techniques for surface/bulk property enhancement (such as laser shot peening, grain boundary engineering and grain refinement). Recent developments in topics like phase prediction, stacking fault energy, superplasticity, metadynamic recrystallisation and the calculation of mechanical properties are introduced, too. In the end of this article, several new applications that involve the use of stainless steels are presented. Some of these are the use of austenitic stainless steels for signature authentication (magnetic recording), the utilisation of the cryogenic magnetic transition of the sigma phase for hot spot detection (the Sigmaplugs), the new Pt-enhanced radiopaque stainless steel (PERSS) coronary stents and stainless steel stents that may be used for magnetic drug targeting. Besides recent developments in conventional stainless steels, those in the high-nitrogen, low-Ni (or Ni-free) varieties are also introduced. These recent developments include new methods for attaining very high nitrogen contents, new guidelines for alloy design, the merits/demerits associated with high nitrogen contents, etc.

Laser Material Processing

Abstract: In the laser treatment of a workpiece (9), e.g. for surface hardening, melting, alloying, cladding, welding or cutting, the adverse effect of reflectivity of the surface, when a pure, monochromatic laser (6) is used, is remedied by the simultaneous application of a relatively shorter wavelength beam (1). The two beams (1)(5) may be combined by a beam coupler (4) or may reach the workpiece (9) by separate optical paths (not shown). The shorter wavelength beam (1) improves the coupling efficiency of the higher- powered laser beam (5).

Additively manufactured hierarchical stainless steels with high strength and ductility

Abstract: Many traditional approaches for strengthening steels typically come at the expense of useful ductility, a dilemma known as strength-ductility trade-off. New metallurgical processing might offer the possibility of overcoming this. Here we report that austenitic 316L stainless steels additively manufactured via a laser powder-bed-fusion technique exhibit a combination of yield strength and tensile ductility that surpasses that of conventional 316L steels. High strength is attributed to solidification-enabled cellular structures, low-angle grain boundaries, and dislocations formed during manufacturing, while high uniform elongation correlates to a steady and progressive work-hardening mechanism regulated by a hierarchically heterogeneous microstructure, with length scales spanning nearly six orders of magnitude. In addition, solute segregation along cellular walls and low-angle grain boundaries can enhance dislocation pinning and promote twinning. This work demonstrates the potential of additive manufacturing to create alloys with unique microstructures and high performance for structural applications.

Recent Developments in Irradiation-Resistant Steels

Abstract: Advanced fission and future fusion energy will require new high-performance structural alloys with outstanding properties that are sustained under long-term service in ultrasevere environments, including neutron damage producing up to 200 atomic displacements per atom and, for fusion, 2000 appm of He. Following a brief description of irradiation damage and damage resistance, we focus on an emerging class of nanostructured ferritic alloys (NFAs) that show promise for meeting these challenges. NFAs contain an ultrahigh density of Y-Ti-O-enriched dispersion-strengthening nanofeatures (NFs) that, along with fine grains and high dislocation densities, provide remarkably high tensile, creep, and fatigue strength. The NFs are stable under irradiation up to 800°C and trap He in fine-scale bubbles, suppressing void swelling and fast fracture embrittlement at lower temperatures and creep rupture embrittlement at high temperatures. The current state of the development and understanding of NFAs is described, along wi...