Piergiulio Cappelletti

Bio: Piergiulio Cappelletti is an academic researcher from University of Naples Federico II. The author has contributed to research in topics: Phillipsite & Zeolite. The author has an hindex of 29, co-authored 94 publications receiving 2160 citations.

Phillipsite and Al-tobermorite mineral cements produced through low-temperature water-rock reactions in Roman marine concrete

Abstract: Author(s): Jackson, MD; Mulcahy, SR; Chen, H; Li, Y; Li, Q; Cappelletti, P; Wenk, HR | Abstract: Pozzolanic reaction of volcanic ash with hydrated lime is thought to dominate the cementing fabric and durability of 2000-year-old Roman harbor concrete. Pliny the Elder, however, in first century CE emphasized rock-like cementitious processes involving volcanic ash (pulvis) "that as soon as it comes into contact with the waves of the sea and is submerged becomes a single stone mass (fierem unum lapidem), impregnable to the waves and every day stronger" (Naturalis Historia 35.166). Pozzolanic crystallization of Al-tobermorite, a rare, hydrothermal, calcium-silicate-hydrate mineral with cation exchange capabilities, has been previously recognized in relict lime clasts of the concrete. Synchrotron-based X-ray microdiffraction maps of cementitious microstructures in Baianus Sinus and Portus Neronis submarine breakwaters and a Portus Cosanus subaerial pier now reveal that Al-tobermorite also occurs in the leached perimeters of feldspar fragments, zeolitized pumice vesicles, and in situ phillipsite fabrics in relict pores. Production of alkaline pore fluids through dissolution-precipitation, cation-exchange and/or carbonation reactions with Campi Flegrei ash components, similar to processes in altered trachytic and basaltic tuffs, created multiple pathways to post-pozzolanic phillipsite and Al-tobermorite crystallization at ambient seawater and surface temperatures. Long-term chemical resilience of the concrete evidently relied on water-rock interactions, as Pliny the Elder inferred. Raman spectroscopic analyses of Baianus Sinus Al-tobermorite in diverse microstructural environments indicate a cross-linked structure with Al3+ substitution for Si4+ in Q3 tetrahedral sites, and suggest coupled [Al3++Na+] substitution and potential for cation exchange. The mineral fabrics provide a geoarchaeological prototype for developing cementitious processes through low-temperature rock-fluid interactions, subsequent to an initial phase of reaction with lime that defines the activity of natural pozzolans. These processes have relevance to carbonation reactions in storage reservoirs for CO2 in pyroclastic rocks, production of alkali-activated mineral cements in maritime concretes, and regenerative cementitious resilience in waste encapsulations using natural volcanic pozzolans.

Genesis of zeolites in the Neapolitan Yellow Tuff: geological, volcanological and mineralogical evidence

Abstract: The study proposes a model by which a thick succession of volcanic tuffs can be zeolitized by alteration of pyroclastic material in the presence of sufficient eruptive water and at temperatures close to water vapour condensation. In the case of phreatomagmatic products, the model simplifies interpretation of problematic deposits that exhibit pronounced vertical and lateral variation in lithification grade. A major feature of the model is that thick zeolitized tuffs can be formed during emplacement of pyroclastic products, in marked contrast to later alteration in an open hydrologic system. Geological, volcanological and mineralogical data for the Neapolitan Yellow Tuff, a widespread trachytic pyroclastic deposit outcropping around Campi Flegrei (Southern Italy), have been used to infer the physico-chemical conditions that determined mineral genesis. This tuff shows a reduction in lithification grade towards the base, top and with distance from the vent and very variable zeolitization within the lithified portion. We suggest that during initial emplacement the erupted products chilled against the ground, inhibiting zeolite crystallization. During rapid deposition of the thick, wet succession thermal insulation allowed the persistence of elevated temperatures for a time sufficient for enhancement of hydration-dissolution processes in the volcanic glass. The highly reactive alkali-trachytic glass quickly buffered the acid pH of the system, favouring phillipsite crystallization followed by chabazite nucleation. The variable zeolite content reflects fluctuating emplacement conditions (e.g. changes in water content and temperature). Cooling of the upper and relatively thin distal deposits inhibited the zeolitization process, thereby preserving the primary unlithified deposit.

Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) on Mars Reconnaissance Orbiter (MRO)

Abstract: [1] The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) is a hyperspectral imager on the Mars Reconnaissance Orbiter (MRO) spacecraft. CRISM consists of three subassemblies, a gimbaled Optical Sensor Unit (OSU), a Data Processing Unit (DPU), and the Gimbal Motor Electronics (GME). CRISM's objectives are (1) to map the entire surface using a subset of bands to characterize crustal mineralogy, (2) to map the mineralogy of key areas at high spectral and spatial resolution, and (3) to measure spatial and seasonal variations in the atmosphere. These objectives are addressed using three major types of observations. In multispectral mapping mode, with the OSU pointed at planet nadir, data are collected at a subset of 72 wavelengths covering key mineralogic absorptions and binned to pixel footprints of 100 or 200 m/pixel. Nearly the entire planet can be mapped in this fashion. In targeted mode the OSU is scanned to remove most along-track motion, and a region of interest is mapped at full spatial and spectral resolution (15–19 m/pixel, 362–3920 nm at 6.55 nm/channel). Ten additional abbreviated, spatially binned images are taken before and after the main image, providing an emission phase function (EPF) of the site for atmospheric study and correction of surface spectra for atmospheric effects. In atmospheric mode, only the EPF is acquired. Global grids of the resulting lower data volume observations are taken repeatedly throughout the Martian year to measure seasonal variations in atmospheric properties. Raw, calibrated, and map-projected data are delivered to the community with a spectral library to aid in interpretation.