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Author

Prem S. Felix

Bio: Prem S. Felix is an academic researcher from Deen Dayal Upadhyay Gorakhpur University. The author has contributed to research in topics: Thermal decomposition. The author has an hindex of 1, co-authored 1 publications receiving 47 citations.

Papers
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Journal ArticleDOI
TL;DR: The present review deals with the chemistry and thermolysis of NTO and plausible decomposition pathways have been described and methods of detection as well as safe disposal ofNTO have been mentioned.

54 citations


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Journal ArticleDOI
TL;DR: This paper also reviews work done on primary explosives of current and futuristic interest based on energetic co-ordination compounds and highlights the important contributions made by the various researchers in the frontier areas energetic ballistic modifiers, energetic binders and energetic plasticizers.

766 citations

Journal ArticleDOI
TL;DR: In this paper, the structure of 3-amino-1,2,4-triazolium 3-nitro-5-trifluoromethyl-1.2, 4.4, 5.5, and 5.nitroimino-tetrazolate anions were characterized using the computationally feasible DFT(B3LYP) and MP2 methods.
Abstract: Energetic salts comprised of substituted 1,2,4-triazolium and tetrazolium cations and 3-nitro-1,2,4-triazolate-5-one (NTO), 5-nitroimino-tetrazolate, 3-nitro-5-trifluoromethyl-1,2,4-triazolate, 3,5-dinitro-1,2,4-triazolate, 4,5-dinitro-imidazolate, 3,5-dinitro-pyrazolate, and 5-nitro-tetrazolate anions were synthesized and characterized The structures of 3-amino-1,2,4-triazolium 3-nitro-5-trifluoromethyl-1,2,4-triazolate (6), and 1-propyl-1,2,4-triazolium 5-nitroimino-tetrazolate (20) were confirmed by X-ray analysis Standard enthalpies of formation were calculated using the computationally feasible DFT(B3LYP) and MP2 methods in conjunction with an empirical approach based on densities of salts Cheetah 40 was used to calculate detonation properties Salts 2, 14, 20, and 21 fall into the ionic liquid class (mp < 100 °C)

165 citations

Journal ArticleDOI
TL;DR: In this article, the authors reviewed the recent work done in the frontier areas of advanced novel high energy materials, including oxidizers, binders, plasticizers, high energy density materials, and insensitive high-energy materials.
Abstract: Enhanced performance of propellants and explosives is the most sought-after attribute for ambitious research programs in the field of high energy materials. Convergence of defence and space sector priorities has always kept research and development efforts in the area of propellants to the forefront. With the diminishing boundaries between rocket and gun propellants, as well as explosives, the possibility of low-vulnerable munitions with high performance potentials and spin-off advantages of research on rocket propellants are also emerging on the forefront. At the same time, an increasing predominance of missiles in today’s military warfare, as well as the space sector, has brought the issue of pollution by chlorine-containing combustion products of modern ammonium-perchlorate-based propellants into focus. A drastic transformation of high energy material technology is in offing. Research and development efforts made in this direction have brought an array of new materials into prominence. This paper reviews the recent work done in the frontier areas of advanced novel high energy materials. This paper covers the global scenario in the development of oxidizers, binders, plasticizers, high energy density materials, and insensitive high energy materials.

109 citations

Journal ArticleDOI
TL;DR: In this paper, the effect of 5-nitro-2-4-dihydro-3H-1,2,4-triazole-3-one (NTO) and two of its transition metal salts, namely Cu(nTO) 2 and Fe(nto) 3, during the combustion of composite solid propellants of hydroxyl-terminated polybutadiene (HTPB) and ammonium perchlorate (AP) has been studied.

77 citations

Journal ArticleDOI
TL;DR: In this paper, the synthesis of Cu nanoparticles by reducing CuSO 4 with hydrazine in ethylene glycol under microwave irradiation, has been described, and the catalytic activity, of CU nanoparticles on thermal decomposition of ammonium perchlorate (AP), composite solid propellants (CSPs) using thermogravimetry (TG), differential scanning calorimetry(DSC) have been measured.

66 citations