The field of phase transitions and critical phenomena continues to be active in research, producing a steady stream of interesting and fruitful results. It has moved into a central place in condensed matter studies. Statistical physics, and more specifically, the theory of transitions between states of matter, more or less defines what we know about 'everyday' matter and its transformations. The major aim of this serial is to provide review articles that can serve as standard references for research workers in the field, and for graduate students and others wishing to obtain reliable information on important recent developments.

Phase Transitions and Critical Phenomena

Spintronics, or spin electronics, involves the study of active control and manipulation of spin degrees of freedom in solid-state systems. This article reviews the current status of this subject, including both recent advances and well-established results. The primary focus is on the basic physical principles underlying the generation of carrier spin polarization, spin dynamics, and spin-polarized transport in semiconductors and metals. Spin transport differs from charge transport in that spin is a nonconserved quantity in solids due to spin-orbit and hyperfine coupling. The authors discuss in detail spin decoherence mechanisms in metals and semiconductors. Various theories of spin injection and spin-polarized transport are applied to hybrid structures relevant to spin-based devices and fundamental studies of materials properties. Experimental work is reviewed with the emphasis on projected applications, in which external electric and magnetic fields and illumination by light will be used to control spin and charge dynamics to create new functionalities not feasible or ineffective with conventional electronics.

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Spintronics: Fundamentals and applications

Within the space of a few years, hybrid organic–inorganic perovskite solar cells have emerged as one of the most exciting material platforms in the photovoltaic sector. This review describes the rapid progress that has been made in this area.

The emergence of perovskite solar cells

We review the dynamical mean-field theory of strongly correlated electron systems which is based on a mapping of lattice models onto quantum impurity models subject to a self-consistency condition. This mapping is exact for models of correlated electrons in the limit of large lattice coordination (or infinite spatial dimensions). It extends the standard mean-field construction from classical statistical mechanics to quantum problems. We discuss the physical ideas underlying this theory and its mathematical derivation. Various analytic and numerical techniques that have been developed recently in order to analyze and solve the dynamical mean-field equations are reviewed and compared to each other. The method can be used for the determination of phase diagrams (by comparing the stability of various types of long-range order), and the calculation of thermodynamic properties, one-particle Green's functions, and response functions. We review in detail the recent progress in understanding the Hubbard model and the Mott metal-insulator transition within this approach, including some comparison to experiments on three-dimensional transition-metal oxides. We present an overview of the rapidly developing field of applications of this method to other systems. The present limitations of the approach, and possible extensions of the formalism are finally discussed. Computer programs for the numerical implementation of this method are also provided with this article.

Dynamical mean-field theory of strongly correlated fermion systems and the limit of infinite dimensions

An introductory review of the central ideas in the modern theory of dynamic critical phenomena is followed by a more detailed account of recent developments in the field. The concepts of the conventional theory, mode-coupling, scaling, universality, and the renormalization group are introduced and are illustrated in the context of a simple example---the phase separation of a symmetric binary fluid. The renormalization group is then developed in some detail, and applied to a variety of systems. The main dynamic universality classes are identified and characterized. It is found that the mode-coupling and renormalization group theories successfully explain available experimental data at the critical point of pure fluids, and binary mixtures, and at many magnetic phase transitions, but that a number of discrepancies exist with data at the superfluid transition of $^{4}\mathrm{He}$.

Theory of Dynamic Critical Phenomena

The effect of spin-orbit coupling on the usual band theory of electrons in a lattice is considered. Particular attention is given to the bands in impurity semiconductors with diamond-type structure. $g$-values are calculated for electron states typical of various possible cases and it is found that different values are obtained according as to whether the Fermi level is near or distant from a band degeneracy. The spin-lattice relaxation time is calculated so that the effect of spin-orbit coupling on the wave functions is included, and times in fair agreement with those observed in silicon and alkali metals are obtained.

Theory of the Effect of Spin-Orbit Coupling on Magnetic Resonance in Some Semiconductors

The intensity of optical absorption close to the edge in semiconductors is examined using band theory together with the effective-mass approximation for the excitons. Direct transitions which occur when the band extrema on either side of the forbidden gap are at the same K, give a line spectrum and a continuous absorption of characteristically different form and intensity, according as transitions between band states at the extrema are allowed or forbidden. If the extrema are at different K values, indirect transitions involving phonons occur, giving absorption proportional to ${(\ensuremath{\Delta}E)}^{\frac{1}{2}}$ for each exciton band, and to ${(\ensuremath{\Delta}E)}^{2}$ for the continuum. The experimental results on ${\mathrm{Cu}}_{2}$O and Ge are in good qualitative agreement with direct forbidden and indirect transitions, respectively.

Intensity of Optical Absorption by Excitons

We review the methods which have been developed over the past several years to determine the behavior of solids whose properties vary randomly at the microscopic level, with principal attention to systems having composition variation on a well-defined structure (random "alloys"). We begin with a survey of the various elementary excitations and put the dynamics of electrons, phonons, magnons, and excitons into one common descriptive Hamiltonian; we then review the use of double-time thermodynamic Green's functions to determine the experimental properties of systems. Next we discuss these aspects of the problem which derive from the statistical specification of the microscopic parameters; we examine what information can and cannot be obtained from averaged Green's functions. The central portion of the review concerns methods for calculating the averaged Green's function to successively better approximation, including various self-consistent methods, and higher-order cluster effects. The last part of the review presents a comparison of theory with the experimental results of a variety of properties---optical, electronic, magnetic, and neutron scattering. An epilogue calls attention to the similarity between these problems and those of other fields where random material heterogeneity has played an essential role.

The theory and properties of randomly disordered crystals and related physical systems

The fundamental relationship between radiative lifetime and spectral linewidth of free excitons is demonstrated theoretically and experimentally for quasi 2D excitons in GaAs/AlGaAs quantum wells.

Linewidth dependence of radiative exciton lifetimes in quantum wells

The incoherent inelastic scattering cross section of slow neutrons from liquids is calculated using a simple model in which the liquid is assumed to have appreciable short range order in a quasi-crystalline form. Diffusive motion takes place in large discrete jumps, between which the atoms oscillate as in a solid. The model predicts a definite, easily calculable cross section which is not dominated by diffusion effects as when continuous diffusion is assumed, but shows a characteristic variation with angle which could be looked for experimentally. The related pair correlation functions are dominated at small r and t by vibrational effects. Although simple and extreme the model explains several aspects of the observations of Brockhouse and Pope in 1959 and others. A brief discussion of the coherent scattering cross sections for the model is given although explicit formulae are not obtained.

https://iopscience.iop.org/article/10.1088/0370-1328/77/2/319/pdf

R. J. Elliott

Papers

Theory of the Effect of Spin-Orbit Coupling on Magnetic Resonance in Some Semiconductors

Intensity of Optical Absorption by Excitons

The theory and properties of randomly disordered crystals and related physical systems

Linewidth dependence of radiative exciton lifetimes in quantum wells

Neutron Scattering from a Liquid on a Jump Diffusion Model