Rich-Catalytic Lean-burn combustion for fuel-flexible operation with ultra low emissions

In collaboration with U.S. aircraft engine companies, NASA Glenn Research Center has contributed to the advancement of low emissions combustion systems. For the High Speed Research Program (HSR), a 90% reduction in nitrogen oxides (NOx) emissions (relative to the then-current state of the art) has been demonstrated in sector rig testing at General Electric Aircraft Engines (GEAE). For the Advanced Subsonic Technology Program (AST), a 50% reduction in NOx emissions relative to the 1996 International Civil Aviation Organization (ICAO) standards has been demonstrated in sector rigs at both GEAE and Pratt & Whitney (P&W). During the Ultra Efficient Engine Technology Program (UEET), a 70% reduction in NOx emissions, relative to the 1996 ICAO standards, was achieved in sector rig testing at Glenn in the world class Advanced Subsonic Combustion Rig (ASCR) and at contractor facilities. Low NOx combustor development continues under the Fundamental Aeronautics Program. To achieve these reductions, experimental and analytical research has been conducted to advance the understanding of emissions formation in combustion processes. Lean direct injection (LDI) concept development uses advanced laser-based non-intrusive diagnostics and analytical work to complement the emissions measurements and to provide guidance for concept improvement. This paper describes emissions results from flametube tests of a 9-injection-point LDI fuel/air mixer tested at inlet pressures up to 5500 kPa. Sample results from CFD and laser diagnostics are also discussed.

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NASA Glenn High Pressure Low NOx Emissions Research

A new rich-catalytic lean-burn combustion concept (trademarked by PCI as RCL) was tested at industrial gas turbine conditions, in Solar Turbines' high-pressure (17 atm) combustion rig and in a modified Solar Turbines engine, demonstrating ultralow emissions of NO x <2 ppm and CO<10 ppm for natural gas fuel For the single-injector rig tests, an RCL catalytic reactor replaced a single swirler/injector NO x <3 ppm and CO<10 ppm were achieved over a 110°C operating range in flame temperature, including NO x < 1 ppm at about 1350°C flame temperature Combustion noise was less than 015% peak to peak Four RCL catalytic reactors were then installed in a modified (single can combustor) engine NO x emissions averaged 21 ppm over the allowable operating range for this modified engine, with CO<10 ppm and without combustion noise (less than 015% peak to peak)

Rich-Catalytic Lean-Burn Combustion for Low-Single-Digit NOx Gas Turbines

In collaboration with U.S. aircraft engine companies, NASA Glenn Research Center has contributed to the advancement of low emissions combustion systems. For the High Speed Research Program (HSR), a 90% reduction in nitrogen oxides (NOx) emissions (relative to the then-current state of the art) has been demonstrated in sector rig testing at General Electric Aircraft Engines (GEAE). For the Advanced Subsonic Technology Program (AST), a 50% reduction in NOx emissions relative to the 1996 International Civil Aviation Organization (ICAO) standards has been at demonstrated in sector rigs at both GEAE and Pratt & Whitney (P&W). During the Ultra Efficient Engine Technology Program (UEET), a 70% reduction in NOx emissions, relative to the 1996 ICAO standards, was achieved in sector rig testing at Glenn in the world class Advanced Subsonic Combustion Rig (ASCR) and at contractor facilities. Low NOx combustor development continues under the Fundamental Aeronautics Program. To achieve these reductions, experimental and analytical research has been conducted to advance the understanding of emissions formation in combustion processes. Lean direct injection (LDI) concept development uses advanced laser-based non-intrusive diagnostics and analytical work to complement the emissions measurements and to provide guidance for concept improvement. This paper describes emissions results from flametube tests of a 9- injection-point LDI fuel/air mixer tested at inlet pressures up to 5500 kPa. Sample results from CFD and laser diagnostics are also discussed.

https://ntrs.nasa.gov/api/citations/20070022362/downloads/20070022362.pdf

High Pressure Low NOx Emissions Research: Recent Progress at NASA Glenn Research Center

This paper describes the design and testing of a catalytically stabilized pilot burner for current and advanced Dry Low NO x (DLN) gas turbine combustors. In this paper, application of the catalytic pilot technology to industrial engines is described using Solar Turbines' Taurus 70 engine. The objective of the work described is to develop the catalytic pilot technology and document the emission benefits of catalytic pilot technology when compared to higher, NO x producing pilots. The catalytic pilot was designed to replace the existing pilot in the existing DLN injector without major modification to the injector. During high-pressure testing, the catalytic pilot showed no incidence of flashback or autoignition while operating over wide range of combustion temperatures. The catalytic reactor lit off at a temperature of approximately 598 K (325°C/617°F) and operated at simulated 100% and 50% load conditions without a preburner. At high pressure, the maximum catalyst surface temperature was similar to that observed during atmospheric pressure testing and considerably lower than the surface temperature expected in lean-burn catalytic devices. In single-injector rig testing, the integrated assembly of the catalytic pilot and Taurus 70 injector demonstrated NO x and CO emission less than 5 ppm @ 15% O 2 for 100% and 50% load conditions along with low acoustics. The results demonstrate that a catalytic pilot burner replacing a diffusion flame or partially premixed pilot in an otherwise DLN combustor can enable operation at conditions with substantially reduced NO x emissions.

Advanced Catalytic Pilot for Low NOx Industrial Gas Turbines

Future aeropropulsion gas turbine combustion requirements call for operating at very high inlet temperatures, pressures, and large temperature rises. At the same time, the combustion process is to have minimum pollution effects on the environment. Aircraft gas turbine engines utilize liquid hydrocarbon fuels which are difficult to uniformly atomize and mix with combustion air. An approach for minimizing fuel related problems is to transform the liquid fuel into gaseous form prior to the completion of the combustion process. Experimentally obtained results are presented for vaporizing and partially oxidizing a liquid hydrocarbon fuel into burnable gaseous components. The presented experimental data show that 1200 to 1300 K reaction product gas, rich in hydrogen, carbon monoxide, and light-end hydrocarbons, is formed when flowing 0.3 to 0.6 fuel to air mixes through a catalyst reactor. The reaction temperatures are kept low enough that nitrogen oxides and carbon particles (soot) do not form. Results are reported for tests using different catalyst types and configurations, mass flowrates, input temperatures, and fuel to air ratios.

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Fuel-rich, catalytic reaction experimental results

An experimental investigation was conducted to obtain combustion performance values for specific heavyend, synthetic hydrocarbon fuels. A flame tube combustor modified to duplicate an advanced gas turbine engine combustor was used for the tests. Each fuel was tested at steady-state operating conditions over a range of mass flow rates, fuel-to-air mass ratio, and inlet air temperatures. The combustion pressure, as well as the hardware, were kept nearly constant over the program test phase. Test results were obtained in regards to geometric temperature pattern factors as a function of combustor wall temperatures, the combustion gas temperature, and the combustion emissions, both as affected by the mass flow rate and fuel-to-air ratio. The synthetic fuels were reacted in the combustor such that for most tests their performance was as good, if not better, than the baseline gasoline or diesel fuel tests. The only detrimental effects were that at high inlet air temperature conditions, fuel decomposition occurred in the fuel atomizing nozzle passages resulting in blockage. And the nitrogen oxide emissions were above EPA limits at low flow rate and high operating temperature conditions.

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Combustion characteristics of gas turbine alternative fuels

A catalyst containing reactor is being tested using a fuel-rich mixture of Jet A fuel and hot input air. The reactor product is a gaseous fuel that can be utilized in aeropropulsion gas turbine engines. Because the catalyst material is susceptible to damage from high temperature conditions, fuel-rich operating conditions are attained by introducing the fuel first into an inert gas stream in the reactor and then displacing the inert gas with reaction air. Once a desired fuel-to-air ratio is attained, only limited time is allowed for a catalyst induced reaction to occur; otherwise the inert gas is substituted for the air and the fuel flow is terminated. Because there presently is not a gas turbine combustor in which to burn the reactor product gas, the gas is combusted at the outlet of the test facility flare stack. This technique in operations has worked successfully in over 200 tests.

https://ntrs.nasa.gov/api/citations/19920007843/downloads/19920007843.pdf

R. James Rollbuhler

Papers

Fuel-rich, catalytic reaction experimental results

Combustion characteristics of gas turbine alternative fuels

Safety considerations in testing a fuel-rich aeropropulsion gas generator