Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

Phd by thesis

Friction stir welding (FSW) is a relatively new solid-state joining process. This joining technique is energy efficient, environment friendly, and versatile. In particular, it can be used to join high-strength aerospace aluminum alloys and other metallic alloys that are hard to weld by conventional fusion welding. FSW is considered to be the most significant development in metal joining in a decade. Recently, friction stir processing (FSP) was developed for microstructural modification of metallic materials. In this review article, the current state of understanding and development of the FSW and FSP are addressed. Particular emphasis has been given to: (a) mechanisms responsible for the formation of welds and microstructural refinement, and (b) effects of FSW/FSP parameters on resultant microstructure and final mechanical properties. While the bulk of the information is related to aluminum alloys, important results are now available for other metals and alloys. At this stage, the technology diffusion has significantly outpaced the fundamental understanding of microstructural evolution and microstructure–property relationships.

/pdf/friction-stir-welding-and-processing-3hu3ejo7ub.pdf

Friction Stir Welding and Processing

Biodegradable metals are breaking the current paradigm in biomaterial science to develop only corrosion resistant metals. In particular, metals which consist of trace elements existing in the human body are promising candidates for temporary implant materials. These implants would be temporarily needed to provide mechanical support during the healing process of the injured or pathological tissue. Magnesium and its alloys have been investigated recently by many authors as a suitable biodegradable biomaterial. In this investigative review we would like to summarize the latest achievements and comment on the selection and use, test methods and the approaches to develop and produce magnesium alloys that are intended to perform clinically with an appropriate host response.

/pdf/degradable-biomaterials-based-on-magnesium-corrosion-4sw919tlb2.pdf

Degradable biomaterials based on magnesium corrosion

Pitting corrosion of aluminum

The comprehensive body of knowledge that has built up with respect to the friction stir welding (FSW) of aluminium alloys since the technique was invented in 1991 is reviewed The basic principles of FSW are described, including thermal history and metal flow, before discussing how process parameters affect the weld microstructure and the likelihood of entraining defects After introducing the characteristic macroscopic features, the microstructural development and related distribution of hardness are reviewed in some detail for the two classes of wrought aluminium alloy (non-heat-treatable and heat-treatable) Finally, the range of mechanical properties that can be achieved is discussed, including consideration of residual stress, fracture, fatigue and corrosion It is demonstrated that FSW of aluminium is becoming an increasingly mature technology with numerous commercial applications In spite of this, much remains to be learned about the process and opportunities for further research a

Friction stir welding of aluminium alloys

Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy

Electroless nickel-plating on AZ91D magnesium alloy has been investigated to understand the effect of substrate microstructure and plating parameters. The initial stage of the deposition was investigated using scanning electron microscopy (SEM) and energy dispersive X-ray analysis on substrates plated for a very short interval of time. The early stage of growth was strongly influenced by the substrate microstructure. Plating was initiated on b-phase grains probably due to the galvanic coupling of b and eutectic a-phase. Once the b-phase was covered with the coating, it then spread onto eutectic a and primary a-phase. The coating produced with the optimised bath showed 7 wt.% phosphorus with a hardness of approximately 600–700 VHN. The optimum ligand to metal ion ratio was found to be 1:1.5, while the safe domain for thiourea (TU) was in the range of 0.5–1 mgyl. Fluoride was found to be an essential component of the bath to plate AZ91D alloy with an optimum value of 7.5 gyl. The presence of 0.25–0.5 mgyl mercapto-benzo-thiosole (MBT) found to accelerate the plating process. 2003 Elsevier B.V. All rights reserved.

/pdf/electroless-nickel-plating-on-az91d-magnesium-alloy-effect-2nwjl2nvat.pdf

Electroless nickel-plating on AZ91D magnesium alloy: effect of substrate microstructure and plating parameters

The effect of welding parameters on the corrosion behaviour of friction stir welded AA2024–T351

Effect of Iron-Containing Intermetallic Particles on the Corrosion Behaviour of Aluminium

The influence of chloride ion concentration and pH on the corrosion and electrochemical behaviour of die-cast and ingot-cast AZ91D alloy have been studied with a focus on the stability of microconstituents in these environments. The experimental techniques used include immersion studies, potentiodynamic polarization, X-ray diffraction and optical and scanning electron microscopy. The corrosion rate for the ingot and die-cast was very high in highly acidic solutions (pH 1–2) as compared to that in neutral and highly alkaline solutions (pH 4.5–12.0), and the rate increased with chloride ion concentration at all pH levels. In general, the die-cast showed a lower corrosion rate at all pH values and chloride ion concentrations. The open circuit corrosion potential shifted to more negative (more active) values with increase in concentration of chloride ions. Corrosion morphologies revealed more attack on primary α and eutectic α with increasing chloride concentration. In highly acidic conditions, corrosion attack was found on β (Mg17Al12) and eutectic α phase (α regions with higher Al content) while at pH 12.0 the ingot exhibited a pitting type of morphology. The corrosion product consisted of magnesium hydroxide, fallen β particles and magnesium–aluminium oxide; the amount of each component was found to be a function of chloride ion concentration and pH.

Rajan Ambat

Papers

Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy

Electroless nickel-plating on AZ91D magnesium alloy: effect of substrate microstructure and plating parameters

The effect of welding parameters on the corrosion behaviour of friction stir welded AA2024–T351

Effect of Iron-Containing Intermetallic Particles on the Corrosion Behaviour of Aluminium

Studies on the influence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy