Rameshprabu Ramaraj

Bio: Rameshprabu Ramaraj is an academic researcher from Maejo University. The author has contributed to research in topics: Biofuel & Chemistry. The author has an hindex of 21, co-authored 96 publications receiving 1159 citations. Previous affiliations of Rameshprabu Ramaraj include National Chung Hsing University.

Biochar derived from non-customized matamba fruit shell as an adsorbent for wastewater treatment

Abstract: This study of Matamba shell reviled them as material with outstanding surface morphology, elemental and kinetic mechanism characteristics. Mutamba biochar revealed irregular honeycomb morphological transformation from the field emission scanning electron microscope after pyrolysis at 600 °C for 2 h. Energy dispersive X-ray spectroscopy revealed high content of carbon (72.68wt%), nitrogen (14.14wt%) and oxygen (10.35wt%) on the biochar surface. The available oxygen composition provides enough polarization ability for high iodine adsorption (43.65 mmol/g) from the experimental data which were significantly induced by weak van der Waals forces and π-π and π-stacking interaction on the biochar surface and its micropores. The carbon content above 50% in ash rich biochar with an increase in pyrolysis can be ascribed to elements incorporated into aromatic or heterocyclic ring system established through preferential loss of oxygen at 600 °C pyrolysis. The adsorption kinetics were conducted to evaluate the equilibrium adsorption of the novel material and Elovich and Intra particle diffusion better described well the kinetic adsorption through Iodine adsorption than pseudo first order and pseudo second order models. Elovich was the best model to fit the adsorption kinetics with 45.41 mmol/(g•min) adsorption rate. The second order Akaike Information Criterion (38.26), adjusted correlation coefficient R2 (0.9898) and sum of squares error (1.442) were used to fit the data. Consequently, the biochar in this study can serve as a promising green material for efficiently removing organic and inorganic contaminants from the environmental water ecosystem. The environmental significance of biochar will be of fundamental meaning to rural areas in developing countries in aquatic contaminants immobilization for water reuse. These results indicate that the Matamba fruit shells has the possibility to be used as an eco-friendly and low-cost effective adsorbent for anionic dye removal from the water environment. They also demonstrate the immense potential of the fruit shell waste to produce high performance biochar as an alternative green carbonaceous material that can be applied to adsorb organic and inorganic unwanted constituencies from wastewater as well as improvement of waste management in developing countries at a low cost. Its application as a pathway mitigation for diminishing greenhouse gasses and reducing the global warming potential could not be underestimated.

Bioethanol production from sunflower stalk: application of chemical and biological pretreatments by response surface methodology (RSM)

Abstract: The present paper discusses response surface methodology (RSM) as an efficient tactic for predictive model and optimization of the whole experimental methods of reducing sugar and energy. In this work, the application of RSM presented for optimizing reducing sugar and energy as compared with production between chemical and biological pretreatments. All experiments applied statistical designs in order to develop a statistic multivariate analysis model that provides to consider the effect of different parameters on a process and describe the optimum values of these variables to optimize the response. Dred sunflower stalks were pretreated by sodium hydroxide (NaOH) and Trichoderma reesei as a function of two variables: concentration of NaOH (%) and T. reesei (%) and time for pretreatment (Day) to receive reducing sugar and energy. The chemical pretreatment model was characterized by 13 runs, varying the variables at two factors, NaOH (1, 1.5, 2%) and Day (1, 2, 3). The biological pretreatment model was characterized by 13 runs, varying the variables at two factors, T. reesei (1, 1.5, 2%) and Day (1, 2, 3), by central composite design experimental design. In the chemical pretreatment, experiments performed at 2% (w/v) of NaOH for 3 days were used. The chemical pretreatment model at 2% NaOH for a 3-day release reduced sugar by 5.812 g/L and energy by 92.992 kJ/L; on the other hand, biological pretreatment model at 2% T. reesei for a 3-day release reduced sugar by 3.891 g/L and energy by 62.256 kJ/L, reducing sugar starter for fermentation by 49.0670 ± 6.4660 g/L and fermentation efficiency by 71.60% at 48 h fermented time.

Fermentation of pineapple fruit peel wastes for bioethanol production

Abstract: In the past few years, the global demand in bioethanol has been continuously rising due to its economic importance. Several countries have exerted considerable efforts in the production of bioethanol as a transport fuel from different feedstocks and started to practice consuming this environment-friendly fuel. Thailand is now one of the top consumers of bioethanol in South East Asia and belongs to the top 5 leading countries in producing pineapples. Production of bioethanol from pineapple wastes, especially the fruit peels, became possible. In this study, the effects of alkaline pretreatment and microbial hydrolysis through Trichoderma harzianum of pineapple fruit peel were evaluated. Among the four concentrations of NaOH, the 0% NaOH gave the highest total and reducing sugar (458.44 ± 13.6 g/L and 279.67 ± 21 g/L) than 1%, 3%, and 5% concentrations of NaOH. Samples pretreated with 0% NaOH were subjected to microbial hydrolysis which showed an increase in reducing sugar of the samples. At the end of the experiment, a bioethanol yield of 5.98 ± 1.01 g/L from pineapple fruit peel was successfully produced at 48 h of fermentation.

Wastewater Engineering Treatment Disposal And Reuse

Abstract: wastewater engineering treatment disposal and reuse is available in our digital library an online access to it is set as public so you can download it instantly. Our books collection hosts in multiple countries, allowing you to get the most less latency time to download any of our books like this one. Kindly say, the wastewater engineering treatment disposal and reuse is universally compatible with any devices to read.

Recent advances in the development of biomass gasification technology: A comprehensive review

Abstract: Due to fast climate change and foreseen damage through global warming, access to clean and green energy has become very much essential for the sustainable development of the society, globally. Biomass based energy is one of the important renewable energy resources to meet the day to day energy requirements and is as old as the human civilization. Biomass gasification is among few important aspects of bioenergy for producing heat, power and biofuels for useful applications. Despite, the availability of vast literature, technological and material advancements, the dissemination of gasification technology could not overcome the critical barriers for the widespread acceptability over the conventional energy resources. This article presents a comprehensive review on the technical advancements, developments of biomass gasification technology and the barriers being faced by different stakeholders in the wide dissemination of the technology for day to day requirements of the society, followed by recommendations for policy makers to make this technology popular while serving the society.

Green Synthesis of Metallic Nanoparticles and Their Prospective Biotechnological Applications: an Overview

Abstract: The green synthesis of nanoparticles (NPs) using living cells is a promising and novelty tool in bionanotechnology. Chemical and physical methods are used to synthesize NPs; however, biological methods are preferred due to its eco-friendly, clean, safe, cost-effective, easy, and effective sources for high productivity and purity. High pressure or temperature is not required for the green synthesis of NPs, and the use of toxic and hazardous substances and the addition of external reducing, stabilizing, or capping agents are avoided. Intra- or extracellular biosynthesis of NPs can be achieved by numerous biological entities including bacteria, fungi, yeast, algae, actinomycetes, and plant extracts. Recently, numerous methods are used to increase the productivity of nanoparticles with variable size, shape, and stability. The different mechanical, optical, magnetic, and chemical properties of NPs have been related to their shape, size, surface charge, and surface area. Detection and characterization of biosynthesized NPs are conducted using different techniques such as UV-vis spectroscopy, FT-IR, TEM, SEM, AFM, DLS, XRD, zeta potential analyses, etc. NPs synthesized by the green approach can be incorporated into different biotechnological fields as antimicrobial, antitumor, and antioxidant agents; as a control for phytopathogens; and as bioremediative factors, and they are also used in the food and textile industries, in smart agriculture, and in wastewater treatment. This review will address biological entities that can be used for the green synthesis of NPs and their prospects for biotechnological applications.

The role of pretreatment in improving the enzymatic hydrolysis

Abstract: Lignocellulosic materials are among the most promising alternative energy resources that can be utilized to produce cellulosic ethanol. However, the physical and chemical structure of lignocellulosic materials forms strong native recalcitrance and results in relatively low yield of ethanol from raw lignocellulosic materials. An appropriate pretreatment method is required to overcome this recalcitrance. For decades various pretreatment processes have been developed to improve the digestibility of lignocellulosic biomass. Each pretreatment process has a different specificity on altering the physical and chemical structure of lignocellulosic materials. In this paper, the chemical structure of lignocellulosic biomass and factors likely affect the digestibility of lignocellulosic materials are discussed, and then an overview about the most important pretreatment processes available are provided. In particular, the combined pretreatment strategies are reviewed for improving the enzymatic hydrolysis of lignocellulose and realizing the comprehensive utilization of lignocellulosic materials.