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Ray L. Frost

Bio: Ray L. Frost is an academic researcher from Queensland University of Technology. The author has contributed to research in topics: Raman spectroscopy & Infrared spectroscopy. The author has an hindex of 86, co-authored 1356 publications receiving 41053 citations. Previous affiliations of Ray L. Frost include University of Western Sydney & Southwest University of Science and Technology.


Papers
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TL;DR: Co-precipitation is a common method for the preparation of layered double hydroxides (LDHs) and related materials as mentioned in this paper, and it has been shown to be useful for direct synthesis of LDHs with a wide range of interlayer anions.

233 citations

Journal ArticleDOI
TL;DR: In this article, high-quality Raman spectra were used for the characterization of alumina phases of gibbsite, bayerite, diaspore and boehmite.
Abstract: High-quality Raman spectra were used for the characterization of alumina phases of gibbsite, bayerite, diaspore and boehmite. The Raman spectrum of gibbsite shows four strong, sharp bands at 3617, 3522, 3433 and 3364 cm in the hydroxyl stretching region. The spectrum of bayerite shows seven bands at 3664, 3652, 3552, 3542, 3450, 3438 and 3420 cm. Five broad bands at 3445, 3363, 3226, 3119 and 2936 cm and four broad and weak bands at 3371, 3220, 3085 and 2989 cm-1 are present in the Raman spectrum of the hydroxyl stretching region of diaspore and boehmite. The hydroxyl stretching bands are related to the surface structure of the minerals. The Raman spectra of bayerite, gibbsite and diaspore are complex whereas the Raman spectrum of boehmite shows only four bands in the low-wavenumber region. These bands are assigned to deformation and translational modes of the alumina phases. A comparison of the Raman spectrum of bauxite with those of boehmite and gibbsite showed the possibility of using Raman spectroscopy for on-line processing of bauxites that contain a mixture of alumina phases.

228 citations

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TL;DR: In this paper, the synthesis and properties of smectites and related metal oxide pillared clay (PILC) are discussed and the relation between the performance of the PILC and its physico-chemical features is addressed.
Abstract: Metal oxide pillared clay (PILC) possesses several interesting properties, such as large surface area, high pore volume and tunable pore size (from micropore to mesopore), high thermal stability, strong surface acidity and catalytic active substrates/metal oxide pillars. These unique characteristics make PILC an attractive material in catalytic reactions. It can be made either as catalyst support or directly used as catalyst. This paper is a continuous work from Kloprogge's review (J.T. Kloprogge, J. Porous Mater. 5, 5 1998) on the synthesis and properties of smectites and related PILCs and will focus on the diverse applications of clay pillared with different types of metal oxides in the heterogeneous catalysis area and adsorption area. The relation between the performance of the PILC and its physico-chemical features will be addressed.

228 citations

Journal ArticleDOI
TL;DR: In this paper, the formation mechanisms, characteristics, interactions, and environmental applications of surface-bound EPFRs in biochars are reviewed, and new and important insights into the fate and emerging applications of EPFR-mediated removal of organics/inorganics by bio-char are provided.

225 citations

Journal ArticleDOI
TL;DR: The use of organo-clays for cleaning up oil spills is feasible due to its many desirable properties such as high hydrocarbon sorption and retention capacities, hydrophobicity, and recyclability.

216 citations


Cited by
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08 Dec 2001-BMJ
TL;DR: There is, I think, something ethereal about i —the square root of minus one, which seems an odd beast at that time—an intruder hovering on the edge of reality.
Abstract: There is, I think, something ethereal about i —the square root of minus one. I remember first hearing about it at school. It seemed an odd beast at that time—an intruder hovering on the edge of reality. Usually familiarity dulls this sense of the bizarre, but in the case of i it was the reverse: over the years the sense of its surreal nature intensified. It seemed that it was impossible to write mathematics that described the real world in …

33,785 citations

Journal ArticleDOI
01 Apr 1988-Nature
TL;DR: In this paper, a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) is presented.
Abstract: Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

9,929 citations

Journal ArticleDOI
TL;DR: Biesinger et al. as mentioned in this paper proposed a more consistent and effective approach to curve fitting based on a combination of standard spectra from quality reference samples, a survey of appropriate literature databases and/or a compilation of literature references and specific literature references where fitting procedures are available.

7,498 citations

Journal ArticleDOI
TL;DR: In this article, a detailed analysis of the thermal expansion mechanism of graphite oxide to produce functionalized graphene sheets is provided, where it is shown that the decomposition rate of the epoxy and hydroxyl sites exceeds the diffusion rate of evolved gases, yielding pressures that exceed the van der Waals forces holding the graphene sheets together.
Abstract: A detailed analysis of the thermal expansion mechanism of graphite oxide to produce functionalized graphene sheets is provided. Exfoliation takes place when the decomposition rate of the epoxy and hydroxyl sites of graphite oxide exceeds the diffusion rate of the evolved gases, thus yielding pressures that exceed the van der Waals forces holding the graphene sheets together. A comparison of the Arrhenius dependence of the reaction rate against the calculated diffusion coefficient based on Knudsen diffusion suggests a critical temperature of 550 °C which must be exceeded for exfoliation to occur. As a result of their wrinkled nature, the functionalized and defective graphene sheets do not collapse back to graphite oxide but are highly agglomerated. After dispersion by ultrasonication in appropriate solvents, statistical analysis by atomic force microscopy shows that 80% of the observed flakes are single sheets.

3,340 citations

Journal ArticleDOI
TL;DR: From a comprehensive literature review, it was found that some LCAs, in addition to having wide availability, have fast kinetics and appreciable adsorption capacities too.

3,163 citations