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Author

Raymond Flynn

Other affiliations: Queen's University
Bio: Raymond Flynn is an academic researcher from Queen's University Belfast. The author has contributed to research in topics: Aquifer & Groundwater. The author has an hindex of 15, co-authored 50 publications receiving 681 citations. Previous affiliations of Raymond Flynn include Queen's University.


Papers
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Journal ArticleDOI
TL;DR: A conceptual framework for a tiered CSA-based approach to assist in the development of supplementary measures would provide a means of developing catchment-specific and cost-effective programmes of measures for diffuse P in High Status Waterbodies (HSW).

103 citations

Journal ArticleDOI
TL;DR: In this paper, a methodology for catchment-scale characterisation is presented, based on the integration of complementary, multi-scale hydrogeological, geophysical and geological approaches.
Abstract: Groundwater flow in hard-rock aquifers is strongly controlled by the characteristics and distribution of structural heterogeneity. A methodology for catchment-scale characterisation is presented, based on the integration of complementary, multi-scale hydrogeological, geophysical and geological approaches. This was applied to three contrasting catchments underlain by metamorphic rocks in the northern parts of Ireland (Republic of Ireland and Northern Ireland, UK). Cross-validated surface and borehole geophysical investigations confirm the discontinuous overburden, lithological compartmentalisation of the bedrock and important spatial variations of the weathered bedrock profiles at macro-scale. Fracture analysis suggests that the recent (Alpine) tectonic fabric exerts strong control on the internal aquifer structure at meso-scale, which is likely to impact on the anisotropy of aquifer properties. The combination of the interpretation of depth-specific hydraulic-test data with the structural information provided by geophysical tests allows characterisation of the hydrodynamic properties of the identified aquifer units. Regionally, the distribution of hydraulic conductivities can be described by inverse power laws specific to the aquifer litho-type. Observed groundwater flow directions reflect this multi-scale structure. The proposed integrated approach applies widely available investigative tools to identify key dominant structures controlling groundwater flow, characterising the aquifer type for each catchment and resolving the spatial distribution of relevant aquifer units and associated hydrodynamic parameters.

44 citations

Journal ArticleDOI
TL;DR: A summary of DOC occurrence in groundwater bodies and associated issues capable of indirectly affecting human health is provided in this paper, where the authors also provide a method to confidently investigate the behaviour of dissolved organic carbon and its effect on contaminant transfer in aquifers.
Abstract: Dissolved organic carbon (DOC) is composed of a diverse array of compounds, predominantly humic substances, and is a near ubiquitous component of natural groundwater, notwithstanding climatic extremes such as arid and hyper-arid settings. Despite being a frequently measured parameter of groundwater quality, the complexity of DOC composition and reaction behaviour means that links between concentration and human health risk are difficult to quantify and few examples are reported in the literature. Measured concentrations from natural/unpolluted groundwater are typically below 4 mg C/l, whilst concentrations above these levels generally indicate anthropogenic influences and/or contamination issues and can potentially compromise water safety. Treatment processes are effective at reducing DOC concentrations, but refractory humic substance reaction with chlorine during the disinfection process produces suspected carcinogenic disinfectant by-products (DBPs). However, despite engineered artificial recharge systems being commonly used to remove DOC from recycled treated wastewaters, little research has been conducted on the presence of DBPs in potable groundwater systems. In recent years, the capacity to measure the influence of organic matter on colloidal contaminants and its influence on the mobility of pathogenic microorganisms has aided understanding of transport processes in aquifers. Additionally, advances in polymerase chain reaction techniques used for the detection, identification, and quantification of waterborne pathogens, provide a method to confidently investigate the behaviour of DOC and its effect on contaminant transfer in aquifers. This paper provides a summary of DOC occurrence in groundwater bodies and associated issues capable of indirectly affecting human health.

44 citations

Journal ArticleDOI
TL;DR: An approach for quantifying microsphere deposition onto iron-oxide-coated sand under the influence of adsorbed Suwannee River Humic Acid (SRHA) and results showed that 1 μg of SRHA could block 5.90 ± 0.14 × 10(9) microspheres deposition sites.

43 citations

Journal ArticleDOI
TL;DR: Study findings demonstrate that despite rapid transport rates, the epikarst is capable of physicochemical filtration of viruses and their remobilization, depending on virus type and hydrochemical conditions.

41 citations


Cited by
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Journal Article
TL;DR: A case study explores the background of the digitization project, the practices implemented, and the critiques of the project, which aims to provide access to a plethora of information to EPA employees, scientists, and researchers.
Abstract: The Environmental Protection Agency (EPA) provides access to information on a variety of topics related to the environment and strives to inform citizens of health risks. The EPA also has an extensive library network that consists of 26 libraries throughout the United States, which provide access to a plethora of information to EPA employees, scientists, and researchers. The EPA implemented a reorganization project to digitize their materials so they would be more accessible to a wider range of users, but this plan was drastically accelerated when the EPA was threatened with a budget cut. It chose to close and reduce the hours and services of some of their libraries. As a result, the agency was accused of denying users the “right to know” by making information unavailable, not providing an adequate strategic plan, and discarding vital materials. This case study explores the background of the digitization project, the practices implemented, and the critiques of the project.

2,588 citations

Journal ArticleDOI
TL;DR: As one article in a four-part PLoS Medicine series on water and sanitation, Paul Hunter and colleagues argue that much more effort is needed to improve access to safe and sustainable water supplies.
Abstract: As one article in a four-part PLoS Medicine series on water and sanitation, Paul Hunter and colleagues argue that much more effort is needed to improve access to safe and sustainable water supplies.

465 citations

Journal ArticleDOI
TL;DR: The present analysis provides a useful framework to identify priorities for future research in order to achieve more robust risk assessments of nanopesticides.
Abstract: Published literature has been reviewed in order to (a) explore the (potential) applications of nanotechnology in pesticide formulation, (b) identify possible impacts on environmental fate, and (c) analyze the suitability of current exposure assessment procedures to account for the novel properties of nanopesticides within the EU regulatory context. The term nanopesticide covers a wide variety of products and cannot be considered to represent a single category. Many nanoformulations combine several surfactants, polymers, and metal nanoparticles in the nanometer size range. The aims of nanoformulations are generally common to other pesticide formulations, these being to increase the apparent solubility of poorly soluble active ingredients, to release the active ingredient in a slow/targeted manner and/or to protect against premature degradation. Nanoformulations are thus expected to (a) have significant impacts on the fate of active ingredients and/or (b) introduce new ingredients for which the environmenta...

389 citations

Journal ArticleDOI
TL;DR: In this article, the authors use the UK as an example of societies' multiple stressors on water quality to explore the uncertainties and challenges in achieving a sustainable balance between useable water resources, diverse aquatic ecosystems and a viable agriculture.
Abstract: The eutrophication of surface waters has become an endemic global problem. Nutrient loadings from agriculture are a major driver, but it remains very unclear what level of on-farm controls are necessary or can be justified to achieve water quality improvements. In this review article, we use the UK as an example of societies’ multiple stressors on water quality to explore the uncertainties and challenges in achieving a sustainable balance between useable water resources, diverse aquatic ecosystems and a viable agriculture. Our analysis shows that nutrient loss from agriculture is a challenging issue if farm productivity and profitability is to be maintained and increased. Legacy stores of nitrogen (N) and phosphorus (P) in catchments may be sufficient to sustain algal blooms and murky waters for decades to come and more innovation is needed to drawdown and recover these nutrients. Agriculture’s impact on eutrophication risk may also be overestimated in many catchments, and more accurate accounting of sources, their bioavailabilities and lag times is needed to direct proportioned mitigation efforts more effectively. Best practice farms may still be leaky and incompatible with good water quality in high-risk areas requiring some prioritization of society goals. All sectors of society must clearly use N and P more efficiently to develop long-term sustainable solutions to this complex issue and nutrient reduction strategies should take account of the whole catchment-to-coast continuum. However, the right balance of local interventions (including additional biophysical controls) will need to be highly site specific and better informed by research that unravels the linkages between sustainable farming practices, patterns of nutrient delivery, biological response and recovery trajectories in different types of waterbodies.

360 citations

01 Jan 1992
TL;DR: An overview of crystalline basement aquifer occurrence, geological and climatic controls, evolution, geometry, hydraulic parameters, resources and recharge, combined with a discussion on exploration and management is provided in this paper.
Abstract: The author was the Project Leader of the British Geological Survey (BGS) Research Projects on Basement Aquifers and Collector Wells. This introductory paper constitutes an overview of crystalline basement aquifer occurrence, geological and climatic controls, evolution, geometry, hydraulic parameters, resources and recharge, combined with a discussion on exploration and management. Data from the BGS Research Projects Report Series are incorporated.

299 citations