Richard Phelan

Bio: Richard Phelan is an academic researcher from Trinity College, Dublin. The author has contributed to research in topics: Laser & Semiconductor laser theory. The author has an hindex of 28, co-authored 118 publications receiving 2720 citations. Previous affiliations of Richard Phelan include University College Dublin & University College Cork.

All-optical phase and amplitude regenerator for next-generation telecommunications systems

Abstract: Fibre-optic communications systems have traditionally carried data using binary (on-off) encoding of the light amplitude. However, next-generation systems will use both the amplitude and phase of the optical carrier to achieve higher spectral efficiencies and thus higher overall data capacities(1,2). Although this approach requires highly complex transmitters and receivers, the increased capacity and many further practical benefits that accrue from a full knowledge of the amplitude and phase of the optical field(3) more than outweigh this additional hardware complexity and can greatly simplify optical network design. However, use of the complex optical field gives rise to a new dominant limitation to system performance-nonlinear phase noise(4,5). Developing a device to remove this noise is therefore of great technical importance. Here, we report the development of the first practical ('black-box') all-optical regenerator capable of removing both phase and amplitude noise from binary phase-encoded optical communications signals.

Multilevel quantization of optical phase in a novel coherent parametric mixer architecture

Abstract: The exponentially increasing capacity demand in information systems will be met by carefully exploiting the complementary strengths of electronics and optics. Optical signal processing provides simple but powerful pipeline functions that offer high speed, low power, low latency and a route to densely parallel execution. A number of functions such as modulation and sampling, complex filtering and Fourier transformation have already been demonstrated. However, the key functionality of all-optical quantization has still not been addressed effectively. Here, we report an all-optical signal processing architecture that enables, for the first time, multilevel all-optical quantization of phase-encoded optical signals. A four-wavemixing process is used to generate a comb of phase harmonics of the input signal, and a two-pump parametric process to coherently combine a selected harmonic with the input signal, realizing phase quantization. We experimentally demonstrate operation up to six levels

Generation of Coherent Multicarrier Signals by Gain Switching of Discrete Mode Lasers

Abstract: The authors demonstrate the generation of a highly coherent multicarrier signal that consists of eight clearly resolved 10.7-GHz coherent sidebands generated within 3 dB of the spectral envelope peak and with an extinction ratio in excess of 45 dB by gain switching a discrete mode (DM) laser. The generated spectral comb displays a corresponding picosecond pulse train at a repetition rate of 10.7 GHz with a pulse duration of 24 ps and a temporal jitter of ~450 fs. The optical spectra and associated pulses of the gain-switched DM laser are subsequently compared with a gain-switched distributed feedback (DFB) laser that generates a spectrum with no discernible sidebands and corresponding pulses with ~3 ps of temporal jitter. By means of external injection, the temporal jitter of the gain-switched DFB laser is then reduced to <; 1 ps, resulting in visible tones on the output spectrum. Finally, a nonlinear scheme is employed and initially tailored to compress the optical pulses, after which, the setup is slightly altered to expand the original frequency comb from the gain-switched DM laser.

100 Gbit/s WDM transmission at 2 µm: transmission studies in both low-loss hollow core photonic bandgap fiber and solid core fiber

Abstract: We show for the first time 100 Gbit/s total capacity at 2 µm waveband, using 4 × 9.3 Gbit/s 4-ASK Fast-OFDM direct modulation and 4 × 15.7 Gbit/s NRZ-OOK external modulation, spanning a 36.3 nm wide wavelength range. WDM transmission was successfully demonstrated over 1.15 km of low-loss hollow core photonic bandgap fiber (HC-PBGF) and over 1 km of solid core fiber (SCF). We conclude that the OSNR penalty associated with the SCF is minimal, while a ~1-2 dB penalty was observed after the HC-PBGF probably due to mode coupling to higher-order modes.

Demonstration of amplified data transmission at 2 µm in a low-loss wide bandwidth hollow core photonic bandgap fiber

Abstract: The first demonstration of a hollow core photonic bandgap fiber (HC-PBGF) suitable for high-rate data transmission in the 2 µm waveband is presented. The fiber has a record low loss for this wavelength region (4.5 dB/km at 1980 nm) and a >150 nm wide surface-mode-free transmission window at the center of the bandgap. Detailed analysis of the optical modes and their propagation along the fiber, carried out using a time-of-flight technique in conjunction with spatially and spectrally resolved (S2) imaging, provides clear evidence that the HC-PBGF can be operated as quasi-single mode even though it supports up to four mode groups. Through the use of a custom built Thulium doped fiber amplifier with gain bandwidth closely matched to the fiber's low loss window, error-free 8 Gbit/s transmission in an optically amplified data channel at 2008nm over 290m of 19 cell HC-PBGF is reported.

Space-division multiplexing in optical fibres

Abstract: This Review summarizes the simultaneous transmission of several independent spatial channels of light along optical fibres to expand the data-carrying capacity of optical communications. Recent results achieved in both multicore and multimode optical fibres are documented.

New CMOS-compatible platforms based on silicon nitride and hydex for nonlinear optics

Abstract: Nonlinear photonic chips can generate and process signals all-optically with far superior performance to that possible electronically — particularly with respect to speed. Although silicon-on-insulator has been the leading platform for nonlinear optics, its high two-photon absorption at telecommunication wavelengths poses a fundamental limitation. We review recent progress in non-silicon CMOS-compatible platforms for nonlinear optics, with a focus on Si3N4 and Hydex®. These material systems have opened up many new capabilities such as on-chip optical frequency comb generation and ultrafast optical pulse generation and measurement. We highlight their potential future impact as well as the challenges to achieving practical solutions for many key applications. This article reviews recent progress in the use of silicon nitride and Hydex as non-silicon-based CMOS-compatible platforms for nonlinear optics. New capabilities such as on-chip optical frequency comb generation, ultrafast optical pulse generation and measurement using these materials, and their potential future impact and challenges are covered.

Spherical Ordered Mesoporous Carbon Nanoparticles with High Porosity for Lithium–Sulfur Batteries

Abstract: Rechargeable lithium–sulfur (Li–S) batteries are attracting increasing attention due to their high theoretical specific energy density, which is 3 to 5 times higher than that of Li-ion batteries based on intercalation chemistry. Since the electronic conductivity of sulfur is extremely low, conductive carbon materials with high accessible porosity to “wire” and contain the sulfur are an essential component of the positive electrode. During the past decades, attempts have been made to fabricate C/S composites using carbon black, activated carbons (ACs), and carbon nanotubes (CNTs). Although improvements resulted, the cathodes suffered from inhomogeneous contact between the active material and the electronic conductors. A major step forward in fabricating a uniform C/S composite was reported in 2009. Some of us employed CMK-3, an ordered mesoporous carbon (OMC) featuring high specific surface area and large pore volume as a scaffold. As much as 70 wt% sulfur was incorporated into the uniform 3–4 nm mesopores, and the cells exhibited reversible capacities up to 1350 mAhg , albeit at moderate rates. Inspired by this, another OMC, a bulk bimodal mesoporous carbon (BMC-1) was investigated as a Li-S cathode. The favorable pore dimensions and large pore volume greatly improved the rate performance. An electrode with 40 wt% S showed a high initial discharge capacity of 1135 mAhg 1 at a current rate of 1 C (defined as discharge/ charge in one hour). However, similar to other reports, the capacity is sensitive to the sulfur ratio, dropping to 718 mAhg 1 at a sulfur content of 60 wt%. These results suggest that the texture of the mesoporous carbon could be further enhanced. Recently, Archer et al. reported nanoscale hollow porous C/S spheres prepared through vapor infusion. These materials displayed good cyclability and capacity at a C/5 rate, illustrating the advantages of nanosized porous carbon in the sulfur cathodes. Here we report the synthesis of unique nanoscale spherical OMCs with extremely high bimodal porosities. The particles were investigated as a cathode material and sulfur host in Li–S batteries where they showed high initial discharge capacity and good cyclability without sacrificing rate capability. Unlike bulk porous carbons, these carbon– sulfur sphere electrodes did not display significant capacity fading with the increase of sulfur content in the cathodes. We show that the nanoscale morphology of these materials is of key importance for ensuring very efficient use of the sulfur content even at high cycling rates. Morphology control is a central issue in OMC synthesis. There are numerous examples of mesoporous bulk materials obtained either by hard-templating or soft-templating, including thin films, membranes or free fibers. Most syntheses use evaporation-induced self-assembly (EISA) followed by thermal treatment for template-removal and carbonization. It is a challenge to either create solution-based OMC nanoparticle syntheses or to adapt the established EISA methods to nanoparticles. Only few examples of OMC nanoparticles have been reported so far which are mostly unsuitable for applications in Li–S cells due to low pore volume and/or surface area. Approaches include templating with PMMA colloidal crystals or mesoporous silica nanoparticles, aerosol-assisted synthesis, ultrasonic emulsification or hydrothermal synthesis. Ordered arrays of fused mesoporous carbon spheres were reported by Liu et al. using a macroporous silica as template. Recently Lei et al. reported the synthesis of 65 nm mesoporous carbon nanospheres, with both 2.7 nm mesopores and high textural porosity (surface area of 2400 mg ). These showed promising supercapacitor properties. Our spherical OMC nanoparticles of 300 nm in diameter, prepared by a novel method, can be dispersed in water by sonification to form stable colloidal suspensions. The spherical mesoporous carbon nanoparticles were obtained in a twostep casting process. An opal structure of PMMA spheres was cast with a silica precursor solution to form a silica inverse opal. The inverse opal was then used as template for a triconstituent precursor solution containing resol as the carbon precursor, tetraethylorthosilicate (TEOS) as the silica precursor and the block copolymer Pluronic F127 as a structure-directing agent. Carbonization was followed by etching of the silica template and the silica in the carbon/silica nanocomposite, resulting in the formation of OMC with hierarchical porosity. Through the presence of silica in the [*] J. Schuster, B. Mandlmeier, Prof. Dr. T. Bein Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstrasse 5–13 (Gerhard Ertl Building), 81377 Munich (Germany) E-mail: tbein@cup.uni-muenchen.de Homepage: http://bein.cup.uni-muenchen.de G. He, T. Yim, K. T. Lee, Prof. Dr. L. F. Nazar Department of Chemistry, University of Waterloo 200 University Avenue West, Waterloo, Ontario N2L 3G1 (Canada) E-mail: lfnazar@uwaterloo.ca [] These authors contributed equally to this work.

Applications of nonlinear fiber optics

Abstract: * The only book describing applications of nonlinear fiber optics * Two new chapters on the latest developments: highly nonlinear fibers and quantum applications* Coverage of biomedical applications* Problems provided at the end of each chapterThe development of new highly nonlinear fibers - referred to as microstructured fibers, holey fibers and photonic crystal fibers - is the next generation technology for all-optical signal processing and biomedical applications. This new edition has been thoroughly updated to incorporate these key technology developments.The book presents sound coverage of the fundamentals of lightwave technology, along with material on pulse compression techniques and rare-earth-doped fiber amplifiers and lasers. The extensively revised chapters include information on fiber-optic communication systems and the ultrafast signal processing techniques that make use of nonlinear phenomena in optical fibers.New material focuses on the applications of highly nonlinear fibers in areas ranging from wavelength laser tuning and nonlinear spectroscopy to biomedical imaging and frequency metrology. Technologies such as quantum cryptography, quantum computing, and quantum communications are also covered in a new chapter.This book will be an ideal reference for: RD scientists involved with research on fiber amplifiers and lasers; graduate students and researchers working in the fields of optical communications and quantum information. * The only book on how to develop nonlinear fiber optic applications* Two new chapters on the latest developments; Highly Nonlinear Fibers and Quantum Applications* Coverage of biomedical applications

Two-dimensional mesoporous carbon nanosheets and their derived graphene nanosheets: synthesis and efficient lithium ion storage.

Abstract: We report a new solution deposition method to synthesize an unprecedented type of two-dimensional ordered mesoporous carbon nanosheets via a controlled low-concentration monomicelle close-packing assembly approach. These obtained carbon nanosheets possess only one layer of ordered mesopores on the surface of a substrate, typically the inner walls of anodic aluminum oxide pore channels, and can be further converted into mesoporous graphene nanosheets by carbonization. The atomically flat graphene layers with mesopores provide high surface area for lithium ion adsorption and intercalation, while the ordered mesopores perpendicular to the graphene layer enable efficient ion transport as well as volume expansion flexibility, thus representing a unique orthogonal architecture for excellent lithium ion storage capacity and cycling performance. Lithium ion battery anodes made of the mesoporous graphene nanosheets have exhibited an excellent reversible capacity of 1040 mAh/g at 100 mA/g, and they can retain at 833 mAh/g even after numerous cycles at varied current densities. Even at a large current density of 5 A/g, the reversible capacity is retained around 255 mAh/g, larger than for most other porous carbon-based anodes previously reported, suggesting a remarkably promising candidate for energy storage.