Author
Robert D. Feltham
Other affiliations: University College London
Bio: Robert D. Feltham is an academic researcher from University of Arizona. The author has contributed to research in topics: Valence (chemistry) & X-ray photoelectron spectroscopy. The author has an hindex of 10, co-authored 25 publications receiving 1683 citations. Previous affiliations of Robert D. Feltham include University College London.
Papers
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1,436 citations
TL;DR: In this paper, a new synthesis of di-and tri-tertiary arsines is described, which involves the reaction of dimethylarsinosodium with organic halides, and appears to be of general applicability.
59 citations
TL;DR: In this article, the crystal and molecular structures of two magnetically distinct forms of Fe(NO)(salen), C 16 H 14 N 3 O 3 Fe, have been determined by single crystal X-ray diffraction at 23 °C and at −175 °C.
46 citations
TL;DR: In this paper, the reaction between NaAs(CH 3 ) 2 and cis-1,2-dichloroethylene gives a mixture of cis- and trans -1, 2-bis(dimethylarsino)ethylene.
46 citations
TL;DR: In this paper, the X-ray photoelectron spectra of singly bent, doubly bent and protonated doubly-bent aryldiazonium complexes have been obtained and show that the RN2 ligand is highly reduced.
37 citations
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TL;DR: The integration of this chemistry with current perspectives of NO biology illuminates many aspects of NO biochemistry, including the enzymatic mechanism of synthesis, the mode of transport and targeting in biological systems, the means by which its toxicity is mitigated, and the function-regulating interaction with target proteins.
Abstract: Nitric oxide (NO.), a potentially toxic molecule, has been implicated in a wide range of biological functions. Details of its biochemistry, however, remain poorly understood. The broader chemistry of nitrogen monoxide (NO) involves a redox array of species with distinctive properties and reactivities: NO+ (nitrosonium), NO., and NO- (nitroxyl anion). The integration of this chemistry with current perspectives of NO biology illuminates many aspects of NO biochemistry, including the enzymatic mechanism of synthesis, the mode of transport and targeting in biological systems, the means by which its toxicity is mitigated, and the function-regulating interaction with target proteins.
2,713 citations
TL;DR: Functionalization via covalent grafting of organic functions allows to tune the redox and acid-base properties, and the solubility of polyoxometalates, to enhance their stability and biological activity and to reduce their toxicity.
799 citations
TL;DR: The surface chemistry of porphyrins, phthalocyanines, their metal complexes, and related compounds, with particular focus on chemical reactions at solid/vacuum interfaces, is discussed in this paper.
513 citations
TL;DR: In this paper, the most common instances where non-innocent behaviour of redox-active ligands, either substrates or supporting components, is observed in a biochemical context are discussed.
453 citations
429 citations