Initial-value ordinary differential equation solution via variable order Adams method (SIVA/DIVA) package is collection of subroutines for solution of nonstiff ordinary differential equations. There are versions for single-precision and double-precision arithmetic. Requires fewer evaluations of derivatives than other variable-order Adams predictor/ corrector methods. Option for direct integration of second-order equations makes integration of trajectory problems significantly more efficient. Written in FORTRAN 77.

Solving Ordinary Differential Equations

Ultrasonic irradiation of liquids causes acoustic cavitation: the formation, growth, and implosive collapse of bubbles. Bubble collapse during cavitation generates transient hot spots responsible for high-energy chemistry and emission of light. Determination of the temperatures reached in a cavitating bubble has remained a difficult experimental problem. As a spectroscopic probe of the cavitation event, sonoluminescence provides a solution. Sonoluminescence spectra from silicone oil were reported and analyzed. The observed emission came from excited state C2 (Swan band transitions, d3IIg—a3IIµ), which has been modeled with synthetic spectra as a function of rotational and vibrational temperatures. From comparison of synthetic to observed spectra, the effective cavitation temperature was found to be 5075 ± 156 K.

https://science.sciencemag.org/content/sci/253/5026/1397.full.pdf

The temperature of cavitation.

The organization of inorganic nanostructures within self-assembled organic or biological templates is receiving the attention of scientists interested in developing functional hybrid materials. Previous efforts have concentrated on using such scaffolds to spatially arrange nanoscopic elements as a strategy for tailoring the electrical, magnetic or photonic properties of the material. Recent theoretical arguments have suggested that synergistic interactions between self-organizing particles and a self-assembling matrix material can lead to hierarchically ordered structures. Here we show that mixtures of diblock copolymers and either cadmium selenide- or ferritin-based nanoparticles exhibit cooperative, coupled self-assembly on the nanoscale. In thin films, the copolymers assemble into cylindrical domains, which dictate the spatial distribution of the nanoparticles; segregation of the particles to the interfaces mediates interfacial interactions and orients the copolymer domains normal to the surface, even when one of the blocks is strongly attracted to the substrate. Organization of both the polymeric and particulate entities is thus achieved without the use of external fields, opening a simple and general route for fabrication of nanostructured materials with hierarchical order.

Self-directed self-assembly of nanoparticle/copolymer mixtures

Physics of shock waves and high-temperature hydrodynamic phenomena - Ya.B. Zeldovich and Yu.P. Raizer (translated from the Russian and then edited by Wallace D. Hayes and Ronald F. Probstein); Dover Publications, New York, 2002, 944 pp., $34.

Ultrasound, an efficient and virtually innocuous means of activation in synthetic chemistry, has been employed for decades with varied success. Not only can this high-energy input enhance mechanical effects in heterogeneous processes, but it is also known to induce new reactivities leading to the formation of unexpected chemical species. What makes sonochemistry unique is the remarkable phenomenon of cavitation, currently the subject of intense research which has already yielded thought-provoking results. This critical review is aimed at discussing the present status of cavitational chemistry and some of the underlying phenomena, and to highlight some recent applications and trends in organic sonochemistry, especially in combination with other sustainable technologies. (151 references.).

Power ultrasound in organic synthesis: moving cavitational chemistry from academia to innovative and large-scale applications

Part 1 Volume 1: equations of mechanics of heterogeneous continuous media mechanics of processes near dispersed particles drops and bubbles wave dynamics of shocks and detonations in condensed media with phase transitions dynamics of two-velocity flows of disperse media (gas-particle suspensions) gas and wave dynamics of combustion and detonation of gas particle suspensions and powders. Part 2 Volume 2: wave dynamics of bubbly liquids hydrodynamics and thermodynamics of stationary one-dimensional gas-liquid and vapor-liquid flows in channels theory of inertia-free and percolation flows of heterogeneous media.

Dynamics of multiphase media

In cavitation experiments with deuterated acetone, tritium decay activity above background levels was detected. In addition, evidence for neutron emission near 2.5 million electron volts was also observed, as would be expected for deuterium-deuterium fusion. Control experiments with normal acetone did not result in tritium activity or neutron emissions. Hydrodynamic shock code simulations supported the observed data and indicated highly compressed, hot (10 6 to 10 7 kelvin) bubble implosion conditions, as required for nuclear fusion reactions.

/pdf/evidence-for-nuclear-emissions-during-acoustic-cavitation-to8o1p1brd.pdf

Evidence for Nuclear Emissions During Acoustic Cavitation

Spatial averaging in the mechanics of heterogeneous and dispersed systems

Dynamics, heat and mass transfer of vapour-gas bubbles in a liquid

Time spectra of neutron and sonoluminescence emissions were measured in cavitation experiments with chilled deuterated acetone. Statistically significant neutron and gamma ray emissions were measured with a calibrated liquid-scintillation detector, and sonoluminescence emissions were measured with a photomultiplier tube. The neutron and sonoluminescence emissions were found to be time correlated over the time of significant bubble cluster dynamics. The neutron emission energy was less than 2.5 MeV and the neutron emission rate was up to approximately 4 x 10(5) n/s. Measurements of tritium production were also performed and these data implied a neutron emission rate due to D-D fusion which agreed with what was measured. In contrast, control experiments using normal acetone did not result in statistically significant tritium activity, or neutron or gamma ray emissions.

/pdf/additional-evidence-of-nuclear-emissions-during-acoustic-4meju7u7jk.pdf

Robert I. Nigmatulin

Papers

Dynamics of multiphase media

Evidence for Nuclear Emissions During Acoustic Cavitation

Spatial averaging in the mechanics of heterogeneous and dispersed systems

Dynamics, heat and mass transfer of vapour-gas bubbles in a liquid

Additional evidence of nuclear emissions during acoustic cavitation.