Showing papers by "Robert J. Yokelson published in 1993"
TL;DR: In this article, the UV absorption spectrum of Cl 2 O 3 between 220 and 320 nm was measured using time-resolved transient absorption, which peaks at 267 nm with a cross section of (1.60 -0.22 + 0.35 )×10 -17 cm 2 (2σ error limits including estimated systematic errors).
Abstract: The UV absorption spectrum of Cl 2 O 3 between 220 and 320 nm was measured using time-resolved transient absorption. Cl 2 O 3 was produced following 193-nm pulsed laser photolysis of N 2 O/Cl 2 /OClO/He or CF 2 /Cl 2 /OClO/N 2 gas mixtures by reaction 1:ClO+OClO+M→Cl 2 O 3 +M. The absorption spectrum peaks at 267 nm with a cross section of (1.60 -0.22 +0.35 )×10 -17 cm 2 (2σ error limits including estimated systematic errors)
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