scispace - formally typeset

Author

Roger Atkinson

Bio: Roger Atkinson is an academic researcher from University of California, Riverside. The author has contributed to research in topic(s): Reaction rate constant & Radical. The author has an hindex of 92, co-authored 416 publication(s) receiving 44449 citation(s).
Papers
More filters

Journal ArticleDOI
Roger Atkinson1Institutions (1)
Abstract: The present status of knowledge of the gas-phase reactions of inorganic Ox, HOx and NOx species and of selected classes of volatile organic compounds (VOCs) [alkanes, alkenes, aromatic hydrocarbons, oxygen-containing VOCs and nitrogen-containing VOCs] and their degradation products in the troposphere is discussed. There is now a good qualitative and, in a number of areas, quantitative understanding of the tropospheric chemistry of NOx and VOCs involved in the photochemical formation of ozone. During the past five years much progress has been made in elucidating the reactions of alkoxy radicals, the mechanisms of the gas-phase reactions of O3 with alkenes, and the mechanisms and products of the OH radical-initiated reactions of aromatic hydrocarbons, and further progress is expected. However, there are still areas of uncertainty which impact the ability to accurately model the formation of ozone in urban, rural and regional areas, and these include a need for: rate constants and mechanisms of the reactions of organic peroxy ( R O 2 ) radicals with NO, NO3 radicals, HO2 radicals and other R O 2 radicals; organic nitrate yields from the reactions of R O 2 radicals with NO, preferably as a function of temperature and pressure; the reaction rates of alkoxy radicals for decomposition, isomerization, and reaction with O2, especially for alkoxy radicals other than those formed from alkanes and alkenes; the detailed mechanisms of the reactions of O3 with alkenes and VOCs containing >CC

2,367 citations


Journal ArticleDOI
Roger Atkinson1, Janet Arey1Institutions (1)

1,995 citations


Journal ArticleDOI
Roger Atkinson1, Donald L. Baulch2, R. A. Cox3, John Crowley4  +6 moreInstitutions (10)
Abstract: This article, the fourth in the series, presents kinetic and photochemical data sheets evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and photochemical reactions of organic halogen species, which were last published in 1997, and were updated on the IUPAC website in 2006/07. The article consists of a summary sheet, containing the recommended kinetic parameters for the evaluated reactions, and four appendices containing the data sheets, which provide information upon which the recommendations are made.

1,474 citations


Journal ArticleDOI
Roger Atkinson1, Donald L. Baulch2, R. A. Cox3, John Crowley4  +5 moreInstitutions (9)
Abstract: . This article, the first in the series, presents kinetic and photochemical data evaluated by the IUPAC Subcommittee on GasKinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and photochemical reactions of Ox, HOx, NOx and SOx species, which were last published in 1997, and were updated on the IUPAC website in late 2001. The article consists of a summary sheet, containing the recommended kinetic parameters for the evaluated reactions, and five appendices containing the data sheets, which provide information upon which the recommendations are made.

1,458 citations


Journal ArticleDOI
Abstract: Literature data (through mid-1996) concerning the gas-phase reactions of alkanes and alkenes (including isoprene and monoterpenes) leading to their first generation products are reviewed and evaluated for tropospheric conditions. The recommendations of the most recent IUPAC evaluation [J. Phys. Chem. Ref. Data, 26, No. 3 (1997)] are used for the ⩽C3 organic compounds, unless more recent data necessitates reevaluation. The most recent review and evaluation of Atkinson [J. Phys. Chem. Ref. Data, Monograph 2, 1 (1994)] concerning the kinetics of the reactions of OH radicals, NO3 radicals, and O3 is also updated for these two classes of volatile organic compounds.

1,176 citations


Cited by
More filters

Journal ArticleDOI
Abstract: Numerical assessments of global air quality and potential changes in atmospheric chemical constituents require estimates of the surface fluxes of a variety of trace gas species. We have developed a global model to estimate emissions of volatile organic compounds from natural sources (NVOC). Methane is not considered here and has been reviewed in detail elsewhere. The model has a highly resolved spatial grid (0.5° × 0.5° latitude/longitude) and generates hourly average emission estimates. Chemical species are grouped into four categories: isoprene, monoterpenes, other reactive VOC (ORVOC), and other VOC (OVOC). NVOC emissions from oceans are estimated as a function of geophysical variables from a general circulation model and ocean color satellite data. Emissions from plant foliage are estimated from ecosystem specific biomass and emission factors and algorithms describing light and temperature dependence of NVOC emissions. Foliar density estimates are based on climatic variables and satellite data. Temporal variations in the model are driven by monthly estimates of biomass and temperature and hourly light estimates. The annual global VOC flux is estimated to be 1150 Tg C, composed of 44% isoprene, 11% monoterpenes, 22.5% other reactive VOC, and 22.5% other VOC. Large uncertainties exist for each of these estimates and particularly for compounds other than isoprene and monoterpenes. Tropical woodlands (rain forest, seasonal, drought-deciduous, and savanna) contribute about half of all global natural VOC emissions. Croplands, shrublands and other woodlands contribute 10–20% apiece. Isoprene emissions calculated for temperate regions are as much as a factor of 5 higher than previous estimates.

3,645 citations


Journal ArticleDOI
Alex Guenther1, Thomas Karl1, Peter Harley1, Christine Wiedinmyer1  +2 moreInstitutions (3)
Abstract: . Reactive gases and aerosols are produced by terrestrial ecosystems, processed within plant canopies, and can then be emitted into the above-canopy atmosphere. Estimates of the above-canopy fluxes are needed for quantitative earth system studies and assessments of past, present and future air quality and climate. The Model of Emissions of Gases and Aerosols from Nature (MEGAN) is described and used to quantify net terrestrial biosphere emission of isoprene into the atmosphere. MEGAN is designed for both global and regional emission modeling and has global coverage with ~1 km2 spatial resolution. Field and laboratory investigations of the processes controlling isoprene emission are described and data available for model development and evaluation are summarized. The factors controlling isoprene emissions include biological, physical and chemical driving variables. MEGAN driving variables are derived from models and satellite and ground observations. Tropical broadleaf trees contribute almost half of the estimated global annual isoprene emission due to their relatively high emission factors and because they are often exposed to conditions that are conducive for isoprene emission. The remaining flux is primarily from shrubs which have a widespread distribution. The annual global isoprene emission estimated with MEGAN ranges from about 500 to 750 Tg isoprene (440 to 660 Tg carbon) depending on the driving variables which include temperature, solar radiation, Leaf Area Index, and plant functional type. The global annual isoprene emission estimated using the standard driving variables is ~600 Tg isoprene. Differences in driving variables result in emission estimates that differ by more than a factor of three for specific times and locations. It is difficult to evaluate isoprene emission estimates using the concentration distributions simulated using chemistry and transport models, due to the substantial uncertainties in other model components, but at least some global models produce reasonable results when using isoprene emission distributions similar to MEGAN estimates. In addition, comparison with isoprene emissions estimated from satellite formaldehyde observations indicates reasonable agreement. The sensitivity of isoprene emissions to earth system changes (e.g., climate and land-use) demonstrates the potential for large future changes in emissions. Using temperature distributions simulated by global climate models for year 2100, MEGAN estimates that isoprene emissions increase by more than a factor of two. This is considerably greater than previous estimates and additional observations are needed to evaluate and improve the methods used to predict future isoprene emissions.

3,236 citations


Journal ArticleDOI
Mattias Hallquist1, John C. Wenger2, Urs Baltensperger3, Yinon Rudich4  +25 moreInstitutions (21)
Abstract: Secondary organic aerosol (SOA) accounts for a significant fraction of ambient tropospheric aerosol and a detailed knowledge of the formation, properties and transformation of SOA is therefore required to evaluate its impact on atmospheric processes, climate and human health. The chemical and physical processes associated with SOA formation are complex and varied, and, despite considerable progress in recent years, a quantitative and predictive understanding of SOA formation does not exist and therefore represents a major research challenge in atmospheric science. This review begins with an update on the current state of knowledge on the global SOA budget and is followed by an overview of the atmospheric degradation mechanisms for SOA precursors, gas-particle partitioning theory and the analytical techniques used to determine the chemical composition of SOA. A survey of recent laboratory, field and modeling studies is also presented. The following topical and emerging issues are highlighted and discussed in detail: molecular characterization of biogenic SOA constituents, condensed phase reactions and oligomerization, the interaction of atmospheric organic components with sulfuric acid, the chemical and photochemical processing of organics in the atmospheric aqueous phase, aerosol formation from real plant emissions, interaction of atmospheric organic components with water, thermodynamics and mixtures in atmospheric models. Finally, the major challenges ahead in laboratory, field and modeling studies of SOA are discussed and recommendations for future research directions are proposed.

2,925 citations


Journal ArticleDOI
Abstract: Fenton chemistry encompasses reactions of hydrogen peroxide in the presence of iron to generate highly reactive species such as the hydroxyl radical and possibly others. In this review, the complex mechanisms of Fenton and Fenton-like reactions and the important factors influencing these reactions, from both a fundamental and practical perspective, in applications to water and soil treatment, are discussed. The review covers modified versions including the photoassisted Fenton reaction, use of chelated iron, electro-Fenton reactions, and Fenton reactions using heterogeneous catalysts. Sections are devoted to nonclassical pathways, by-products, kinetics and process modeling, experimental design methodology, soil and aquifer treatment, use of Fenton in combination with other advanced oxidation processes or biodegradation, economic comparison with other advanced oxidation processes, and case studies.

2,745 citations


Journal ArticleDOI
Maria Kanakidou1, John H. Seinfeld2, Spyros N. Pandis3, Ian Barnes  +18 moreInstitutions (9)
Abstract: The present paper reviews existing knowledge with regard to Organic Aerosol (OA) of importance for global climate modelling and defines critical gaps needed to reduce the involved uncertainties. All pieces required for the representation of OA in a global climate model are sketched out with special attention to Secondary Organic Aerosol (SOA): The emission estimates of primary carbonaceous particles and SOA precursor gases are summarized. The up-to-date understanding of the chemical formation and transformation of condensable organic material is outlined. Knowledge on the hygroscopicity of OA and measurements of optical properties of the organic aerosol constituents are summarized. The mechanisms of interactions of OA with clouds and dry and wet removal processes parameterisations in global models are outlined. This information is synthesized to provide a continuous analysis of the flow from the emitted material to the atmosphere up to the point of the climate impact of the produced organic aerosol. The sources of uncertainties at each step of this process are highlighted as areas that require further studies.

2,630 citations


Network Information
Related Authors (5)
Janet Arey

207 papers, 14.3K citations

96% related
Sara M. Aschmann

204 papers, 9.9K citations

93% related
James N. Pitts

198 papers, 15.3K citations

92% related
William P. L. Carter

149 papers, 9.5K citations

88% related
Timothy J. Wallington

562 papers, 24.5K citations

86% related
Performance
Metrics

Author's H-index: 92

No. of papers from the Author in previous years
YearPapers
20151
20143
20136
20126
20115
20106