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S. Chandrasekhar

Bio: S. Chandrasekhar is an academic researcher from Raman Research Institute. The author has contributed to research in topics: Liquid crystal & Biaxial nematic. The author has an hindex of 31, co-authored 124 publications receiving 3368 citations. Previous affiliations of S. Chandrasekhar include Royal Institution & University of Mysore.


Papers
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Journal ArticleDOI
TL;DR: In this article, the refractive indices of anisaldazine, CH3OC6H4CH:NN:CHC4H4OCH3, have been measured in the crystalline, nematic and isotropic phases and the orientational order parameter in the mesophase has been evaluated by the application of the Vuks formula.
Abstract: The refractive indices of anisaldazine, CH3OC6H4CH:NN:CHC4H4OCH3, have been measured in the crystalline, nematic and isotropic phases and the orientational order parameter in the mesophase has been evaluated by the application of the Vuks formula. The curve for the order parameter versus the relative temperature (Te-T) is nearly parallel with those for p-azoxyanisole and p-azoxyphenetole and lies approximately midway between them.

58 citations

Journal ArticleDOI
TL;DR: Results of studies on the effect of pressure on phase transitions in 1,2-dimyristoyl-phosphatidylcholine (DMPC) and DPPC dispersed in excess water are presented.

56 citations

Journal ArticleDOI
TL;DR: In this paper, the authors describe recent progress in elucidating the properties of columnar phases as one-dimensional electrical conductors, fast photoconductors, light emitting diodes and ferroelectrics, all of which have potentially important practical applications.
Abstract: After a brief introduction to discotic liquid crystals, we describe recent progress in elucidating the properties of the columnar phases as one-dimensional electrical conductors (or molecular wires), fast photoconductors, light emitting diodes and ferroelectrics, all of which have potentially important practical applications.

56 citations

Journal ArticleDOI
01 May 1988-Pramana
TL;DR: In this paper, a biaxial nematic liquid crystal was found in a simple thermotropic system, where the liquid crystal is a bao-nematic liquid.
Abstract: We report a biaxial nematic liquid crystal in a simple thermotropic system.

51 citations

Journal ArticleDOI
TL;DR: In this paper, the nematic phase of 4,4-(p-terphenyl)-bis and 2,3,4-tri(dodecyloxy)benzalimine is found to be biaxial, the biaaxial angle increasing with schlieren textures exhibited by the nematic phase have been between glass plates, as well as free standing consisting entirely of s or 2-brush disclinations.
Abstract: Conoscopic studies reveal that the nematic phase of 4,4-(p-terphenyl)-bis\[2,3,4-tri(dodecyloxy)benzal]imine is biaxial, the biaxial angle increasing with schlieren textures exhibited by the nematic phase have been between glass plates, as well as free-standing consisting entirely of s or 2-brush disclinations, confirming an earlier suggestion that the absence of 4-brush disclinations is evidence of biaxiality decreasing temperature The examined Films sandwiched films, exhibit a nematic schlieren texture

51 citations


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Book
24 Sep 2002
Abstract: CRYSTALLINE MATERIALS Introduction Physical Properties Optical Properties Mechanical Properties Thermal Properties Magnetooptic Properties Electrooptic Properties Elastooptic Properties Nonlinear Optical Properties GLASSES Introduction Commercial Optical Glasses Specialty Optical Glasses Fused Silica Fluoride Glasses Chalcogenide Glasses Magnetooptic Properties Electrooptic Properties Elastooptic Properties Nonlinear Optical Properties Special Glasses POLYMERIC MATERIALS Optical Plastics Index of Refraction Nonlinear Optical Properties Thermal Properties Engineering Data METALS Physical Properties of Selected Metals Optical Properties Mechanical Properties Thermal Properties Mirror Substrate Materials LIQUIDS Introduction Water Physical Properties of Selected Liquids Index of Refraction Nonlinear Optical Properties Magnetooptic Properties Commercial Optical Liquids GASES Introduction Physical Properties of Selected Gases Index of Refraction Nonlinear Optical Properties Magnetooptic Properties Atomic Resonance Filters APPENDICES Safe Handling of Optical Materials Abbreviations, Acronyms, and Mineralogical or Common Names for Optical Materials Abbreviations for Methods of Preparing Optical Materials and Thin Films Fundamental Physical Constants Units and Conversion Factors

1,262 citations

Journal ArticleDOI
TL;DR: The structural origin of chirality in different supramolecular structures through combinations of structural analysis methods has been investigated in this article, where the most ideal building blocks would need to display shape persistence in solution and in the solid state, since only this feature provides access to the use of complementary methods of structural analyses.
Abstract: Dendron-mediated self-assembly, disassembly, and self-organization of complex systems have been investigated. The most ideal building blocks would need to display shape persistence in solution and in the solid state, since only this feature provides access to the use of complementary methods of structural analysis. Most supramolecular dendrimers are chiral even when they are constructed from nonchiral building blocks and are equipped with mechanisms that amplify chirality. This poses additional challenges associated with the understanding of the structural origin of chirality in different supramolecular structures through combinations of structural analysis methods. While many supramolecular structures assembled from dendrimers and dendrons resemble some of the related morphologies generated from block-copolymers, they are much more complex and are not determined by the volume ratio between the dissimilar parts of the molecule.

1,061 citations

Journal ArticleDOI
TL;DR: This Review will focus on the major classes of columnar mesogens rather than presenting a library of columner liquid crystals, and emphasis will be given to efficient synthetic procedures, and relevant mesomorphic and physical properties.
Abstract: Most associate liquid crystals with their everyday use in laptop computers, mobile phones, digital cameras, and other electronic devices. However, in contrast to their rodlike (calamitic) counterparts, first described in 1907 by Vorlander, disklike (discotic, columnar) liquid crystals, which were discovered in 1977 by Chandrasekhar et al., offer further applications as a result of their orientation in the columnar mesophase, making them ideal candidates for molecular wires in various optical and electronic devices such as photocopiers, laser printers, photovoltaic cells, light-emitting diodes, field-effect transistors, and holographic data storage. Beginning with an overview of the various mesophases and characterization methods, this Review will focus on the major classes of columnar mesogens rather than presenting a library of columnar liquid crystals. Emphasis will be given to efficient synthetic procedures, and relevant mesomorphic and physical properties. Finally, some applications and perspectives in materials science and molecular electronics will be discussed.

1,056 citations