A topical review of numerical and experimental studies of supercontinuum generation in photonic crystal fiber is presented over the full range of experimentally reported parameters, from the femtosecond to the continuous-wave regime. Results from numerical simulations are used to discuss the temporal and spectral characteristics of the supercontinuum, and to interpret the physics of the underlying spectral broadening processes. Particular attention is given to the case of supercontinuum generation seeded by femtosecond pulses in the anomalous group velocity dispersion regime of photonic crystal fiber, where the processes of soliton fission, stimulated Raman scattering, and dispersive wave generation are reviewed in detail. The corresponding intensity and phase stability properties of the supercontinuum spectra generated under different conditions are also discussed.

Supercontinuum generation in photonic crystal fiber

The term photonic crystals appears because of the analogy between electron waves in crystals and the light waves in artificial periodic dielectric structures. During the recent years the investigation of one-, two-and three-dimensional periodic structures has attracted a widespread attention of the world optics community because of great potentiality of such structures in advanced applied optical fields. The interest in periodic structures has been stimulated by the fast development of semiconductor technology that now allows the fabrication of artificial structures, whose period is comparable with the wavelength of light in the visible and infrared ranges.

http://ieeexplore.ieee.org/iel5/6354/16969/00781867.pdf

Photonic crystals

Surface plasmons (SPs) are coherent oscillations of conduction electrons on a metal surface excited by electromagnetic radiation at a metal -dielectric interface. The growing field of research on such light -metal interactions is known as ‘plasmonics’. 1-3 This branch of research has attracted much attention due to its potential applications in miniaturized optical devices, sensors, and photonic circuits as well as in medical diagnostics and therapeutics. 4-8

Nanostructured plasmonic sensors.

This review discusses how low-energy, valence excitations created by swift electrons can render information on the optical response of structured materials with unmatched spatial resolution. Electron microscopes are capable of focusing electron beams on sub-nanometer spots and probing the target response either by analyzing electron energy losses or by detecting emitted radiation. Theoretical frameworks suited to calculate the probability of energy loss and light emission (cathodoluminescence) are revisited and compared with experimental results. More precisely, a quantum-mechanical description of the interaction between the electrons and the sample is discussed, followed by a powerful classical dielectric approach that can be in practice applied to more complex systems. We assess the conditions under which classical and quantum-mechanical formulations are equivalent. The excitation of collective modes such as plasmons is studied in bulk materials, planar surfaces, and nanoparticles. Light emission induced by the electrons is shown to constitute an excellent probe of plasmons, combining sub-nanometer resolution in the position of the electron beam with nanometer resolution in the emitted wavelength. Both electron energy-loss and cathodoluminescence spectroscopies performed in a scanning mode of operation yield snap shots of plasmon modes in nanostructures with fine spatial detail as compared to other existing imaging techniques, thus providing an ideal tool for nanophotonics studies.

/pdf/optical-excitations-in-electron-microscopy-3d2rfnfkst.pdf

Optical excitations in electron microscopy

Platinum-based nanostructured materials: synthesis, properties, and applications.

Nanostructured metal films of platinum, gold and silver up to 675 nm thick we prepared by electrochemical deposition through templates of 700 nm diameter polystyrene spheres assembled as hexagonal close packed monolayer on an evaporated gold surface followed by removal of the template by dissolution in tetrahydrofuran. The reflection spectra of the films at normal incidence were recorded as a function of film thickness and the spectra correlated with the local visual appearance of the film and the surface structure from SEM. For thin films, below one quarter sphere height, the spectra show a single reflectivity dip at a wavelength just below the sphere diameter consistent with surface-plasmon grating-like behaviour. For the thicker films several reflectivity dips are observed which move towards longer wavelength with increasing film thickness. This behaviour is shown to be consistent with a model in which light reflected from the top of the structure interferes with light reflected from within the spherical segment cavities in the film.

Optical properties of nanostructured metal films

We investigate the properties of gold surfaces patterned using a nanoscale "lost wax" technique by electrochemical deposition through a self-assembled latex template. Near-spherical gold nanocavities within the resulting porous films support localized surface plasmons which couple strongly to incident light, appearing as sharp spectral features in reflectivity measurements. The energy of the resonances is easily tunable from ultraviolet to near infrared by controlling the diameter and height of the nanocavities. The energies of these features agree well with the Mie resonances of a perfect spherical void.

Confined Plasmons in Metallic Nanocavities

Self-assembly of colloidal spheres onto patterned (e.g., lithographically modified [1]) substrates is a promising approach to prepare complex 3D geometries (e.g., assemble colloidal spheres into square pyramidal shapes[2]) that can not be produced by self-assembly of colloidal spheres on flat substrates. Generally self-assembly alone is restricted to the formation of close-packed 2D and 3D arrays of colloidal particles and does not lead to more complex lattice types and geometries. A certain degree of control over colloidal self-assembly has been achieved through external electric[3] or intense optical fields[4] and by manipulating the interaction potential[5]. Here we demonstrate a simple scheme that combines two self-assembly steps and electrochemical deposition to produce patterns of ordered arrays of spheres with controlled spacing and eventually isolated metallic arrays of spherical cavities.

/pdf/preparation-of-arrays-of-isolated-spherical-cavities-by-self-45qmsinrfz.pdf

Preparation of arrays of isolated spherical cavities by self-assembly of polystyrene spheres on self-assembled pre-patterned macroporous films

Confined Surface Plasmons in Gold Photonic Nanocavities

We report supercontinuum generation extending to 300nm in the UV from a pure-silica holey fiber. The broad spectrum was obtained by launching ultra-short pulses (~150fs, 10nJ at 820nm) from an amplified Ti:sapphire laser. The extension of holey-fiber-based supercontinuum generation into the UV should prove to be of immediate application in spectroscopy. By slightly detuning the launch conditions we excited a higher order spatial mode, which produced a narrower supercontinuum, but with enhanced conversion efficiency at a series of blue/UV peaks around 360nm. We present numerical simulations, which suggest that differences in the dispersion profiles between the modes are an important factor in explaining this enhancement. In a related experiment, using the same laser source and fiber, we demonstrate a visible supercontinuum from several subsidiary cores, with distinct colours in each core. The subsidiary cores were excited by an appropriate input coupling. Fabrication of a fiber with a range of core sizes (dispersion profiles) for tailored supercontinuum generation can therefore be envisaged for practical applications.

/pdf/uv-generation-in-a-pure-silica-holey-fiber-ai5kuqs9pg.pdf

S. Coyle

Papers

Optical properties of nanostructured metal films

Confined Plasmons in Metallic Nanocavities

Preparation of arrays of isolated spherical cavities by self-assembly of polystyrene spheres on self-assembled pre-patterned macroporous films

Confined Surface Plasmons in Gold Photonic Nanocavities

UV generation in a pure-silica holey fiber