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S. Roth

Bio: S. Roth is an academic researcher from Max Planck Society. The author has contributed to research in topics: Carbon nanotube & Polyacetylene. The author has an hindex of 44, co-authored 281 publications receiving 25195 citations.


Papers
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Journal ArticleDOI
TL;DR: In this article, the effect of irradiation by Ar + and N + ions on the properties of thin transparent networks of single-wall carbon nanotubes (SWNTs) was investigated.
Abstract: We investigate the effect of irradiation by Ar + and N + ions on the properties of thin transparent networks of single-wall carbon nanotubes (SWNTs). The irradiation produces a small reduction in the infra-red transmittance of the networks at a wavelength of 2000 nm that correlates with the much larger reduction in conductance, and the peaks in the infra-red-visible absorbance spectrum are strongly reduced. Ion irradiation greatly increases the localization of the charge carriers, suppressing the conductance at low temperatures more severely than at room temperature. The conductance follows variable-range hopping behaviour for all samples. Nonlinearity in the current-voltage characteristics of the thin SWNT networks is observed only at very low temperatures.

22 citations

Journal ArticleDOI
TL;DR: In this article, the first low temperature measurements of I-V characteristics of polyacetylene nanofibers were reported, which are signatures of a novel conduction mechanism: the creation of charged soliton-antisoliton pairs by quantum-mechanical tunneling.

21 citations

Journal ArticleDOI
TL;DR: In this paper, the atomic nature of hydrogen storage in single wall carbon nanotubes (SWNTs) was investigated by thermal desorption spectroscopy utilizing mass spectrometry.
Abstract: The atomic nature of hydrogen storage in single wall carbon nanotubes (SWNTs) has been investigated by thermal desorption spectroscopy utilizing mass spectrometry The partial pressures of desorbed H2, D2, and HD have been simultaneously recorded after sample loading with a 1:1 mixture of H2 and D2 gases The amount of desorbed HD molecules approaches the ratio 2:1:1 for HD:H2:D2 in the case of atomic storage, ie chemisorption In the case of storage as molecules, ie physisorption, the concentration of HD approaches the background level Hydrogen isotopes are absorbed as atoms in SWNT samples containing transition metals from either sample production (Ni, Fe, …) and/or activation (opening) process (Ni, Fe, Ti, …) Purified SWNTs adsorb hydrogen molecules at low temperatures

21 citations

Journal ArticleDOI
TL;DR: In this article, a single polyacetylene (PA) nanofiber, a single-walled carbon nanotube (SWNT)-rope, and a lithographically prepared stripe of poly(2-methoxy-5-(2-ethyl hexyloxy)-p-phenylene vinylene) (MEH-PPV) were measured.

21 citations

Journal ArticleDOI
TL;DR: In this paper, the synthesis of the first polydecker sandwich complex (η5,μ-2,3,dihydro-1,3-diborolyl) was reported by a polycondensation reaction from a binuclear precursor.

20 citations


Cited by
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Journal ArticleDOI
TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
Abstract: Graphene is a rapidly rising star on the horizon of materials science and condensed-matter physics. This strictly two-dimensional material exhibits exceptionally high crystal and electronic quality, and, despite its short history, has already revealed a cornucopia of new physics and potential applications, which are briefly discussed here. Whereas one can be certain of the realness of applications only when commercial products appear, graphene no longer requires any further proof of its importance in terms of fundamental physics. Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena, some of which are unobservable in high-energy physics, can now be mimicked and tested in table-top experiments. More generally, graphene represents a conceptually new class of materials that are only one atom thick, and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.

35,293 citations

Journal ArticleDOI
TL;DR: In this paper, the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations, are discussed.
Abstract: This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

20,824 citations

28 Jul 2005
TL;DR: PfPMP1)与感染红细胞、树突状组胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作�ly.
Abstract: 抗原变异可使得多种致病微生物易于逃避宿主免疫应答。表达在感染红细胞表面的恶性疟原虫红细胞表面蛋白1(PfPMP1)与感染红细胞、内皮细胞、树突状细胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作用。每个单倍体基因组var基因家族编码约60种成员,通过启动转录不同的var基因变异体为抗原变异提供了分子基础。

18,940 citations

Journal ArticleDOI
Changgu Lee1, Xiaoding Wei1, Jeffrey W. Kysar1, James Hone1, James Hone2 
18 Jul 2008-Science
TL;DR: Graphene is established as the strongest material ever measured, and atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.
Abstract: We measured the elastic properties and intrinsic breaking strength of free-standing monolayer graphene membranes by nanoindentation in an atomic force microscope. The force-displacement behavior is interpreted within a framework of nonlinear elastic stress-strain response, and yields second- and third-order elastic stiffnesses of 340 newtons per meter (N m(-1)) and -690 Nm(-1), respectively. The breaking strength is 42 N m(-1) and represents the intrinsic strength of a defect-free sheet. These quantities correspond to a Young's modulus of E = 1.0 terapascals, third-order elastic stiffness of D = -2.0 terapascals, and intrinsic strength of sigma(int) = 130 gigapascals for bulk graphite. These experiments establish graphene as the strongest material ever measured, and show that atomically perfect nanoscale materials can be mechanically tested to deformations well beyond the linear regime.

18,008 citations

Journal ArticleDOI
19 Jun 2009-Science
TL;DR: This review analyzes recent trends in graphene research and applications, and attempts to identify future directions in which the field is likely to develop.
Abstract: Graphene is a wonder material with many superlatives to its name. It is the thinnest known material in the universe and the strongest ever measured. Its charge carriers exhibit giant intrinsic mobility, have zero effective mass, and can travel for micrometers without scattering at room temperature. Graphene can sustain current densities six orders of magnitude higher than that of copper, shows record thermal conductivity and stiffness, is impermeable to gases, and reconciles such conflicting qualities as brittleness and ductility. Electron transport in graphene is described by a Dirac-like equation, which allows the investigation of relativistic quantum phenomena in a benchtop experiment. This review analyzes recent trends in graphene research and applications, and attempts to identify future directions in which the field is likely to develop.

12,117 citations