Sally Ann Swanson

Bio: Sally Ann Swanson is an academic researcher from IBM. The author has contributed to research in topics: Polyimide & Nanofoam. The author has an hindex of 24, co-authored 50 publications receiving 4356 citations.

Lithium−Air Battery: Promise and Challenges

Abstract: The lithium−air system captured worldwide attention in 2009 as a possible battery for electric vehicle propulsion applications. If successfully developed, this battery could provide an energy source for electric vehicles rivaling that of gasoline in terms of usable energy density. However, there are numerous scientific and technical challenges that must be overcome if this alluring promise is to turn into reality. The fundamental battery chemistry during discharge is thought to be the electrochemical oxidation of lithium metal at the anode and reduction of oxygen from air at the cathode. With aprotic electrolytes, as used in Li-ion batteries, there is some evidence that the process can be reversed by applying an external potential, i.e., that such a battery can be electrically recharged. This paper summarizes the authors’ view of the promise and challenges facing development of practical Li−air batteries and the current understanding of its chemistry. However, it must be appreciated that this perspective ...

Transmissive electrophoretic display with laterally adjacent color cells

Abstract: A transmissive electrophoretic color display is comprised of a plurality of color pixels; each uniformly illuminated from the rear by a backlight and each comprised of at least two electrophoretic cells. Each cell is comprised of a suspension of charged, black or colored light-absorbing pigment particles in a light-transmissive fluid. Each cell is also comprised of a light-transmissive front and rear window, at least one non-obstructing counter electrode, at least one non-obstructing collecting electrode, and a color filter medium. The cells of different colors are in a laterally adjacent relationship to each other and the charged pigment particles are responsive to the electrodes. The filter medium in each cell can be a light-transmissive color filter element or the pigment suspension fluid can be colored and serve as the filter medium.

Reflective electrophoretic display with laterally adjacent color cells using a reflective panel

Abstract: An ambient light reflective color electrophoretic display is comprised of a plurality of color pixels; each comprised of at least two electrophoretic cells. Each cell is comprised of a suspension of charged, black or colored light-absorbing pigment particles in a light-transmissive fluid. Each cell is also comprised of a light-transmissive front window, at least one non-obstructing counter electrode, at least one non-obstructing collecting electrode, a light-reflective panel, and a color filter medium. The cells of different colors are in a laterally adjacent relationship to each other and the charged pigment particles are responsive to the electrodes. The filter medium in each cell can be a light-transmissive color filter element or a light-reflective colored surface or the pigment suspension fluid can be colored and serve as the filter medium.

Transmissive electrophoretic display with vertical electrodes

Abstract: A transmissive electrophoretic display is generally comprised of a regular lateral array of transmissive electrophoretic cells; each uniformly illuminated from the rear by a backlight. Each cell is comprised of a suspension of charged, black or colored light-absorbing pigment particles in a light-transmissive fluid. Each cell is also comprised of a light-transmissive front and rear window, at least one non-obstructing counter electrode, and at least one non-obstructing, vertically-disposed collecting electrode. With the application of appropriate voltages to the collecting and counter electrodes, each cell can be switched between a light and dark state. In the dark state, the light-absorbing pigment particles are distributed to cover the horizontal area of the cell, thus absorbing light from the backlight and preventing it from reaching the viewer. In the light state, the light-absorbing pigment particles are collected on vertical surfaces within the cell, thus allowing light from the backlight to pass through the cell and reach the viewer.

Electrical Energy Storage for the Grid: A Battery of Choices

Abstract: The increasing interest in energy storage for the grid can be attributed to multiple factors, including the capital costs of managing peak demands, the investments needed for grid reliability, and the integration of renewable energy sources. Although existing energy storage is dominated by pumped hydroelectric, there is the recognition that battery systems can offer a number of high-value opportunities, provided that lower costs can be obtained. The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.

Li-O2 and Li-S batteries with high energy storage.

Abstract: Li-ion batteries have transformed portable electronics and will play a key role in the electrification of transport. However, the highest energy storage possible for Li-ion batteries is insufficient for the long-term needs of society, for example, extended-range electric vehicles. To go beyond the horizon of Li-ion batteries is a formidable challenge; there are few options. Here we consider two: Li-air (O(2)) and Li-S. The energy that can be stored in Li-air (based on aqueous or non-aqueous electrolytes) and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed. Fundamental scientific advances in understanding the reactions occurring in the cells as well as new materials are key to overcoming these obstacles. The potential benefits of Li-air and Li-S justify the continued research effort that will be needed.

Challenges in the development of advanced Li-ion batteries: a review

Abstract: Li-ion battery technology has become very important in recent years as these batteries show great promise as power sources that can lead us to the electric vehicle (EV) revolution. The development of new materials for Li-ion batteries is the focus of research in prominent groups in the field of materials science throughout the world. Li-ion batteries can be considered to be the most impressive success story of modern electrochemistry in the last two decades. They power most of today's portable devices, and seem to overcome the psychological barriers against the use of such high energy density devices on a larger scale for more demanding applications, such as EV. Since this field is advancing rapidly and attracting an increasing number of researchers, it is important to provide current and timely updates of this constantly changing technology. In this review, we describe the key aspects of Li-ion batteries: the basic science behind their operation, the most relevant components, anodes, cathodes, electrolyte solutions, as well as important future directions for R&D of advanced Li-ion batteries for demanding use, such as EV and load-leveling applications.

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review.

Abstract: The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applicatio...