Samit K. Ray

Bio: Samit K. Ray is an academic researcher from Indian Institute of Technology Kharagpur. The author has contributed to research in topics: Photoluminescence & Thin film. The author has an hindex of 44, co-authored 507 publications receiving 8085 citations. Previous affiliations of Samit K. Ray include University of Delaware & Indian Institute of Technology Kanpur.

Temperature dependent growth and optical properties of SnO2 nanowires and nanobelts

Abstract: SnO2 nanowires and nanobelts have been grown by the thermal evaporation of Sn powders. The growth of nanowires and nanobelts has been investigated at different temperatures (750–1000°C). The field emission scanning electron microscopic and transmission electron microscopic studies revealed the growth of nanowires and nano-belts at different growth temperatures. The growth mechanisms of the formation of the nanostructures have also been discussed. X-ray diffraction patterns showed that the nanowires and nanobelts are highly crystalline with tetragonal rutile phase. UV-visible absorption spectrum showed the bulk bandgap value (∼ 3–6 eV) of SnO2. Photoluminescence spectra demonstrated a Stokes-shifted emission in the wavelength range 558–588 nm. The Raman and Fourier transform infrared spectra revealed the formation of stoichiometric SnO2 at different growth temperatures.

Enhanced UV-visible photodetection characteristics of a flexible Si membrane-ZnO heterojunction utilizing piezo-phototronic effect

Abstract: We report the characteristics of an n-ZnO/p-Si membrane heterojunction flexible photodetector sensitive to UV and visible illumination. A piezo-phototronic effect has been observed for the deposited ZnO thin films on flexible silicon membranes. Si membranes as low as ~3.0 µm thick have been fabricated by the alkaline etching of Si wafers followed by ZnO deposition using RF sputtering for realizing the heterostructure. A peak responsivity of 0.20 AW−1 with a detectivity of 4.8 × 1011 cm Hz1/2 W−1 is found at ~490 nm for zero bias. Strain induced piezo-potential developed in ZnO thin films is found to modulate the transport property of the photo generated carriers, resulting in the enhanced performance of the device. With a gradual increase in the external tensile stress, the photocurrent increases by 22%. The accompanying COMSOL analysis displays the piezopotential distribution developed in ZnO films on application of an external stress to the heterojunction, which is in close agreement with the experimental data.

Evolution of strain and composition of Ge islands on Si (001) grown by molecular beam epitaxy during postgrowth annealing

Abstract: Self-assembled Ge islands have been grown using a Stranski–Krastanov growth mechanism on Si (001) substrates by solid source molecular beam epitaxy. We performed time varying annealing experiments at a representative temperature of 650°C to study the shape and size evolution of islands for a relatively high Ge coverage. Islands are found to coarsen due to heat treatment via structural and compositional changes through continuous strain relaxation. Different island morphologies, namely, “pyramids,” “transitional domes,” and “domes” are found during the annealing sequence. The dominant coarsening mechanisms for the temporal evolution of islands of as-grown and annealed samples are explained by the comprehensive analysis of Rutherford back scattering, Raman spectroscopy, high-resolution x-ray diffraction, and atomic force microscopy. A correlation of the morphological evolution with the composition and strain relaxation of grown islands is presented.

The Study of Cyanobacterial Flora from Geothermal Springs of Bakreswar, West Bengal, India

Abstract: Geothermal springs in India, formed as a result of volcanic or tectonic activities, are characterized by high temperature and relatively abundant reduced compounds. These thermal springs are inhabited by characteristic thermophilic organisms including cyanobacteria. Cyanobacteria are among the few organisms that can occupy high temperature aquatic environments including hot springs. In alkaline and neutral hot springs and streams flowing from them cyanobacteria can form thick colourful mats that exhibit banding patterns. The present investigation involves study of mat forming cyanobacterial flora from hot springs located in Bakreswar, West Bengal, India. The important species found are Synechococcus bigranulatus, S. lividus, Gloeocapsa gelatinosa, G. muralis, Phormidium laminosum, P. frigidum, Oscillatoria princes, O. fragilis, Lyngbya lutea, Pseudanabaena sp., Calothrix thermalis, and Fischerella thermalis. Their distribution pattern in relation to physico-chemical parameters of spring water has also been studied. Three cyanobacterial strains of the above mentioned list were grown in culture and their pigment content and nitrogen fixing capacity were also studied. Nitrogen fixing capacities of Calothrix thermalis, Nostoc sp. (isolated in culture) and Fischerella thermalis are 5.14, 0.29, and 2.60 n mole C2H4/µg of Chl-a/hr respectively. Carotenoid : Chlorophyll-a ratio of four mat samples collected from Kharkunda, Suryakunda, Dudhkunda and bathing pool are 2.45, 1.60, 1.48, and 1.34, respectively. Higher value of Carotenoid : Chlorophyll-a ratio coincided with higher temperature.

Piezo-phototronic mediated enhanced photodetection characteristics of plasmonic Au-g-C3N4/CdS/ZnO based hybrid heterojunctions on a flexible platform.

Abstract: We have studied the piezo-phototronic induced enhancement in the photo-response of CdS/ZnO heterojunctions attached with plasmonic Au nanoparticle loaded 2D-graphitic carbon nitride (g-C3N4) The hybrid g-C3N4/CdS/ZnO heterojunction favours the charge carrier separation through the formation of a step-like band alignment Furthermore, the integration of plasmonic Au loaded g-C3N4 nanosheets on the conventional CdS/ZnO heterojunction facilitates improved visible light absorption properties The heterojunction device on a flexible platform under the application of a strain (∼0017%) exhibits ∼102 times higher photoresponse over the control sample at a constant bias of ∼2 V The variation in the photo-response under different bending conditions has been explained in terms of the improved charge transport through the modified energy bands at the interface of ZnO The improved piezo-phototronic properties originated from the plasmonic properties of Au loaded g-C3N4 and the piezoelectric characteristics of c-axis oriented ZnO films may be used for future flexible photonic devices

Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications

Abstract: Nanocrystals (NCs) discussed in this Review are tiny crystals of metals, semiconductors, and magnetic material consisting of hundreds to a few thousand atoms each. Their size ranges from 2-3 to about 20 nm. What is special about this size regime that placed NCs among the hottest research topics of the last decades? The quantum mechanical coupling * To whom correspondence should be addressed. E-mail: dvtalapin@uchicago.edu. † The University of Chicago. ‡ Argonne National Lab. Chem. Rev. 2010, 110, 389–458 389

Principles Of Fluorescence Spectroscopy

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Nanoscale metal oxide-based heterojunctions for gas sensing: A review

Abstract: Metal oxide-based resistive-type gas sensors are solid-state devices which are widely used in a number of applications from health and safety to energy efficiency and emission control. Nanomaterials such as nanowires, nanorods, and nanoparticles have dominated the research focus in this field due to their large number of surface sites facilitating surface reactions. Previous studies have shown that incorporating two or more metal oxides to form a heterojunction interface can have drastic effects on gas sensor performance, especially the selectivity. Recently, these effects have been amplified by designing heterojunctions on the nano-scale. These designs have evolved from mixed commercial powders and bi-layer films to finely-tuned core–shell and hierarchical brush-like nanocomposites. This review details the various morphological classes currently available for nanostructured metal-oxide based heterojunctions and then presents the dominant electronic and chemical mechanisms that influence the performance of these materials as resistive-type gas sensors. Mechanisms explored include p–n and n–n potential barrier manipulation, n–p–n response type inversions, spill-over effects, synergistic catalytic behavior, and microstructure enhancement. Tables are presented summarizing these works specifically for SnO2, ZnO, TiO2, In2O3, Fe2O3, MoO3, Co3O4, and CdO-based nanocomposites. Recent developments are highlighted and likely future trends are explored.

Diversity of life

Abstract: It is clear that the above can lead to confusion when scientists of different countries are trying to communicate with each other. Another example is the burrowing rodent called a gopher found throughout the western United States. In the southeastern United States the term gopher refers to a burrowing turtle very similar to the desert tortoise found in the American southwest. One final example; two North American mammals known as the elk and the caribou are known in Europe as the reindeer and the elk. We never sing “Rudolph the Red-nosed elk”! Confused? This was the reason for creating an internationally recognized system of naming organisms. To avoid confusion, living organisms are assigned a scientific name based on Latin or Latinized words. The English sparrow is Passer domesticus or Passer domesticus (italics or underlining these two names is the official written representation of a scientific name). Using a uniform naming system allows scientists from all over the world to recognize exactly which life form a scientist is referring to. The naming process is called the binomial system of nomenclature. Passer is comparable to a surname and is called the genus, while domesticus is the specific or species name (like your given name) of the English sparrow. Now scientists can give all sparrow-like birds the genus Passer but the species name will vary. All similar genera (plural for genus) can be grouped into another, “higher” category (see below). Study the following for a more through understanding of taxonomy. Taxonomy Analogy Kingdom: Animalia Country

Environmental applications of graphene-based nanomaterials.

Abstract: Graphene-based materials are gaining heightened attention as novel materials for environmental applications The unique physicochemical properties of graphene, notably its exceptionally high surface area, electron mobility, thermal conductivity, and mechanical strength, can lead to novel or improved technologies to address the pressing global environmental challenges This critical review assesses the recent developments in the use of graphene-based materials as sorbent or photocatalytic materials for environmental decontamination, as building blocks for next generation water treatment and desalination membranes, and as electrode materials for contaminant monitoring or removal The most promising areas of research are highlighted, with a discussion of the main challenges that we need to overcome in order to fully realize the exceptional properties of graphene in environmental applications