Sanchita Goswami

TL;DR: The observation of VT in complex 1 is the first example where a mixed valence semiquinone-catecholate iron(III) complex undergoes intramolecular electron transfer similar to manganese and cobalt complexes.

TL;DR: The ligand H2Vd is an excellent probe for sensing Zn2+ in solution, whereas complexes 1(a-c) are able to selectively detect pyrophosphate (PPi) in aqueous medium and the structure of the pyroph phosphate complex has been proposed using DFT calculations and the selectivity is due to the unique ability of this anion to simultaneously coordinate to both the Zn metal centers.

TL;DR: In this paper, a new macrocyclic hexanuclear manganese(III) 18-azametallacrown-6 compound, [Mn6(ashz)6(CH3OH)3(H2O)3] AE 3H 2O AE 3DMF (1), has been prepared using a trianionic pentadentate ligand N-acetylsalicylhydrazide (ashz 3� ) and characterised by various techniques such as elemental analysis, IR, UV-vis and fluorescence spectroscopy,

TL;DR: In this paper, a new, highly selective and sensitive Schiff base chemosensor, H 2 bpet, based on benzophenone that can detect Al 3+ in a 0.01% ethanol in 50mM HEPES buffer medium by fluorimetric sensing.

TL;DR: The potential of complex1 to act as an anticancer agent is thoroughly examined on a series of liver cancer cell lines and screening shows the HepG2 cell line exhibits maximum cytotoxicity by phosphatidyl serine exposure in the outer cell membrane associated with ROS generation and mitochondrial depolarization with increasing time in the in vitro model system.