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Sandro Santucci

Bio: Sandro Santucci is an academic researcher from University of L'Aquila. The author has contributed to research in topics: Thin film & X-ray photoelectron spectroscopy. The author has an hindex of 51, co-authored 365 publications receiving 10887 citations. Previous affiliations of Sandro Santucci include AREA Science Park & Elettra Sincrotrone Trieste.


Papers
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Journal ArticleDOI
TL;DR: In this article, carbon nanotubes (CNTs) deposited by plasmaenhanced chemical vapor deposition on Si3N4/Si substrates have been investigated as resistive gas sensors for NO2.
Abstract: Carbon nanotubes (CNTs) deposited by plasma-enhanced chemical vapor deposition on Si3N4/Si substrates have been investigated as resistive gas sensors for NO2. Upon exposure to NO2, the electrical resistance of the CNTs was found to decrease. The maximum variation of resistance to NO2 was found at an operating temperature of around 165 °C. The sensor exhibited high sensitivity to NO2 gas at concentrations as low as 10 ppb, fast response time, and good selectivity. A thermal treatment method, based on repeated heating and cooling of the films, adjusted the resistance of the sensor film and optimized the sensor response to NO2.

532 citations

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TL;DR: In this article, the surface chemistry of L-CVD SnO2 thin films on Si(100) before and after subsequent additional oxidation was studied. And the ageing effect was also checked in order to check the influence of ambient oxidation.

345 citations

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TL;DR: The relaxation properties of a stochastic bistable system perturbed by a periodic low-frequency forcing term is investigated by means of analog simulation and its dependence on the parameters of both the periodic perturbation and the forced system is explained theoretically.
Abstract: The relaxation properties of a stochastic bistable system perturbed by a periodic low-frequency forcing term is investigated by means of analog simulation. The so-called stochastic resonance phenomenon is revealed under diverse experimental conditions. Its dependence on the parameters of both the periodic perturbation and the forced system is explained theoretically.

317 citations

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TL;DR: Stochastic resonance in a bistable potential is fully characterized as a synchronization effect of the hopping mechanism induced by the external periodic bias, thus revealing a bona fide resonant process.
Abstract: Stochastic resonance in a bistable potential is fully characterized as a synchronization effect of the hopping mechanism induced by the external periodic bias. Most notably, synchronization is shown to attain a maximum by increasing the forcing frequency close to the relevant switching rate, thus revealing a bona fide resonant process.

245 citations

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TL;DR: In this article, the surface stoichiometry of SiO x thin films (x = 1-2) has been studied by means of X-ray photoelectron spectroscopy, and the presence of three Si oxidation states (SiO 2, SiO, Si 2 O 3 ) has been observed through an analysis of the Si2p line shape and the intensity variation of these different silicon oxide signals, as a function of the oxygen content.

229 citations


Cited by
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TL;DR: In this paper, the authors report, extend, and interpret much of our current understanding relating to theories of noise-activated escape, for which many of the notable contributions are originating from the communities both of physics and of physical chemistry.
Abstract: The calculation of rate coefficients is a discipline of nonlinear science of importance to much of physics, chemistry, engineering, and biology. Fifty years after Kramers' seminal paper on thermally activated barrier crossing, the authors report, extend, and interpret much of our current understanding relating to theories of noise-activated escape, for which many of the notable contributions are originating from the communities both of physics and of physical chemistry. Theoretical as well as numerical approaches are discussed for single- and many-dimensional metastable systems (including fields) in gases and condensed phases. The role of many-dimensional transition-state theory is contrasted with Kramers' reaction-rate theory for moderate-to-strong friction; the authors emphasize the physical situation and the close connection between unimolecular rate theory and Kramers' work for weakly damped systems. The rate theory accounting for memory friction is presented, together with a unifying theoretical approach which covers the whole regime of weak-to-moderate-to-strong friction on the same basis (turnover theory). The peculiarities of noise-activated escape in a variety of physically different metastable potential configurations is elucidated in terms of the mean-first-passage-time technique. Moreover, the role and the complexity of escape in driven systems exhibiting possibly multiple, metastable stationary nonequilibrium states is identified. At lower temperatures, quantum tunneling effects start to dominate the rate mechanism. The early quantum approaches as well as the latest quantum versions of Kramers' theory are discussed, thereby providing a description of dissipative escape events at all temperatures. In addition, an attempt is made to discuss prominent experimental work as it relates to Kramers' reaction-rate theory and to indicate the most important areas for future research in theory and experiment.

5,180 citations

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TL;DR: In this paper, photo-induced superhydrophilicity was used on the surface of a wide-band gap semiconductor like titanium dioxide (TiO 2 ) for photocatalytic activity towards environmentally hazardous compounds.

4,241 citations

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TL;DR: Department of Materials Science, University of Patras, Greece, Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, and Dipartimento di Scienze Farmaceutiche, Universita di Trieste, Piazzale Europa 1, 34127 Triesteadays.
Abstract: Department of Materials Science, University of Patras, 26504 Rio Patras, Greece, Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Avenue, 116 35 Athens, Greece, Institut de Biologie Moleculaire et Cellulaire, UPR9021 CNRS, Immunologie et Chimie Therapeutiques, 67084 Strasbourg, France, and Dipartimento di Scienze Farmaceutiche, Universita di Trieste, Piazzale Europa 1, 34127 Trieste, Italy

3,886 citations