Sateesh Gedupudi

Bio: Sateesh Gedupudi is an academic researcher from Indian Institute of Technology Madras. The author has contributed to research in topics: Heat transfer coefficient & Heat transfer. The author has an hindex of 10, co-authored 50 publications receiving 412 citations. Previous affiliations of Sateesh Gedupudi include Brunel University London.

Effect of Interaction of Nanoparticles and Surfactants on the Spreading Dynamics of Sessile Droplets.

Abstract: While a body of literature on the spreading dynamics of surfactants and a few studies on the spreading dynamics of nanocolloids exist, to the best of the authors’ knowledge, there are no reports on the effect of presence of surfactants on the spreading dynamics of nanocolloidal suspensions. For the first time the present study reports an extensive experimental and theoretical study on the effect of surfactant impregnated nanocolloidal complex fluids in modulating the spreading dynamics. A segregation analysis of the effect of surfactants alone, nanoparticle alone, and the combined effect of nanoparticle and surfactants in altering the spreading dynamics have been studied in detail. The spreading dynamics of nanocolloidal solutions alone and of the surfactant impregnated nanocolloidal solutions are found to be grossly different, and particle morphology is found to play a predominant role. For the first time the present study experimentally proves that the classical Tanner’s law is disobeyed by the complex ...

Wettability of Complex Fluids and Surfactant Capped Nanoparticle-Induced Quasi-Universal Wetting Behavior B

Abstract: Even though there are quite large studies on wettability of aqueous surfactants and a few studies on effects of nanoparticles on wettability of colloids, to the best of authors’ knowledge, there is no study reported on the combined effect of surfactant and nanoparticles in altering the wettability. The present study, for the first time, reports an extensive experimental and theoretical study on the combined effect of surfactants and nanoparticles on the wettability of complex fluids such as nanocolloids on different substrates, ranging from hydrophilic with a predominantly polar surface energy component (silicon wafer and glass) to near hydrophobic range with a predominantly dispersive component of surface energy (aluminum and copper substrates). Systematically planned experiments are carried out to segregate the contributing effects of surfactants, particles, and combined particle and surfactants in modulating the wettability. The mechanisms and the governing parameters behind the interactions of nanocolloids alone and of surfactant capped nanocolloids with different surfaces are found to be grossly different. The article, for the first time, also analyzes the interplay of the nature of surfaces, surfactant and particle concentrations on contact angle, and contact angle hysteresis (CAH) of particle and surfactant impregnated colloidal suspensions. In the case of nanoparticle suspensions, the contact angle is observed to decrease for the hydrophobic system and increase for the hydrophilic systems considered. On the contrary, the combined particle and surfactant colloidal system shows a quasi-unique wetting behavior of decreasing contact angle with particle concentration on all substrates. Also interestingly, the combined particle surfactant system at all particle concentrations shows a wetting angle much lower than that of the only-surfactant case at the same surfactant concentration. Such counterintuitive observations have been explained based on the near-surface interactivity of the particle, fluid, and surfactant molecules based on effective slip length considerations. The CAH analyses of colloidal suspensions at varying surfactant and particle concentrations reveal in-depth physical insight into contact line pinning, and a unique novel relationship is established between the contact angle and differential energy for distorting the instantaneous contact angle for a pinned sessile droplet. A detailed theoretical analysis of the governing parameters influencing the wettability has been presented invoking the principles of DLVO (Derjaguin–Landau–Verwey–Overbeek), surface energy and interaction parameters influencing at the molecular scale, and the theoretical framework is found to support the experimental observations.

Oscillatory solutothermal convection-driven evaporation kinetics in colloidal nanoparticle-surfactant complex fluid pendant droplets

Abstract: To elucidate the pure physics of evaporation which is free from surface effects, the pendant mode of evaporation is employed in the present study. The present study brings out the evaporation kinetics of a combined surfactant and nanoparticle colloidal system. We also segregate the contributing effects of surfactants alone, particle alone, and the combined effect of surfactant and particles in modulating the evaporation kinetics. It is observed that the rate of evaporation is a strong function of the particle concentration for nanocolloidal suspensions of particle alone and concentration of surfactant molecules up to the micellar concentration and thereafter insensitive to concentration for an aqueous surfactant solution. The combined colloidal system of nanoparticles and surfactant exhibited the maximum evaporation rate, and the rate is a strong function of the concentration of both the particle and surfactant. The theoretical classical diffusion-driven evaporation falls short of the experimentally observed evaporation rate in aqueous surfactant and colloidal solutions. Evidence of convective currents was observed in flow visualization studies in aqueous surfactant solutions, nanocolloidal solution of particle alone, and an oscillatory convective circulation in a combined surfactant-impregnated nanocolloidal solution. Thermal Marangoni and Rayleigh numbers are calculated from the theoretical examination and are found not potent enough to induce strong circulation currents in such systems from a stability map. Scaling analysis of solutal Marangoni is observed to be capable of inducing circulation from a stability map in all the systems and the enhanced thermophoretic drift and Brownian dynamics, and enhancement in the diffusion coefficient of the nanoparticles is also contributing to the enhanced evaporation rate for only nanocolloidal solutions. The oscillatory convective current arising out of two opposing driving potential enhances the evaporation rate of surfactant-impregnated nanocolloids. The present findings could reveal the effect of surfactants in tuning the evaporation rate of colloidal solutions.

Correlating contact line capillarity and dynamic contact angle hysteresis in surfactant-nanoparticle based complex fluids

Abstract: Dynamic wettability and contact angle hysteresis can be correlated to shed insight onto any solid-liquid interaction. Complex fluids are capable of altering the expected hysteresis and dynamic wetting behavior due to interfacial interactions. We report the effect of capillary number on the dynamic advancing and receding contact angles of surfactant-based nanocolloidal solutions on hydrophilic, near hydrophobic, and superhydrophobic surfaces by performing forced wetting and de-wetting experiments by employing the embedded needle method. A segregated study is performed to infer the contributing effects of the constituents and effects of particle morphology. The static contact angle hysteresis is found to be a function of particle and surfactant concentrations and greatly depends on the nature of the morphology of the particles. An order of estimate of line energy and a dynamic flow parameter called spreading factor and the transient variations of these parameters are explored which sheds light on the dynami...