Soddemann T

Bio: Soddemann T is an academic researcher. The author has an hindex of 1, co-authored 1 publications receiving 383 citations.

Fluid mobility and frequency-dependent seismic velocity — Direct measurements

Abstract: The influence of fluid mobility on seismic velocity dispersion is directly observed in laboratory measurements from seismic to ultrasonic frequencies. A forceddeformation system is used in conjunction with pulse transmission to obtain elastic properties at seismic strain amplitude (10 −7 ) from 5 Hz to 800 kHz. Varying fluid types and saturations document the influence of pore-fluids. The ratio of rock permeability to fluid viscosity defines mobility, which largely controls pore-fluid motion and pore pressure in a porous medium. High fluid mobility permits pore-pressure equilibrium either between pores or between heterogeneous regions, resulting in a low-frequency domain where Gassmann’s equations are valid. In contrast, low fluid mobility can produce strong dispersion, even within the seismic band. Here, the low-frequency assumption fails. Since most rocks in the general sedimentary section have very low permeability and fluid mobility (shales, siltstones, tight limestones, etc.), most rocks are not in the lowfrequency domain, even at seismic frequencies. Only those rocks with high permeability (porous sands and carbonates) will remain in the low-frequency domain in the seismic or sonic band.

Absolute hydration free energy scale for alkali and halide ions established from simulations with a polarizable force field.

Abstract: A polarizable potential function for the hydration of alkali and halide ions is developed on the basis of the recent SWM4-DP water model [Lamoureux, G.; MacKerell, A. D., Jr.; Roux, B. J. Chem. Phys. 2003, 119, 5185]. Induced polarization is incorporated using classical Drude oscillators that are treated as auxiliary dynamical degrees of freedom. The ions are represented as polarizable Lennard-Jones centers, whose parameters are optimized to reproduce the binding energies of gas-phase monohydrates and the hydration free energies in the bulk liquid. Systematic exploration of the parameters shows that the monohydrate binding energies can be consistent with a unique hydration free energy scale if the computed hydration free energies incorporate the contribution from the air/water interfacial electrostatic potential (-540 mV for SWM4-DP). The final model, which can satisfyingly reproduce both gas and bulk-phase properties, corresponds to an absolute scale in which the intrinsic hydration free energy of the proton is -247 kcal/mol.