Thermophysical Properties Research Literature Retrieval Guide Edited by Y. S. Touloukian, J. K. Gerritsen and N. Y. Moore Second edition, revised and expanded. Book 1: Pp. xxi + 819. Book 2: Pp.621. Book 3: Pp. ix + 1315. (New York: Plenum Press, 1967.) n.p.

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Heat and Mass Transfer

The movement of drops in electric fields plays a role in processes as diverse as storm cloud formation, ink-jet printing and lab-on-a-chip manipulations. An important factor in practical applications is the tendency for adjacent drops to coalesce, usually assumed to be favoured if drops are oppositely charged and attracted to each other. Now Ristenpart et al. show that when oppositely charged drops move towards each other in an electric field whose strength exceeds a critical value, the drops simply 'bounce' off one another. This observation calls for a re-evaluation of our understanding of all processes involving electrically induced drop motion. Adjacent drops of fluid coalesce, and oppositely charged drops have long been assumed to experience an attractive force that favours their coalescence. However, here it is observed that oppositely charged drops moving towards each other in a strong electric field do not coalesce when the field strength exceeds a certain value but rather 'bounce' off one another. This observation calls for a re-evaluation of our understanding of processes such as storm cloud formation and ink-jet printing, which involve electrically induced droplet motion. Electric fields induce motion in many fluid systems, including polymer melts1, surfactant micelles2 and colloidal suspensions3. Likewise, electric fields can be used to move liquid drops4. Electrically induced droplet motion manifests itself in processes as diverse as storm cloud formation5, commercial ink-jet printing6, petroleum and vegetable oil dehydration7, electrospray ionization for use in mass spectrometry8, electrowetting9 and lab-on-a-chip manipulations10. An important issue in practical applications is the tendency for adjacent drops to coalesce, and oppositely charged drops have long been assumed to experience an attractive force that favours their coalescence11,12,13. Here we report the existence of a critical field strength above which oppositely charged drops do not coalesce. We observe that appropriately positioned and oppositely charged drops migrate towards one another in an applied electric field; but whereas the drops coalesce as expected at low field strengths, they are repelled from one another after contact at higher field strengths. Qualitatively, the drops appear to ‘bounce’ off one another. We directly image the transient formation of a meniscus bridge between the bouncing drops, and propose that this temporary bridge is unstable with respect to capillary pressure when it forms in an electric field exceeding a critical strength. The observation of oppositely charged drops bouncing rather than coalescing in strong electric fields should affect our understanding of any process involving charged liquid drops, including de-emulsification, electrospray ionization and atmospheric conduction.

http://absimage.aps.org/image/DFD09/MWS_DFD09-2009-001564.pdf

Non-coalescence of oppositely charged drops

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Marangoni Effects On Drop Deformation In AnExtensional Flow: The Role Of Surfactant PhysicalChemistry

Failure investigation of buffer layers in high-voltage XLPE cables

The sedimentation of a surfactant-laden deformable viscous drop acted upon by an electric field is considered theoretically. The convection of surfactants in conjunction with the the combined effect electrohydrodynamic flow and sedimentation leads to a locally varying surface tension, which subsequently alters the drop dynamics via the interplay of Marangoni, Maxwell and hydrodynamic stresses. Assuming small capillary number and small electric Reynolds number, we employ a regular perturbation technique to solve the coupled system of governing equations. It is shown that when a leaky dielectric drop is sedimenting in another leaky dielectric fluid, Marangoni stress can oppose the electrohydrodynamic motion severely, thereby causing corresponding changes in internal flow pattern. Such effects further result in retardation of drop settling velocity, which would have otherwise increased due to the influence of charge convection. For highly mobile surfactants (high Peclet number limit), the drop surface becomes immobilized and the charge convection effect gets completely eliminated. For non-spherical drop shapes, the effect of Marangoni stress is overcome by the 'tip stretching' effect on the flow field. As a result, the drop deformation gets intensified with increment in sensitivity of surface tension to the local surfactant concentration. Consequently, for oblate type of deformation the elevated drag force causes further reduction in velocity. Owing to similar reasons, prolate drops experience lesser drag and settles faster than the surfactant-free case. In addition to this, with increased sensitivity of interfacial tension on the surfactant concentration, the asymmetric deformation about the equator gets suppressed.

Sedimentation of a surfactant-laden drop under the influence of an electric field

Results are presented concerning the influence of an applied electric field on the coalescence of a water droplet with a much bigger water drop, both drops being immersed in a crude oil. This original study of electrocoalescence in crude oil was performed through high-speed optical observations, using a near-infrared camera, of a droplet falling onto a bottom drop, a bipolar square voltage being applied. For low electrical field strength, the electrostatic pressure at the water/oil interface of the merging droplet partly counteracts the capillary forces, which slows down the drop coalescence process. Above threshold field strength, the electric forces drastically affect the dynamics of drop deformation and merging. At a working temperature T = 60 °C, partial coalescence was observed, leaving a daughter drop of size increasing with the applied field. At T = 40 °C, there was an abrupt transition from coalescence to non-coalescence, the top droplet inducing an upward directed nearly conical deformation of the bottom drop. This is attributed to charge exchange between the colliding water drops at each polarity reversal of the applied voltage, thus generating a bouncing-like behaviour at a frequency twice the voltage frequency. The charge exchange occurs through a very thin filament interconnecting the drops during a short time and presumably generated by interface instability. Under strong enough applied field, there was also formation of a very fine mist around the zone of drop quasi contact; this mist is ascribed to the break-up of the transitory very thin ligament bridging the drops. Some explanations and considerations are proposed for the various observations; in particular, it is proposed that the contrast between the transitions to partial coalescence (at 60 °C) and to non-coalescence (at 40 °C) arises from geometrical differences in the temporary small bridge interconnecting the drops.

Experimental study of electrocoalescence of water drops in crude oil using near-infrared camera

Influence of surfactants on the electrohydrodynamic stretching of water drops in oil

The main aging mechanism of electrical cables with polymeric electrical insulation is the growth of water trees. Water trees are initiated if the relative humidity (RH) in the electrical insulation is above a critical level. Delaying the water ingress into the electrical insulation system delays the water tree initiation and reduces water tree growth, thus extending the service life of the cable. For a cable without any metallic water barrier, the water ingress can be significantly delayed by the use of an outer sheath material with low water permeability. An even greater delay in the water ingress into the electrical insulation can be achieved using a layered sheath system. To explore the possibilities of a layered sheath system, calculations of water ingress into a typical cable cross section has been performed using a finite element method. The water diffusion and sorption data used in the calculation has been measured for typical cable materials. Calculations have been performed for uniform temperature conditions and for a temperature gradient due to resistive current heating. The time to reach critical humidity levels and stationary humidity levels in the insulation system has been determined for several different arrangements of the sheath system. A sheath system with an outer layer of a material with low water permeability and an inner layer of a material with a high water absorption capacity is shown to give a significant delay of the water ingress into the electrical insulation. For the sheath materials used in this study, there is an optimum distribution of thickness of each layer. The calculations also show that a temperature gradient across the insulation system of a cable in operation gives an advantageous RH profile. With a temperature gradient the equilibrium RH level in parts of the electrical insulation can be lower than the critical value for water tree initiation. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011

Calculation of water ingress in a HV subsea XLPE cable with a layered water barrier sheath system

The behaviour of a single sub-millimetre-size water drop falling through a viscous oil while subjected to an electric field is of fundamental importance to industrial applications such as crude oil electrocoalescers. Detailed studies, both experimental and computational, have been performed previously, but an often challenging issue has been the characterization of the fluids. As numerous authors have noted, it is very difficult to have a perfectly clean water-oil system even for very pure model oils, and the presence of trace chemicals may significantly alter the interface behaviour. In this work, we consider a wellcharacterized water-oil system where controlled amounts of a surface active agent (Span 80) have been added to the oil. This addition dominates any trace contaminants in the oil, such that the interface behaviour can also be well-characterized. We present the results of experiments and corresponding two-phaseflow simulations of a falling water drop covered in surfactant and subjected to a monopolar square voltage pulse. The results are compared and good agreement is found for surfactant concentrations below the critical micelle concentration.

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Experimental and computational studies of water drops falling through model oil with surfactant and subjected to an electric field

Field windings made of MgB2 wires or tapes are considered for their potential to reduce volume, weight, and cost of large offshore wind turbine generators. To gain experience of how to use this relatively new material in full-scale generators, tests of different winding methodologies and techniques are needed. In this paper, we describe in detail the steps used to wind a racetrack coil with a length of 1 m and a width of 0.5 m out of 4.5 km of MgB2 superconducting tape. The width corresponds to a full-scale pole of a 10-MW generator, whereas the length of the straight section is shorter than the corresponding full-scale pole. The coil was built up of ten double pancake coils. Each double pancake coil was wet wound using a semiautomatic winding process, where Stycast 2850 was applied directly to the MgB2 tape without any other dedicated electrical insulation. The strengths and weaknesses of the winding process are discussed and compared to the dry-winding method.

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Svein Magne Hellesø

Papers

Experimental study of electrocoalescence of water drops in crude oil using near-infrared camera

Influence of surfactants on the electrohydrodynamic stretching of water drops in oil

Calculation of water ingress in a HV subsea XLPE cable with a layered water barrier sheath system

Experimental and computational studies of water drops falling through model oil with surfactant and subjected to an electric field

Fabrication of a Scaled MgB2 Racetrack Demonstrator Pole for a 10-MW Direct-Drive Wind Turbine Generator