T. Kimura

Bio: T. Kimura is an academic researcher from University of Electro-Communications. The author has contributed to research in topics: Photoluminescence & Doping. The author has an hindex of 13, co-authored 25 publications receiving 1857 citations. Previous affiliations of T. Kimura include Massachusetts Institute of Technology.

Raman intensity of single-wall carbon nanotubes

Abstract: Using nonresonant bond-polarization theory, the Raman intensity of a single-wall carbon nanotube is calculated as a function of the polarization of light and the chirality of the carbon nanotube. The force-constant tensor for calculating phonon dispersion relations in the nanotubes is scaled from those for two-dimensional graphite. The calculated Raman spectra do not depend much on the chirality, while their frequencies clearly depend on the nanotube diameter. The polarization and sample orientation dependence of the Raman intensity shows that the symmetry of the Raman modes can be obtained by varying the direction of the nanotube axis, keeping the polarization vectors of the light fixed.

Inhomogeneous optical absorption around the K point in graphite and carbon nanotubes

Abstract: The optical absorption spectra of \ensuremath{\pi} electrons are calculated for graphite and carbon nanotubes. Particular attention is paid to the processes contributing to the optical absorption as a function of the electron wave vector k and light polarization direction. The optical absorption amplitude around the K point in the Brillouin zone has a node in the two-dimensional Brillouin zone of graphite. The formula for the absorption scattering matrix around the K point is given analytically by expanding the matrix element into a Taylor series. The chirality dependence of the absorption matrix element of a single-wall carbon nanotube is presented.

Electronic states in heavily Li-doped graphite nanoclusters

Abstract: Fracture modes in a model glass–polymer coating–substrate system indented with hard spheres are investigated. The large modulus mismatch between the glass and polymer results in distinctive transverse fracture modes within the brittle coating: exaggerated circumferential (C) ring cracks that initiate at the upper coating surface well outside the contact (as opposed to the near-contact Hertzian cone fractures observed in monolithic brittle materials); median–radial (M) cracks that initiate at the lower surface (i.e., at the substrate interface) on median planes containing the contact axis. Bonding between the coating and substrate is sufficiently strong as to preclude delamination in our system. The transparency of the constituent materials usefully enables in situ identification and quantification of the two transverse fracture modes during contact. The morphologies of the cracks and the corresponding critical indentation loads for initiation are measured over a broad range of coating thicknesses (20 mm to 5.6 mm), on coatings with like surface flaw states, here ensured by a prebonding abrasion treatment. There is a well-defined, broad intermediate range where the indented coating responds more like a flexing plate than a Hertzian contact, and where the M and C cracks initiate in close correspondence with a simple critical stress criterion, i.e., when the maximum tensile stresses exceed the bulk strength of the (abraded) glass. In this intermediate range the M cracks generally form first—only when the flaws on the lower surface are removed (by etching) do the C cracks form first. Finite element modeling is used to evaluate the critical stresses at crack initiation and the surface locations of the crack origins. Departures from the critical stress condition occur at the extremes of very thick coatings (monolith limit) and very thin coatings (thin-film limit), where stress gradients over the flaw dimension are large. Implications of the results concerning practical coating systems are considered.

Electrochemical Er doping of porous silicon and its room‐temperature luminescence at ∼1.54 μm

Abstract: We present a new electro‐chemical method for incorporating high concentration Er ions deep into porous silicon layers and its intense photoluminescence at ∼1.54 μm at room temperature. Porous silicon layers prepared by anodic etching of p‐type silicon substrates in HF/H2O are immersed in ErCl3/ethanol solution. Then the negative bias relative to a counter platinum electrode is applied to the samples. Er3+ ions are drawn into fine pores of the porous silicon layers by the electric field. After thermal annealing at ∼1300 °C in an O2/Ar atmosphere, the samples show sharp and intense Er3+‐related photoluminescence at ∼1.54 μm at room temperature upon excitation with an Ar ion laser.

Raman spectroscopy as a versatile tool for studying the properties of graphene

Abstract: Raman spectroscopy is an integral part of graphene research. It is used to determine the number and orientation of layers, the quality and types of edge, and the effects of perturbations, such as electric and magnetic fields, strain, doping, disorder and functional groups. This, in turn, provides insight into all sp(2)-bonded carbon allotropes, because graphene is their fundamental building block. Here we review the state of the art, future directions and open questions in Raman spectroscopy of graphene. We describe essential physical processes whose importance has only recently been recognized, such as the various types of resonance at play, and the role of quantum interference. We update all basic concepts and notations, and propose a terminology that is able to describe any result in literature. We finally highlight the potential of Raman spectroscopy for layered materials other than graphene.

Synthetic molecular motors and mechanical machines.

Abstract: The widespread use of controlled molecular-level motion in key natural processes suggests that great rewards could come from bridging the gap between the present generation of synthetic molecular systems, which by and large rely upon electronic and chemical effects to carry out their functions, and the machines of the macroscopic world, which utilize the synchronized movements of smaller parts to perform specific tasks. This is a scientific area of great contemporary interest and extraordinary recent growth, yet the notion of molecular-level machines dates back to a time when the ideas surrounding the statistical nature of matter and the laws of thermodynamics were first being formulated. Here we outline the exciting successes in taming molecular-level movement thus far, the underlying principles that all experimental designs must follow, and the early progress made towards utilizing synthetic molecular structures to perform tasks using mechanical motion. We also highlight some of the issues and challenges that still need to be overcome.